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| CAS No.: | 58-36-6 |
|---|---|
| Name: | 10,10-Oxybisphenoxarsine |
| Molecular Structure: | |
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| Formula: | C24H16As2O3 |
| Molecular Weight: | 502.232 |
| Synonyms: | Phenoxarsine,10,10'-oxydi- (6CI,7CI,8CI);10,10'-Bis(phenoxarsinyl) oxide;10,10'-Oxidiphenoxarsine;10,10'-Oxybisphenoxarsine;Bis(10-phenoxarsyl) oxide;Bis(phenoxarsin-10-yl) ether;10H-Phenoxarsine, 10,10'-oxybis-;SA 546;Vinadine;Vinyzene(pesticide);Vinyzene BP 5;Vinyzene BP 5-2DIDP;Vinyzene BP505;Vinyzene SB 1PR; |
| EINECS: | 200-377-3 |
| Density: | 1.40-1.42 |
| Melting Point: | 180-184 °C |
| Boiling Point: | 531.3 °C at 760 mmHg |
| Flash Point: | 214.1 °C |
| Solubility: | Insoluble in water and slightly denser than water |
| Appearance: | clear light yellow liquid with a mild odor |
| Transport Information: | UN 1557 6.1/PG 2 |
| PSA: | 27.69000 |
| LogP: | 2.82620 |
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| Conditions | Yield |
|---|---|
| With water In acetone | A 83.8% B 93.9% |
- 55369-40-9
10-sec-butyl-10H-phenoxarsine
- 58-36-6
10,10,oxybisphenoxarsine
| Conditions | Yield |
|---|---|
| With oxygen |
| Conditions | Yield |
|---|---|
| (i) AsCl3, (ii) O2; Multistep reaction; |
- 39548-42-0
10-allylphenoxarsine
- 58-36-6
10,10,oxybisphenoxarsine
| Conditions | Yield |
|---|---|
| With oxygen |
- 39548-35-1
10-tert-butylphenoxarsine
- 58-36-6
10,10,oxybisphenoxarsine
| Conditions | Yield |
|---|---|
| With ethanol |
- 58-36-6
10,10,oxybisphenoxarsine
| Conditions | Yield |
|---|---|
| With ethanol; ammonia |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: toluene; diethyl ether 2: O2 View Scheme | |
| Multi-step reaction with 2 steps 1: benzene; diethyl ether 2: O2 View Scheme | |
| Multi-step reaction with 2 steps 1: toluene; diethyl ether 2: aq. EtOH View Scheme |
| Conditions | Yield |
|---|---|
| In toluene Heating; | 80.8% |
| Conditions | Yield |
|---|---|
| In toluene Heating; | 71.5% |
| Conditions | Yield |
|---|---|
| In toluene for 5h; Heating; | 66% |
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Specification
The 10,10-Oxybisphenoxarsine, with the CAS registry number 58-36-6, is also known as Bis(phenoxarsin-10-yl) ether. It belongs to the product categories of Industrial/Fine Chemicals. Its EINECS number is 200-377-3. This chemical's molecular formula is C24H16As2O3 and molecular weight is 502.23. What's more, its systematic name is 10,10'-oxybis(10H-phenoxarsinine). Its classification code is Skin / Eye Irritant. It is a new kind of industrial mould inhibitor. It is mouldproof and antibacterial, and is one of the most effective antimicrobial in industrial fields. It can be used as an antimicrobial add to the PVC products, plastic products, PVC flooring, metope paint and so on.
Physical properties of 10,10-Oxybisphenoxarsine are: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 2; (4)Polar Surface Area: 27.69 Å2; (5)Flash Point: 214.1 °C; (6)Enthalpy of Vaporization: 77.65 kJ/mol; (7)Boiling Point: 531.3 °C at 760 mmHg; (8)Vapour Pressure: 7.77E-11 mmHg at 25°C.
You can still convert the following datas into molecular structure:
(1)SMILES: O5c1c(cccc1)[As](O[As]2c4ccccc4Oc3c2cccc3)c6ccccc56
(2)Std. InChI: InChI=1S/C24H16As2O3/c1-5-13-21-17(9-1)25(18-10-2-6-14-22(18)27-21)29-26-19-11-3-7-15-23(19)28-24-16-8-4-12-20(24)26/h1-16H
(3)Std. InChIKey: VCRZAKVGPJFABU-UHFFFAOYSA-N
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| bird - wild | LD50 | oral | 24mg/kg (24mg/kg) | Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972. | |
| guinea pig | LCLo | inhalation | 141mg/m3/2H (141mg/m3) | Toxicology. Vol. 10, Pg. 341, 1978. | |
| guinea pig | LD50 | oral | 24mg/kg (24mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Toxicology. Vol. 10, Pg. 341, 1978. |
| mouse | LDLo | oral | 42mg/kg (42mg/kg) | Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985. | |
| rat | LD50 | oral | 40mg/kg (40mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION SKIN AND APPENDAGES (SKIN): HAIR: OTHER | Toxicology. Vol. 10, Pg. 341, 1978. |