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5299-64-9

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Basic Information
CAS No.: 5299-64-9
Name: N-NONANOYLMORPHOLINE
Article Data: 9
Molecular Structure:
Molecular Structure of 5299-64-9 (N-NONANOYLMORPHOLINE)
Formula: C13H25 N O2
Molecular Weight: 227.39
Synonyms: Morpholine,4-(1-oxononyl)- (9CI); Morpholine, 4-nonanoyl- (7CI,8CI); 4-Nonanoylmorpholine;AI 318284; NSC 3150
Density: 0.965g/cm3
Boiling Point: 357.4°Cat760mmHg
Flash Point: 169.9°C
Safety: Poison by inhalation and intravenous routes. Human systemic effects by inhalation: lachrymation, deviated nasal septum, and cough. An eye and intense mucous membrane irritant. When heated to decomposition it emits toxic fumes of NOx.
PSA: 29.54000
LogP: 2.53370
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Chemistry

Product Name: 4-Morpholinenonylic (CAS NO.5299-64-9)


Molecular Formula: C13H25NO2
Molecular Weight: 227.34g/mol
Mol File: 5299-64-9.mol
Appearance: Liquid
Boiling point: 357.4 °C at 760 mmHg
Flash Point: 169.9 °C
Density: 0.965 g/cm3
Water Solubility: Insoluble
Surface Tension: 35.1 dyne/cm
Enthalpy of Vaporization: 60.27 kJ/mol
Vapour Pressure: 2.74E-05 mmHg at 25°C
XLogP3: 2.9
H-Bond Donor: 0
H-Bond Acceptor: 2

Uses

 4-Morpholinenonylic (CAS NO.5299-64-9) is a used as a solvent in lachrymatory formulations containing CR gas or CS gas. It is reported to be effective against dogs and starts being effective in concentrations of over 20-40 mg.min/m3. It is considered very safe, with high differences between effective and toxic concentrations. At one time it was reportedly used as food seasoning with no reported adverse effects. However, its effectiveness when used alone is rather low even in the highest permitted concentration, so it is almost always used in combination with CR gas or CS gas commonly referred to as tear gas. In that combination, this blend is effective even against dogs and people under influence of alcohol or drugs. Its effect usually lasts for 15-30 minutes.
MPK blends with CR gas or CS gas are common personal self-defense chemical agents in Russia and Ukraine, but is virtually unknown elsewhere.
4-Nonanoylmorpholine has been reported to have insect repellent properties in Aedes aegypti mosquitoes.

Toxicity Data With Reference

1.    

eye-rbt 500 µg

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
2.    

ihl-hmn TCLo:21 mg/m3/3M:PUL,EYE,NOSE

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),199.
3.    

ihl-rat LD50:23 mg/kg

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
4.    

ihl-mus LD50:104 mg/kg

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
5.    

ivn-mus LD50:18 mg/kg

     CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#08842 .
6.    

ivn-rbt LD50:21 mg/kg

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.
7.    

ihl-gpg LD50:6 mg/kg

     AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),194.

Safety Profile

Poison by inhalation and intravenous routes. Human systemic effects by inhalation: lachrymation, deviated nasal septum, and cough. An eye and intense mucous membrane irritant. When heated to decomposition it emits toxic fumes of NOx.

Specification

 4-Morpholinenonylic ,its CAS NO. is 5299-64-9,the synonyms is 1-(4-Morpholino)-1-nonanon ; 1-Nonanone, 1-(4-morpholino)- ; 4-(1-Oxononyl)-morpholin ; 4-(1-Oxononyl)morpholine ; 4-Nonanoyl-morpholin ; 4-Nonanoylmorpholine ; AI 318284 .