CAS No.556-33-2,Glycyl-glycyl-glycine Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	556-33-2
Name:	Glycyl-glycyl-glycine
Article Data:	39

Formula:	C₆H₁₁N₃O₄
Molecular Weight:	189.171
Synonyms:	Glycylglycylglycine;gly-l-gly-l-gly;N-(N-Glycylglycyl)glycine;
EINECS:	209-122-0
Density:	1.373 g/cm³
Melting Point:	240-250 °C
Boiling Point:	638.8 °C at 760 mmHg
Flash Point:	340.1 °C
Solubility:	H₂O: 0.5 M at 20 °C, clear, colorless
Appearance:	white crystalline powder
PSA:	121.52000
LogP:	-1.25580

Synthetic route

: 15028-44-1
DL-phenylalanine methyl ester

: 75719-94-7
1-O-(glycylglycylglycyl)-β-D-glucopyranose

A: 556-33-2
glycine-glycine-glycine

B: 84814-47-1
glycylglycylglycyl-D,L-phenylalanine methyl ester

Conditions

Conditions	Yield
With 4-methyl-morpholine In N,N-dimethyl-formamide at 38℃; for 72h;	A 67% B 92%
With 4-methyl-morpholine In N,N-dimethyl-formamide at 38℃; for 72h;	A 67% B 28%

...Expand

: 2566-20-3
[2-(2-Benzyloxycarbonylamino-acetylamino)-acetylamino]-acetic acid

: 556-33-2
glycine-glycine-glycine

Conditions

Conditions	Yield
With acetic acid In methanol Ambient temperature; electrolysis: palladium/graphite cathode, -0.6 V to -1.0 V SCE, current density = 15 mA/cm2, catholyte: NaClO4;	90%
With cell extract of Sphingomonas paucimobilis SC 16113 In water at 42℃; for 20h; Enzymatic reaction;	23 % Chromat.

: tetrabutylphosphonium glycinate

: 5680-79-5
glycine ethyl ester hydrochloride

: 556-33-2
glycine-glycine-glycine

Conditions

Conditions	Yield
Stage #1: tetrabutylphosphonium glycinate for 3h; Inert atmosphere; Stage #2: glycine ethyl ester hydrochloride In chloroform at 60℃; for 24h; Stage #3: With acetic acid In chloroform at 20℃; for 10h;	66%

: 56-40-6
glycine

A: 556-33-2
glycine-glycine-glycine

B: 7365-83-5
N-carbamoylmethyl-glycine

C: 598-41-4
H-Gly-NH2

Conditions

Conditions	Yield
With 1,2,4-Triazole; Sodium trimetaphosphate; magnesium chloride In water for 20h; Ambient temperature; var.reag.: pyrrole, pyrrolidine, pyrrazole, imidazole, tetrazole, adenine,quanine, thyamine, uracile, adenosine, quanosine,thymidine, uridine and add of MgCl2: var. pH, time and temp.;	A 5.5% B 23.6% C 3.2%

...Expand

: 15474-96-1
chloroacetyldiglycine

A: 106-57-0
Glycine anhydride

B: 556-33-2
glycine-glycine-glycine

Conditions

Conditions	Yield
With ammonia; water at 25℃;

: 27440-17-1
N-carboxy-glycyl=>glycyl=>glycine

: 556-33-2
glycine-glycine-glycine

Conditions

Conditions	Yield
With borax; sodium dihydrogenphosphate at 26℃; Equilibrium constant;

: 75719-95-8
1-O-(glycylglycylglycyl)-β-D-glucopyranose mono-oxalate

A: 492-61-5
β-D-glucose

B: 556-33-2
glycine-glycine-glycine

Conditions

Conditions	Yield
With β-D-glucosidase; nitrate buffer In water at 37℃; for 6h;

: 75719-94-7
1-O-(glycylglycylglycyl)-β-D-glucopyranose

A: 492-61-5
β-D-glucose

B: 556-33-2
glycine-glycine-glycine

Conditions

Conditions	Yield
In water for 96h; decompn. with/without 0.1M HCl;

: 56-40-6
glycine

A: 556-33-2
glycine-glycine-glycine

B: 637-84-3
tetraglycine

C: 7093-67-6
pentaglycine

D: 556-50-3
glycylglycine

Conditions

Conditions	Yield
titanium(IV) oxide In water for 24h; Product distribution; Irradiation; reactions between var. conditions and with var. semiconductor photocatalysts with and without platinization;	A 0.00021 mmol B 0.00018 mmol C 0.00010 mmol D 0.01026 mmol

...Expand

: 56-40-6
glycine

A: 556-33-2
glycine-glycine-glycine

B: 556-50-3
glycylglycine

Conditions

Conditions	Yield
With copper dichloride In water at 80 - 90℃; Mechanism; Product distribution; Rate constant; other alkali and alkaline-earth-metal cations;
Cu(2+)-doted montmorillonite In water at 80℃; Product distribution; evaporation during 24 h, 4-5 cycles; also by constant volume; natural montmorillonite as catalyst, diglycine as substrate, other products;

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Specification

The Glycine, glycylglycyl-, with CAS registry number 556-33-2, belongs to the following product categories: (1)Biochemistry; (2)Oligopeptides; (3)Peptide Synthesis. It has the systematic name of glycylglycylglycine. This chemical is a kind of white crystalline powder. And it should be stored at the temperature of 2-8°C. What's more, its EINECS is 209-122-0.

Physical properties of Glycine, glycylglycyl-: (1)ACD/LogP: -2.04; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -4.53; (4)ACD/LogD (pH 7.4): -5.02; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 7; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 70.16 Å²; (13)Index of Refraction: 1.524; (14)Molar Refractivity: 42.19 cm³; (15)Molar Volume: 137.7 cm³; (16)Polarizability: 16.72×10^-24cm³; (17)Surface Tension: 62.7 dyne/cm; (18)Density: 1.373 g/cm³; (19)Flash Point: 340.1 °C; (20)Enthalpy of Vaporization: 102.93 kJ/mol; (21)Boiling Point: 638.8 °C at 760 mmHg; (22)Vapour Pressure: 5.82E-18 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(NCC(=O)O)CNC(=O)CN
(2)InChI: InChI=1/C6H11N3O4/c7-1-4(10)8-2-5(11)9-3-6(12)13/h1-3,7H2,(H,8,10)(H,9,11)(H,12,13)
(3)InChIKey: XKUKSGPZAADMRA-UHFFFAOYAU
(4)Std. InChI: InChI=1S/C6H11N3O4/c7-1-4(10)8-2-5(11)9-3-6(12)13/h1-3,7H2,(H,8,10)(H,9,11)(H,12,13)
(5)Std. InChIKey: XKUKSGPZAADMRA-UHFFFAOYSA-N