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Basic Information
CAS No.: 4943-85-5
Name: 2-AMINO-N-(2-METHYLPHENYL)BENZAMIDE
Article Data: 31
Molecular Structure:
Molecular Structure of 4943-85-5 (2-AMINO-N-(2-METHYLPHENYL)BENZAMIDE)
Formula: C14H14N2O
Molecular Weight: 226.278
Synonyms: Anthranilsaeure-o-toluidid;2-Aminobenzoesaeure-2'-methylanilid;2-Amino-benzoesaeure-o-toluidid;anthranilic acid o-toluidide;
PSA: 55.12000
LogP: 3.48370
Related products
Synthetic route
2385-25-3

2-nitro-N-(2-tolyl)benzamide

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
With tetrahydroxydiboron; 5%-palladium/activated carbon; water In acetonitrile at 50℃; for 24h;99%
With tetrahydroxydiboron; palladium on activated charcoal; water In acetonitrile at 50℃; for 24h; Inert atmosphere;99%
With hydrogen; palladium on activated charcoal In ethyl acetate under 750.075 Torr;87%
95-49-8

2-methylchlorobenzene

28144-70-9

anthranilic acid amide

A

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

B

95216-60-7

2-(2-methylphenylamino)benzamide

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos In tert-butyl alcohol at 110℃; for 17h;A 10%
B 87%
...Expand
118-48-9

isatoic anhydride

95-53-4

o-toluidine

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
With aqueous extract of mesocarp of fruit of Balanites roxburghii plant at 60℃; for 0.333333h;83%
In ethanol for 20h; Reflux;67%
95-53-4

o-toluidine

21563-73-5

2-aminobenzoyl chloride

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
In diethyl ether at 0 - 10℃; for 0.5h;81.39%
118-48-9

isatoic anhydride

527-85-5

o-Methylbenzamid

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
In ethyl acetate at 90℃; for 18h;50%
72-44-6

methaqualone

A

70180-39-1

2-Acetamidobenzoesaeure-2'-methylanilid

B

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

C

95-53-4

o-toluidine

Conditions
ConditionsYield
With sodium hydroxide for 7h; Heating; hydrolysis;
...Expand
95-53-4

o-toluidine

chloric acid

chloric acid

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 63 percent / aq. K2CO3 / tetrahydrofuran / 12 h / Heating
2: 51 percent / H2 / 5percent Pd/C / 3 h / 2327.2 Torr
View Scheme
610-14-0

2-nitrobenzyl chloride

3-<β-amino-ethyl>-indole-carboxylic acid-(2)

3-<β-amino-ethyl>-indole-carboxylic acid-(2)

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 63 percent / aq. K2CO3 / tetrahydrofuran / 12 h / Heating
2: 51 percent / H2 / 5percent Pd/C / 3 h / 2327.2 Torr
View Scheme
6'-triisopropylbiphenyl

6'-triisopropylbiphenyl

95-49-8

2-methylchlorobenzene

28144-70-9

anthranilic acid amide

A

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

B

95216-60-7

2-(2-methylphenylamino)benzamide

Conditions
ConditionsYield
With potassium carbonate; tris-(dibenzylideneacetone)dipalladium(0) In hexaneA 98 mg (87%)
B n/a
...Expand
118-92-3

anthranilic acid

4943-85-5

2-amino-N-(2-methylphenyl)benzamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: thionyl chloride / 4.5 h / 80 °C
2: diethyl ether / 0.5 h / 0 - 10 °C
View Scheme
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