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3282-30-2

Basic Information
CAS No.: 3282-30-2
Name: Pivaloyl chloride
Molecular Structure:
Molecular Structure of 3282-30-2 (Pivaloyl chloride)
Formula: C5H9ClO
Molecular Weight: 120.59
Synonyms: Propanoyl chloride,2,2-dimethyl-;Trimethylacetyl chloride [UN2438] [Poison];Trimethylacetyl chloride;Propanoyl chloride, 2,2-dimethyl-;Trimethylacetychloride;
EINECS: 221-921-6
Density: 1.008 g/cm3
Melting Point: -56 °C
Boiling Point: 107.2 °C at 760 mmHg
Flash Point: 8.9 °C
Solubility: hydrolysis with water
Appearance: colorless to yellow liquid
Hazard Symbols: FlammableF, VeryT+, ToxicT
Risk Codes: 11-14-22-26-34-23
Safety: 16-26-36/37/39-45-38-28A
Transport Information: UN 2438 6.1/PG 1
PSA: 17.07000
LogP: 1.79790
Synthetic route
1634-04-4

tert-butyl methyl ether

106-47-8

4-chloro-aniline

A

65854-91-3

N-(4-chlorophenyl)-2,2-dimethylpropionamide

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With sodium hydroxide In waterA 97%
B n/a
With sodium hydroxide In waterA 97%
B n/a
With sodium hydroxide In waterA 97%
B n/a
With sodium hydroxide In waterA 97%
B n/a
75-98-9

Trimethylacetic acid

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With benzoyl chloride88%
With tetrachlorosilane at 50 - 55℃; for 5h;72%
With thionyl chloride for 24h; Ambient temperature;29%
78114-26-8, 114091-61-1, 63853-15-6

(2,2-dimethyl-1-(trimethylsiloxy)propylidene)-trimethylsilylphosphine

A

3282-30-2

pivaloyl chloride

B

PCl3

PCl3

Conditions
ConditionsYield
With sulfuryl dichlorideA 81%
B n/a
124-63-0

methanesulfonyl chloride

75-98-9

Trimethylacetic acid

A

3282-30-2

pivaloyl chloride

B

1538-75-6

2,2-dimethylpropanoic anhydride

C

C6H12O4S

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃;A 54%
B 5%
C 35%
75-98-9

Trimethylacetic acid

A

3282-30-2

pivaloyl chloride

B

1538-75-6

2,2-dimethylpropanoic anhydride

C

C6H12O4S

Conditions
ConditionsYield
With methanesulfonyl chloride; triethylamine In dichloromethane at 0℃;A 54%
B 5%
C 35%
507-20-0

tertiary butyl chloride

201230-82-2

carbon monoxide

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In trichlorofluoromethane at -45℃; under 37503 Torr; for 1h; Product distribution;50%
507-20-0

tertiary butyl chloride

960

960

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In trichlorofluoromethane at -45℃; under 37503 Torr; for 1h;50%
507-20-0

tertiary butyl chloride

960

960

A

14705-30-7

2,2,5-trimethyl-hex-4-en-3-one

B

36967-88-1

Pivalinsaeure-trifluormethansulfonsaeure-anhydrid

C

3282-30-2

pivaloyl chloride

D

HCl

HCl

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In tetrachloromethane at -25℃; under 56254.5 Torr; for 1h;A n/a
B n/a
C 47%
D n/a
507-20-0

tertiary butyl chloride

1493-13-6

trifluorormethanesulfonic acid

960

960

A

14705-30-7

2,2,5-trimethyl-hex-4-en-3-one

B

36967-88-1

Pivalinsaeure-trifluormethansulfonsaeure-anhydrid

C

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
In tetrachloromethane at -25℃; under 56254.5 Torr; for 1h;A n/a
B n/a
C 47%
18243-80-6

trichloro-pivaloyloxy-silane

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
at 159 - 161℃;
98-88-4

benzoyl chloride

75-98-9

Trimethylacetic acid

3282-30-2

pivaloyl chloride

79-37-8

oxalyl dichloride

75-98-9

Trimethylacetic acid

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With hexane
75-97-8

3,3-dimethyl-butan-2-one

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With thionyl chloride 1) pyridin, 2) heating; Yield given. Multistep reaction;
With pyridine; thionyl chloride for 48h; Heating;
507-20-0

tertiary butyl chloride

201230-82-2

carbon monoxide

A

14705-30-7

2,2,5-trimethyl-hex-4-en-3-one

B

36967-88-1

Pivalinsaeure-trifluormethansulfonsaeure-anhydrid

C

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In tetrachloromethane at -25℃; under 56254.5 Torr; for 1h; Product distribution;
50694-27-4

2,2-dimethyl-propionyl

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With tetrachloromethane In hexane at 22.9℃; Rate constant;
507-20-0

tertiary butyl chloride

carbon monoxide

carbon monoxide

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With boron trifluoride at 0 - 25℃; under 532000 Torr;
115-11-7

isobutene

carbon monoxide

carbon monoxide

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With hydrogenchloride; boron trifluoride at 0 - 25℃; under 532000 Torr;
trimethylacetate_of sodium

trimethylacetate_of sodium

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With trichlorophosphate
3938-95-2

2,2-dimethyl-propanoic acid ethyl ester

10294-34-5

boron trichloride

A

16339-28-9

ethoxy-dichloroborane

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
at -80℃; Erhitzen des Reaktionsprodukts bei 120grad;
7719-09-7

thionyl chloride

75-98-9

Trimethylacetic acid

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
In dichloromethane at 25℃; for 12h;
69151-13-9

C3Cl2(C3H7)2

75-98-9

Trimethylacetic acid

A

877675-72-4

2,3-diisopropylcyclopropenone

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 0.0833333h; Inert atmosphere;A 61.6 mg
B n/a
368-44-5

dichloro(fluoro)(phenyl)silane

1538-75-6

2,2-dimethylpropanoic anhydride

A

1344680-35-8

PhSiFClOC(O)C(CH3)3

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
at 20℃;
630-19-3

pivalaldehyde

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With trichloroisocyanuric acid In dichloromethane at 20℃; for 120h; Inert atmosphere;
With trichloroisocyanuric acid In dichloromethane at 20℃; Inert atmosphere;
With trichloroisocyanuric acid In dichloromethane at 20℃; Inert atmosphere;
With trichloroisocyanuric acid In dichloromethane at 20℃; for 4h; Wavelength; Inert atmosphere; Irradiation;
50-99-7

D-glucose

2857-97-8

trimethylsilyl bromide

A

81058-27-7

2,3,4,6-tetra-O-pivaloyl-α-D-glucopyranosyl bromide

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
In dichloromethane
In dichloromethane
In dichloromethane
97-30-3

methyl-alpha-D-glucopyranoside

A

81058-27-7

2,3,4,6-tetra-O-pivaloyl-α-D-glucopyranosyl bromide

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With sodium bromide In dichloromethane
50-99-7

D-glucose

A

(2R,3R,4S,5R,6R)-2-chloro-6-(pivaloyloxymethyl)tetrahydro-2H-pyran-3,4,5-triyl tris(2,2-dimethylpropanoate)

B

3282-30-2

pivaloyl chloride

50-99-7

D-glucose

A

81058-27-7

2,3,4,6-tetra-O-pivaloyl-α-D-glucopyranosyl bromide

B

3282-30-2

pivaloyl chloride

Conditions
ConditionsYield
With sodium bromide In dichloromethane
53-16-7

Estrone

3282-30-2

pivaloyl chloride

4003-22-9

(8R,9S,13S,14S)-13-methyl-17-oxo-7,8,9,11,12,13,14,15,16,17-decahydro-6H-cyclopenta[a]phenanthren-3-yl pivalate

Conditions
ConditionsYield
With triethylamine In chloroform100%
With dmap; triethylamine In dichloromethane at 0℃; for 0.3h; Inert atmosphere;96%
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere; Sealed tube;87%
3282-30-2

pivaloyl chloride

100-46-9

benzylamine

26209-45-0

N-benzyl-2,2-dimethylpropanamide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 1h;100%
With triethylamine In dichloromethane at 0 - 20℃; for 4h; Inert atmosphere;100%
With 1-methyl-1H-imidazole In dichloromethane at 0℃; Inert atmosphere;99%
109-86-4

2-methoxy-ethanol

3282-30-2

pivaloyl chloride

36584-85-7

2-methoxyethyl pivalate

Conditions
ConditionsYield
at 20℃; for 0.0833333h; Neat (no solvent);100%
With lanthanum(III) nitrate at 20℃; for 0.25h;93%
In pyridine; benzene for 2h; Heating;
With pyridine In diethyl ether Heating;
3282-30-2

pivaloyl chloride

134-20-3

2-carbomethoxyaniline

84540-62-5

methyl N-trimethylacetylanthranilate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 16h;100%
With potassium carbonate In benzene Heating;98%
With triethylamine In benzene for 1h; Heating;
With triethylamine In dichloromethane at 0 - 20℃;
3282-30-2

pivaloyl chloride

14630-40-1

Bis(trimethylsilyl)ethyne

53723-94-7

3-tert-butyl-1-(trimethylsilyl)pent-1-yn-3-one

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; for 4.25h; Inert atmosphere; Schlenk technique;100%
With aluminum (III) chloride In pentane at 0℃; Friedel Crafts acylation;98%
With aluminium trichloride
With aluminium trichloride In dichloromethane at 0 - 20℃; for 4h; Acylation;
504-29-0

2-aminopyridine

3282-30-2

pivaloyl chloride

86847-59-8

2-(pivaloylamino)pyridine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 2h;100%
With triethylamine In dichloromethane at 0 - 20℃; for 18h;100%
With triethylamine In dichloromethane at 0℃; for 2h;100%
1824-81-3

2-Amino-6-methylpyridine

3282-30-2

pivaloyl chloride

86847-79-2

2,2-dimethyl-N-(6-methylpyridin-2-yl)propanamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 24h; Inert atmosphere;100%
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;99%
Stage #1: 2-Amino-6-methylpyridine With triethylamine In dichloromethane at 0℃; Inert atmosphere;
Stage #2: pivaloyl chloride In dichloromethane at 0 - 20℃; Inert atmosphere;
96%
1072-98-6

5-chloro-2-pyridylamine

3282-30-2

pivaloyl chloride

86847-83-8

N-(5-Chloro-pyridin-2-yl)-2,2-dimethylpropanamide

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃;100%
With triethylamine In dichloromethane at 0 - 20℃; for 1.08333h;99%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 0 - 20℃; for 1h;97%
6298-19-7

2-chloro-3-aminopyridine

3282-30-2

pivaloyl chloride

109902-33-2

N-2-chloropyrid-3-yl-trimethylacetamide

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 5℃; Acylation;100%
With triethylamine In tetrahydrofuran; diethyl ether90%
With triethylamine In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere; Schlenk technique;83%
580-22-3

2-aminoquinoline

3282-30-2

pivaloyl chloride

107170-67-2

N-(quinolin-2-yl)tert-butylcarboxamide

Conditions
ConditionsYield
With dmap; triethylamine In dichloromethane at 0 - 20℃;100%
91%
With triethylamine In diethyl ether for 2h; Ambient temperature;91%
41324-11-2

1,4-dihydroxy-hex-5-ene

3282-30-2

pivaloyl chloride

158355-62-5

4-hydroxy-hex-5-enyl pivalate

Conditions
ConditionsYield
In pyridine; dichloromethane100%
17618-04-1

2,5-di-O-benzyl-D-mannitol

3282-30-2

pivaloyl chloride

114934-96-2

2,5-di-O-benzyl-1,6-bis-O-(2,2-dimethyl-propionyl)-D-mannitol

Conditions
ConditionsYield
With pyridine at -17℃; for 1.5h;100%
2923-28-6

silver trifluoromethanesulfonate

3282-30-2

pivaloyl chloride

145324-63-6

2-benzyl-5-methylpyrazole 1-oxide

145612-97-1

2-benzyl-1-(2,2-dimethylpropanoyloxy)-5-methylpyrazolium triflate

Conditions
ConditionsYield
In dichloromethane a) -40 deg C, 0.5 h, b) 0 deg C, 0.5 h;100%
119274-25-8, 119363-74-5

(2R,3R,4S,5S)-4-<(1S)-1-(hydroxymethyl)ethyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

3282-30-2

pivaloyl chloride

(2R,3R,4S,5S)-2,3-(isopropylidenedioxy)-5-<(R)-1,2-(isopropylidenedioxy)ethyl>-4-<(S)-1-methyl-2-(pivaloyloxy)ethyl>-4-vinyltetrahydrofuran

Conditions
ConditionsYield
With pyridine for 3h; Ambient temperature;100%

5-Azido-3,6-di-O-benzyl-5-deoxy-D-glucitol

3282-30-2

pivaloyl chloride

5-Azido-3,6-di-O-benzyl-5-deoxy-1-O-pivaloyl-D-glucitol

Conditions
ConditionsYield
With pyridine 1) -40 deg C, 1h, 2) r.t., 1.5h;100%
3282-30-2

pivaloyl chloride

536-90-3

m-Anisidine

56619-93-3

N-(3-methoxyphenyl)pivalamide

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 0℃; for 1h;100%
With sodium carbonate monohydrate In water; ethyl acetate at 0℃; for 1h; Inert atmosphere;99.5%
With sodium carbonate monohydrate In water; ethyl acetate at 0℃; for 1h; Inert atmosphere;99.5%
3282-30-2

pivaloyl chloride

90-04-0

2-methoxy-phenylamine

33768-49-9

N-(2-methoxyphenyl)pivalamide

Conditions
ConditionsYield
With sodium hydrogencarbonate In water; ethyl acetate at 20℃; for 6h;100%
With sodium carbonate In dichloromethane Ambient temperature;98%
With triethylamine In diethyl ether for 16h; Ambient temperature;98%
3282-30-2

pivaloyl chloride

131656-82-1

((4-hydroxy-3-methoxyphenyl)acetyl)pyrrolidine

131656-83-2

((3-methoxy-4-(pivaloyloxy)phenyl)acetyl)pyrrolidine

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane Ambient temperature;100%
3282-30-2

pivaloyl chloride

134614-96-3

(2R,3R,4R,5R)-2-Hydroxymethyl-5-methylsulfanyl-4-phenyl-tetrahydro-furan-3-ol

134615-03-5

2,2-Dimethyl-propionic acid (2R,3R,4R,5R)-3-hydroxy-5-methylsulfanyl-4-phenyl-tetrahydro-furan-2-ylmethyl ester

Conditions
ConditionsYield
With pyridine100%
3282-30-2

pivaloyl chloride

134614-95-2

Acetic acid (2R,3R,4R,5R)-4-hydroxy-5-hydroxymethyl-2-phenylsulfanyl-tetrahydro-furan-3-ylmethyl ester

134615-01-3

2,2-Dimethyl-propionic acid (2R,3R,4R,5R)-4-acetoxymethyl-3-hydroxy-5-phenylsulfanyl-tetrahydro-furan-2-ylmethyl ester

Conditions
ConditionsYield
With pyridine100%
3282-30-2

pivaloyl chloride

135030-15-8

(3R,4R,5R)-6-Benzyloxy-3,5-dimethyl-hexane-1,4-diol

135030-16-9

2,2-Dimethyl-propionic acid (3R,4R,5R)-6-benzyloxy-4-hydroxy-3,5-dimethyl-hexyl ester

Conditions
ConditionsYield
With pyridine100%
3282-30-2

pivaloyl chloride

132592-07-5

(2S,4S)-4-hydroxy-1,2-pyrrolidinedicarboxylic acid 1,2-bis(phenylmethyl ester)

132591-97-0

(2S,4S)-4-(pivaloyloxy)-1,2-pyrrolidinedicarboxylic acid 1,2-bis(phenylmethyl ester)

Conditions
ConditionsYield
With dmap In dichloromethane at 0℃; for 1h;100%
3282-30-2

pivaloyl chloride

87862-83-7

3-amino>-2-<3,4-(methylenedioxy)phenyl>-2-cyclopenten-1-one

N-<(ethoxycarbonyl)methyl>-N-methyl-N-<3-(pivaloyloxy)-2-<3,4-(methylenedioxy)phenyl>cyclopent-2-enylidene>ammonium perchlorate

Conditions
ConditionsYield
With silver perchlorate In acetonitrile 1. 0 deg C 2. 30 min 0 deg C, 30 min 25 deg C;100%
3282-30-2

pivaloyl chloride

139963-96-5, 139964-01-5, 139964-02-6, 139964-04-8

(2S,4R)-4-hydroxy-1-methoxycarbonyl-5-methoxy-2-pyrrolidinecarboxylate

(2S,4R)-4-(2,2-Dimethyl-propionyloxy)-5-methoxy-pyrrolidine-1,2-dicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With dmap100%
3282-30-2

pivaloyl chloride

C6H5Cu*ILi

938-16-9

2,2-dimethylpropiophenone

Conditions
ConditionsYield
With lithium iodide In various solvent(s) -78 deg C, 1 h, -78-0 deg C, 1 h;100%
3282-30-2

pivaloyl chloride

86943-03-5

3-[Methyl-(1-triethylsilanyl-allyl)-amino]-cyclopent-2-enone

[3-(2,2-Dimethyl-propionyloxy)-cyclopent-2-en-(Z)-ylidene]-methyl-(1-triethylsilanyl-allyl)-ammonium; perchlorate

Conditions
ConditionsYield
With silver perchlorate In acetonitrile100%
3282-30-2

pivaloyl chloride

86943-04-6

3-[Methyl-(1-triethylsilanyl-allyl)-amino]-cyclohex-2-enone

[3-(2,2-Dimethyl-propionyloxy)-cyclohex-2-en-(Z)-ylidene]-methyl-(1-triethylsilanyl-allyl)-ammonium; perchlorate

Conditions
ConditionsYield
With silver perchlorate In acetonitrile100%
3282-30-2

pivaloyl chloride

105-13-5

4-Methoxybenzyl alcohol

2,2-dimethylpropionic acid, 4-methoxybenzyl ester

Conditions
ConditionsYield
at 20℃; for 0.0833333h; Neat (no solvent);100%
With lanthanum(III) nitrate at 20℃; for 0.166667h;90%
With pyridine In diethyl ether for 2h; Reflux; Inert atmosphere;85%
With pyridine In benzene Ambient temperature;
3282-30-2

pivaloyl chloride

(1R*,5R*,6S*)-6-hydroxy-8-oxabicyclo<3.2.1>octan-3-one

(1R*,5R*,6S*)-6-pivaloyloxy-8-oxabicyclo<3.2.1>octan-3-one

Conditions
ConditionsYield
With pyridine at 20℃; for 12h;100%
3282-30-2

pivaloyl chloride

119100-05-9

3-deoxy-3-C-hydroxymethyl-1,2:5,6-di-O-isopropylidene-α-D-gulofuranose

119137-60-9

3-deoxy-1,2:5,6-di-O-isopropylidene-3-C-<(pivaloyloxy)methyl>-α-D-gulofuranose

Conditions
ConditionsYield
With dmap In dichloromethane at 25℃; for 0.666667h;100%
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    Pivaloyl chloride

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

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    3282-30-2

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    3282-30-2

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    Product Name Pivaloyl chloride Synonyms Pivaloyl chloride;Trimethylacetyl chloride CAS: 3282-30-2 MF: - MW: - EINECS:

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    3282-30-2

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    3282-30-2

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    3282-30-2

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    Trimethylacetyl chloride Product Name: Trimethylacetyl chloride Molecular Weight: 120.58 CAS NO: 3282-30-2 EC NO: 221-921-6

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    3282-30-2

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    3282-30-2

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    3282-30-2

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    3282-30-2

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    3282-30-2

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    Min.Order: 1 Metric Ton

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    Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Com

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    3282-30-2

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  • Casno:

    3282-30-2

    Acetyl chloride, trimethyl-

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    FOB Price:  USD $ 2200.0-2400.0/Kilogram

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    Business Type:Lab/Research institutions

    Tel:+8615630194059

    Address:LB BLDG,Qiaoxi district,Shijiazhuang,china

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    3282-30-2

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    Min.Order: 1 Kilogram

    FOB Price:  USD $ 1.0-9999.0/Kilogram

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    Business Type:Other

    Tel:+86 021 61559630

    Address:No.7-9,Guanghua St.,Zhonglou District,Changzhou,China

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    3282-30-2

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    Product Name: Pivaloyl chloride Synonyms: 2,2-dimethyl-propanoylchlorid;Acetyl chloride, trimethyl-;Neopantanoyl chloride;Pivalolyl chloride;pivaloyl;PIVALOYL CHLORIDE(PVCL);Pivaloyl chloride(Trimethylacetyl chloride);Primethyl

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    Address:Building 3 of Innovation Park, East District of the National University Science Park

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    3282-30-2

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    Business Type:Lab/Research institutions

    Tel:+86-371-65511936

    Address:NO.56,Hongzhuan Road

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    3282-30-2

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-87396432

    Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China

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    3282-30-2

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-15988566987

    Address:Room1701, Tianxing Building,Licheng district, jinan, Shandong, China

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    3282-30-2

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    Min.Order: 1 Gram

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    Address:46# zhongshan road, quzhou zhejiang

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    3282-30-2

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86 592 605 6448

    Address:No.31 Pingshan South Road, HaiCang District, Xiamen, China

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    3282-30-2

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    3282-30-2

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    Address:Dalian Rd 950th

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    3282-30-2

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    3282-30-2

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    Pivaloyl chloride Basic information Product Name: Pivaloyl chloride Synonyms: 2,2-dimethyl-propanoylchlorid;Acet

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    Business Type:Lab/Research institutions

    Tel:86-371-55170693/55170694

    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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    3282-30-2

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    Address:32 Room, 5th Floor, Building 11, No. 6 Yinxing Road, High-tech Industrial Development Zone, Zhengzhou City, Henan Province

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    3282-30-2

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    Product name: Pivaloyl Chloride CAS No.:3282-30-2 Molecule Formula:C5H9ClO Molecule Weight:120.58 Purity: 99.0% Package: 200kg/drum Description:Transparent oily liquid Manufacture Standards:Enterprise Standard TEST

    Siwei Development Group Ltd. is a reputed professional enterprise in China dedicated to the Amino Acids production and sales of fine chemical products.Over the years we have been m

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    3282-30-2

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    Ality Group, established in 2007, is a comprehensive Chemical Supply Group with Patent Technology as its core. Ality Group operates branches in Hong Kong, Singapore and mainland Ch

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    3282-30-2

    Pivaloyl chloride

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    Shandong Bolode BIO-Technology Co.LTD is a professional company which engaged in the R&D and manufacture of Pharmaceuticals intermediates and Chemical Raw materials. The company is

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-0531-58966870

    Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China

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Chemistry

Molecule structure of Pivaloyl chloride (CAS NO.3282-30-2):
 
IUPAC Name: 2,2-Dimethylpropanoyl chloride 
Molecular Weight: 120.57736 g/mol
Molecular Formula: C5H9ClO 
Density: 1.008 g/cm3 
Melting Point: -56 °C
Boiling Point: 107.2 °C at 760 mmHg 
Flash Point: 8.9 °C
Index of Refraction: 1.416
Molar Refractivity: 30.05 cm3
Molar Volume: 119.6 cm3
Surface Tension: 25.8 dyne/cm 
Enthalpy of Vaporization: 34.6 kJ/mol
Vapour Pressure: 27.4 mmHg at 25 °C
Storage Temp.: store at RT.
Water Solubility: hydrolysis
Sensitive: moisture sensitive
XLogP3-AA: 2.2
H-Bond Acceptor: 1
Rotatable Bond Count: 1
Exact Mass: 120.034193
MonoIsotopic Mass: 120.034193
Topological Polar Surface Area: 17.1
Heavy Atom Count: 7
Canonical SMILES: CC(C)(C)C(=O)Cl
InChI: InChI=1S/C5H9ClO/c1-5(2,3)4(6)7/h1-3H3
InChIKey: JVSFQJZRHXAUGT-UHFFFAOYSA-N
EINECS: 221-921-6

Uses

 Pivaloyl chloride (CAS NO.3282-30-2) is used as acylating agent for the production of drugs such as ampicillin and cephalexin. It is also used for medicine and pesticide intermediates.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: FlammableF, VeryT+, ToxicT
Risk Statements: 11-14-22-26-34-23 
R11:Highly flammable. 
R14 :Reacts violently with water. 
R22:Harmful if swallowed. 
R26:Very toxic by inhalation. 
R34:Causes burns. 
R23 :Toxic by inhalation.
Safety Statements: 16-26-36/37/39-45-38-28A 
S16:Keep away from sources of ignition. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S38:In case of insufficient ventilation, wear suitable respiratory equipment. 
S28:After contact with skin, wash immediately with plenty of soap-suds.
RIDADR: UN 2438 6.1/PG 1
WGK Germany: 1
F: 9-19
HazardClass: 6.1
PackingGroup: I
HS Code: 29159080
A corrosive irritant to skin, eyes, and mucous membranes. The liquid is flammable when exposed to heat, flame, or oxidizers. When heated to decomposition it emits toxic fumes of Cl.

Standards and Recommendations

DOT Classification:  8; Label: Corrosive, Flammable Liquid, Poison

Specification

 Pivaloyl chloride (CAS NO.3282-30-2) is also named as 2,2-Dimethylpropanoyl chloride ; Propanoyl chloride, 2,2-dimethyl- ; Trimethylacetyl chloride ; UN2438 . Pivaloyl chloride (CAS NO.3282-30-2) is colorless to yellow liquid with a pungent odor. It is very toxic by inhalation, ingestion or skin absorption. Fumes irritate the eyes and mucous membranes. Corrosive to most metals and tissue. It is highly flammable. Reacts vigorously and exothermically with water to form trimethylacetic acid and corrosive hydrochloric acid; both acids corrode metals and tissue. Pivaloyl chloride is acidic and incompatible with bases (including amines), strong oxidizing agents, and alcohols. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts. May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated.