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CAS No.: | 53064-79-2 |
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Name: | Iodomethyl pivalate |
Article Data: | 60 |
Molecular Structure: | |
Formula: | C6H11IO2 |
Molecular Weight: | 242.057 |
Synonyms: | IodomethylPivalate;LDO17:Iodomethyl Pivalate;iodomethyl 2,2-dimethylpropanoate; |
EINECS: | 258-339-7 |
Density: | 1.614 g/cm3 |
Melting Point: | 33-35 °C(lit.) |
Boiling Point: | 197.2 °C at 760 mmHg |
Flash Point: | 73.1 °C |
Appearance: | Sight yellow or colorless |
PSA: | 26.30000 |
LogP: | 1.96820 |
Chloromethyl pivalate
iodomethyl pivaloate
Conditions | Yield |
---|---|
With sodium iodide; calcium chloride In ethyl acetate at 78℃; for 6h; | 94% |
With sodium iodide In acetonitrile at 30℃; for 5h; Inert atmosphere; | 86.6% |
With sodium iodide In acetonitrile at 30℃; Inert atmosphere; | 85% |
Conditions | Yield |
---|---|
With sodium iodide In acetone | A 78% B n/a |
Chloromethyl pivalate
iodomethyl pivaloate
Conditions | Yield |
---|---|
In acetonitrile | 75% |
Conditions | Yield |
---|---|
With sodium iodide In hexane; water; acetonitrile | 66% |
Conditions | Yield |
---|---|
With sodium iodide In acetone |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine | 100% |
(6R,7S,Z)-7-(2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(trityloxyimino)acetamido)-8-oxo-3-(trifluoromethylsulfonyloxy)-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid
iodomethyl pivaloate
(6R,7S,Z)-pivaloyloxymethyl 7-(2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(trityloxyimino)acetamido)-8-oxo-3-(trifluoromethylsulfonyloxy)-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate
Conditions | Yield |
---|---|
With tetra-(n-butyl)ammonium iodide; triethylamine In N,N-dimethyl-formamide at 0℃; for 0.833333h; | 100% |
dimethyl 2-benzylidenepropanedioate
iodomethyl pivaloate
dimethyl 2-hydroxymethyl-2-(1-phenyl-2-pivaloyloxyethyl)malonate
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; boron trifluoride diethyl etherate; dimethyl zinc(II) In decane; hexane; dichloromethane at 20℃; for 3h; Cooling with ice; | 99% |
iodomethyl pivaloate
dimethyl 2-(4-chlorobenzylidene)malonate
dimethyl 2-(1-(4-chlorophenyl)-2-pivaloyloxyethyl)-2-hydroxymethylmalonate
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; boron trifluoride diethyl etherate; dimethyl zinc(II) In decane; hexane; dichloromethane at 20℃; for 4h; Cooling with ice; | 99% |
iodomethyl pivaloate
dimethyl 2-(4-methoxybenzylidene)malonate
dimethyl 2-hydroxymethyl-2-(1-(4-methoxyphenyl)-2-pivaloyloxyethyl)malonate
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; boron trifluoride diethyl etherate; dimethyl zinc(II) In decane; hexane; dichloromethane at 20℃; for 4h; Cooling with ice; | 99% |
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IUPAC Name:Iodomethyl 2,2-dimethylpropanoate
Molecular Formula:C6H11IO2
Formula Weight:242.05481g/mol
Melting Point:33-35°C
Boiling Point:211.5°C
EINECS:210-841-7
Index of Refraction:1.506
Molar Refractivity:44.55 cm3
Molar Volume:149.9 cm3
Polarizability:17.66 ×10-24cm3
Surface Tension:34.9 dyne/cm
Density:1.614 g/cm3
Flash Point:73.1 °C
Enthalpy of Vaporization:43.34 kJ/mol
Vapour Pressure:0.383 mmHg at 25°C
Covalently-Bonded Unit Count:1
Synonyms of Iodomethyl pivalate (53064-79-2): Auroraka-7367 ; Iodotoluene(4-) ; Iodomethyl pivalate
Product Categories of Iodomethyl pivalate (53064-79-2):Miscellaneous
Structure of Iodomethyl pivalate (53064-79-2):
It can be used as pharmaceutical intermediates and biochemical reagents.
WGK Germany is 3.