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Basic Information
| CAS No.: | 4246-51-9 |
|---|---|
| Name: | 4,7,10-TRIOXA-1,13-TRIDECANEDIAMINE |
| Article Data: | 6 |
| Molecular Structure: | |
|
|
|
| Formula: | C10H24 N2 O3 |
| Molecular Weight: | 220.312 |
| Synonyms: | Propylamine,3,3'-[oxybis(ethyleneoxy)]bis- (6CI,7CI,8CI);1,13-Diamino-4,7,10-trioxatridecane; 4,7,10-Trioxa-1,13-tridecanamine;4,7,10-Trioxatridecane-1,13-diamine; Ancamine 1922;Bis[2-(3-aminopropoxy)ethyl] ether; DPA-DEG; Diethylene glycolbis(3-aminopropyl) ether; O,O'-Bis(3-aminopropyl)diethylene glycol; Q 19262 |
| EINECS: | 224-207-2 |
| Density: | 1.001 g/cm3 |
| Melting Point: | -32 °C |
| Boiling Point: | 310.6 °C at 760 mmHg |
| Flash Point: | 148 °C |
| Appearance: | clear colorless to light yellow liquid |
| Hazard Symbols: |
 C
|
| Risk Codes: | 34 |
| Safety: | Moderately toxic by skin contact. Mildly toxic by ingestion. When heated to decomposition it emits toxic fumes of NOx. See also GLYCOL ETHERS. |
| Transport Information: | UN 2735 |
| PSA: | 79.73000 |
| LogP: | 1.13440 |
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Synthetic route
- 22397-31-5
bis(2-(2-cyanoethoxy)ethyl)ether
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
Conditions
| Conditions | Yield |
|---|---|
| With ammonia; nickel at 110℃; under 58840.6 Torr; Hydrogenation; | |
| With hydrogen; nickel In propan-1-ol |
- 10143-54-1
3-(2-(2-hydroxyethoxy)ethoxy)propanenitrile
- 22397-31-5
bis(2-(2-cyanoethoxy)ethyl)ether
A
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
B
- 112-33-4
2-[2-(3-amino-propoxy)-ethoxy]-ethanol
C
- 111-46-6
diethylene glycol
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen; Grace 2724 sponge cobalt In water at 60℃; under 42133 Torr; for 4h; Product distribution / selectivity; |
...Expand
- 10143-54-1
3-(2-(2-hydroxyethoxy)ethoxy)propanenitrile
- 22397-31-5
bis(2-(2-cyanoethoxy)ethyl)ether
C
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
D
- 112-33-4
2-[2-(3-amino-propoxy)-ethoxy]-ethanol
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen; Grace 2724 sponge cobalt In methanol at 120℃; under 42133 Torr; for 5h; Product distribution / selectivity; | |
| With hydrogen; Grace 2724 sponge cobalt In DMF (N,N-dimethyl-formamide) at 120℃; under 42133 Torr; for 5h; Product distribution / selectivity; | |
| With hydrogen; Grace 2724 sponge cobalt In tert-butyl methyl ether at 120℃; under 42133 Torr; for 5h; Product distribution / selectivity; |
...Expand
- 10143-54-1
3-(2-(2-hydroxyethoxy)ethoxy)propanenitrile
- 22397-31-5
bis(2-(2-cyanoethoxy)ethyl)ether
B
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
C
- 112-33-4
2-[2-(3-amino-propoxy)-ethoxy]-ethanol
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen; Grace 2724 sponge cobalt at 125℃; under 47304.6 Torr; for 4h; Product distribution / selectivity; | |
| With hydrogen; Grace 2724 sponge cobalt In tetrahydrofuran at 120℃; under 42133 Torr; for 5h; Product distribution / selectivity; |
...Expand
- 10143-54-1
3-(2-(2-hydroxyethoxy)ethoxy)propanenitrile
- 22397-31-5
bis(2-(2-cyanoethoxy)ethyl)ether
A
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
B
- 112-33-4
2-[2-(3-amino-propoxy)-ethoxy]-ethanol
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen; Grace 2724 sponge cobalt In tert-butyl methyl ether at 120℃; under 42133 Torr; for 5h; Product distribution / selectivity; | |
| With hydrogen; Grace 2724 sponge cobalt In tetrahydrofuran at 120℃; under 42133 Torr; for 5h; Product distribution / selectivity; |
...Expand
- 929-75-9
2-[2-[2-[2-aminoethoxy]ethoxy]ethoxy]ethylamine
- 1073123-93-9
1(4)-methoxy-7,10,13-trioxa-3,17-diaza-1(2,6)-pyridinaoctadecacyclophan-2,17-diene
A
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
B
- 1073123-92-8
1(4)-methoxy-6,9,12-trioxa-3,15-diaza-1(2,6)-pyridinahexadecacyclophan-2,15-diene
Conditions
| Conditions | Yield |
|---|---|
| In d(4)-methanol at 20℃; for 12h; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| Stage #1: carbon disulfide; 4,7,10-trioxa-1,13-diaminotridecane With triethylamine In ethanol at 20℃; Stage #2: With dmap; di-tert-butyl dicarbonate In ethanol at 20℃; for 0.25h; Further stages.; | 100% |
| Stage #1: carbon disulfide; 4,7,10-trioxa-1,13-diaminotridecane With triethylamine In N,N-dimethyl-formamide at 0℃; Stage #2: With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate In N,N-dimethyl-formamide at 0℃; for 0.25h; |
Conditions
| Conditions | Yield |
|---|---|
| With triethylamine In tetrahydrofuran for 0.5h; | 100% |
Conditions
| Conditions | Yield |
|---|---|
| In N,N-dimethyl-formamide; acetonitrile at 20℃; for 12h; Inert atmosphere; | 100% |
- 4246-51-9
4,7,10-trioxa-1,13-diaminotridecane
- 24424-99-5
di-tert-butyl dicarbonate
- 194920-62-2
tert-butyl N-(3-{2-[2-(3-aminopropoxy)ethoxy]ethoxy}propyl)carbamate
Conditions
| Conditions | Yield |
|---|---|
| In 1,4-dioxane Inert atmosphere; | 99% |
| In 1,4-dioxane | 98% |
| In 1,4-dioxane; water at 20℃; for 17h; | 96% |
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4,7,10-TRIOXA-1,13-TRIDECANEDIAMINE
Chemistry
Product Name:DIETHYLENE GLYCOL DI(3-AMINOPROPYL) ETHER(4246-51-9)
CAS No:4246-51-9
Molecular Formula : C10H24N2O3
Formula Weight : 220.31
MP : -32 °C
BP : 146-148 °C4 mm Hg(lit.)
Density : 1.005 g/mL at 25 °C(lit.)
Refractive index : n20/D 1.464(lit.)
Fp : >230 °F
Synonyms of DIETHYLENE GLYCOL DI(3-AMINOPROPYL) ETHER(4246-51-9):BIS[2-(3-AMINOPROPOXY)ETHYL] ETHER;DIETHYLENE GLYCOL BIS(3-AMINOPROPYL) ETHER;DCA 221;ALPHA, OMEGA,-BIS-(3-AMINOPROPYL)-DIETHYLENEGLYCOL ETHER;4,7,10-TRIOXA-1,13-TRIDECANEDIAMINE;1,13-DIAMINO-4,7,10-TRIOXATRIDECANE;3,3'-OXYBIS(ETHYLENE-OXY)BIS(PROPYLAMINE);O,O'-BIS(3-AMINOPROPYL)DIETHYLENE GLYCOL
Molecular Structure of DIETHYLENE GLYCOL DI(3-AMINOPROPYL) ETHER(4246-51-9):
CAS No:4246-51-9
Molecular Formula : C10H24N2O3
Formula Weight : 220.31
MP : -32 °C
BP : 146-148 °C4 mm Hg(lit.)
Density : 1.005 g/mL at 25 °C(lit.)
Refractive index : n20/D 1.464(lit.)
Fp : >230 °F
Synonyms of DIETHYLENE GLYCOL DI(3-AMINOPROPYL) ETHER(4246-51-9):BIS[2-(3-AMINOPROPOXY)ETHYL] ETHER;DIETHYLENE GLYCOL BIS(3-AMINOPROPYL) ETHER;DCA 221;ALPHA, OMEGA,-BIS-(3-AMINOPROPYL)-DIETHYLENEGLYCOL ETHER;4,7,10-TRIOXA-1,13-TRIDECANEDIAMINE;1,13-DIAMINO-4,7,10-TRIOXATRIDECANE;3,3'-OXYBIS(ETHYLENE-OXY)BIS(PROPYLAMINE);O,O'-BIS(3-AMINOPROPYL)DIETHYLENE GLYCOL
Molecular Structure of DIETHYLENE GLYCOL DI(3-AMINOPROPYL) ETHER(4246-51-9):
Toxicity Data With Reference
| 1. | orl-rat LD50:4290 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470. | ||
| 2. | skn-rbt LD50:2500 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470. |
Consensus Reports
Diethylene glycol di(3-aminppropyl) ether was reported in EPA TSCA Inventory. Glycol ether compounds are on the Community Right-To-Know List.
Safety Profile
Moderately toxic by skin contact. Mildly toxic by ingestion. When Diethylene glycol di(3-aminppropyl) ether was heated to decomposition, it emits toxic fumes of NOx. See also GLYCOL ETHERS.
Hazard Codes : C
Risk Statements : 34
Safety Statements : 26-36/37/39-45
RIDADR : UN 2735 8/PG 3
WGK Germany : 2
RTECS : ID6475000
F : 10-34
HazardClass : 8
PackingGroup : III
Hazard Codes : C
Risk Statements : 34
Safety Statements : 26-36/37/39-45
RIDADR : UN 2735 8/PG 3
WGK Germany : 2
RTECS : ID6475000
F : 10-34
HazardClass : 8
PackingGroup : III
Specification
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4246-51-9: 2
Canada
CAS# 4246-51-9 is listed on Canada's DSL List
US Federal
TSCA
CAS# 4246-51-9 is listed on the TSCA Inventory.
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S 61 Avoid release to the environment. Refer to special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4246-51-9: 2
Canada
CAS# 4246-51-9 is listed on Canada's DSL List
US Federal
TSCA
CAS# 4246-51-9 is listed on the TSCA Inventory.