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5518-52-5

Basic Information
CAS No.: 5518-52-5
Name: Phosphine,tri-2-furanyl-
Molecular Structure:
Molecular Structure of 5518-52-5 (Phosphine,tri-2-furanyl-)
Formula: C12H9O3P
Molecular Weight: 232.17
Synonyms: Phosphine,tri-2-furyl- (7CI,8CI);Tri-2-furanylphosphine;Tri-2-furylphosphine;Tris(2-furanyl)phosphine;Tris(2-furyl)phosphine;Tris(o-furyl)phosphine;Tri(2-furyl)phosphine;
EINECS: 628-036-8
Density:
Melting Point: 59-64 °C(lit.)
Boiling Point: 286.4 °C at 760 mmHg
Flash Point: 127 °C
Solubility:
Appearance: white to light yellow crystal powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-24/25
Transport Information:
PSA: 53.01000
LogP: 2.22380
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Chemistry


Systematic Name: Trifuran-2-ylphosphane 
SMILES: o1cccc1P(c2occc2)c3occc3  
InChI: InChI=1/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H  
InChIKey: DLQYXUGCCKQSRJ-UHFFFAOYAK 
Empirical Formula: C12H9O3
Molecular Weight: 232.1718 
color: faintly brown 
Melting Point: 59-64 °C(lit.)
Flash Point:  127 °C 
Enthalpy of Vaporization:  50.44 kJ/mol 
Boiling Point:  286.4 °C at 760 mmHg 
Vapour Pressure:  0.00456 mmHg at 25 °C 
Product Categories of Phosphine,tri-2-furanyl- (CAS NO.5518-52-5): Ligand; Phosphine Ligands; Synthetic Organic Chemistry; Catalysis and Inorganic Chemistry; Phosphine Ligands; Phosphorus Compounds 

Uses

 A phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements of Phosphine,tri-2-furanyl- (CAS NO.5518-52-5): 26-24/25 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3

Specification

 Phosphine,tri-2-furanyl- (CAS NO.5518-52-5), its Synonyms are Tri(2-furyl)phosphine ; Tri-(2-furyl)phosphine ; Tris(2-furyl)phosphine ; Tri-2-furylphosphine ; Tris-furan-2-yl-phosphine . It is white to light yellow crystal powder.