CAS No.58-36-6,10,10-Oxybisphenoxarsine Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	58-36-6
Name:	10,10-Oxybisphenoxarsine

Formula:	C₂₄H₁₆As₂O₃
Molecular Weight:	502.23
Synonyms:	Phenoxarsine,10,10'-oxydi- (6CI,7CI,8CI);10,10'-Bis(phenoxarsinyl) oxide;10,10'-Oxidiphenoxarsine;10,10'-Oxybisphenoxarsine;Bis(10-phenoxarsyl) oxide;Bis(phenoxarsin-10-yl) ether;10H-Phenoxarsine, 10,10'-oxybis-;SA 546;Vinadine;Vinyzene(pesticide);Vinyzene BP 5;Vinyzene BP 5-2DIDP;Vinyzene BP505;Vinyzene SB 1PR;
EINECS:	200-377-3
Density:	1.40-1.42
Melting Point:	180-184 °C
Boiling Point:	531.3 °C at 760 mmHg
Flash Point:	214.1 °C
Solubility:	Insoluble in water and slightly denser than water
Appearance:	clear light yellow liquid with a mild odor
Hazard Symbols:
Risk Codes:
Safety:
Transport Information:	UN 1557 6.1/PG 2
PSA:	27.69000
LogP:	2.82620

Synthetic route

: 10-<2-chloro-1-(chloromethyl)ethoxy>phenoxarsine

A: 96-23-1
1,3-Dichloro-2-propanol

B: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
With water In acetone	A 83.8% B 93.9%

: 55369-40-9
10-sec-butyl-10H-phenoxarsine

: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
With oxygen

: 101-84-8
diphenylether

: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
(i) AsCl3, (ii) O2; Multistep reaction;

: 39548-42-0
10-allylphenoxarsine

: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
With oxygen

: 39548-35-1
10-tert-butylphenoxarsine

: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
With ethanol

phenoxarsine chloride: phenoxarsine chloride

: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
With ethanol; ammonia

: 2865-70-5
10-chloro-10H-phenoxarsine

: 58-36-6
10,10,oxybisphenoxarsine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: toluene; diethyl ether 2: O2 View Scheme
Multi-step reaction with 2 steps 1: benzene; diethyl ether 2: O2 View Scheme
Multi-step reaction with 2 steps 1: toluene; diethyl ether 2: aq. EtOH View Scheme

: 112-79-8
Elaidic Acid

: 58-36-6
10,10,oxybisphenoxarsine

: (E)-Octadec-9-enoic acid phenoxarsin-10-yl ester

Conditions

Conditions	Yield
In toluene Heating;	80.8%

: 58-36-6
10,10,oxybisphenoxarsine

: 79-10-7
acrylic acid

: Acrylic acid phenoxarsin-10-yl ester

Conditions

Conditions	Yield
In toluene Heating;	71.5%

: 108-30-5
succinic acid anhydride

: 58-36-6
10,10,oxybisphenoxarsine

: Succinic acid diphenoxarsin-10-yl ester

Conditions

Conditions	Yield
In toluene for 5h; Heating;	66%

: 3724-65-0
2-butenoic acid

: 58-36-6
10,10,oxybisphenoxarsine

: (E)-But-2-enoic acid phenoxarsin-10-yl ester

Conditions

Conditions	Yield
In toluene Heating;	62.8%

: 110-15-6
succinic acid

: 58-36-6
10,10,oxybisphenoxarsine

: succinic acid mono(10-phenoxyarsinyl) ester

Conditions

Conditions	Yield
In toluene for 5h; Heating;	61.2%

: 110-15-6
succinic acid

: 58-36-6
10,10,oxybisphenoxarsine

: Succinic acid diphenoxarsin-10-yl ester

Conditions

Conditions	Yield
In toluene for 8h; Heating;	59%

: 58-36-6
10,10,oxybisphenoxarsine

: 4846-20-2
10-oxo-10H-10λ5-phenoxarsin-10-ol

Conditions

Conditions	Yield
With ethanol; iodine

: 64-17-5
ethanol

: 86119-84-8, 7664-38-2
phosphoric acid

: 58-36-6
10,10,oxybisphenoxarsine

bis-phenoxarsinyl-(10): bis-phenoxarsinyl-(10)

...Expand

: 10035-10-6, 12258-64-9
hydrogen bromide

: 58-36-6
10,10,oxybisphenoxarsine

phenoxarsine bromide: phenoxarsine bromide

: 58-36-6
10,10,oxybisphenoxarsine

: 10,10'bis(phenoxarsine) selenide

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: conc. HI / benzene / 2 h 2: H2Se, pyridine / ethanol / 2 h View Scheme

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Consensus Reports

EPA Extremely Hazardous Substances List. Arsenic and its compounds are on the Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 0.5 mg(As)/m³

Specification

The 10,10-Oxybisphenoxarsine, with the CAS registry number 58-36-6, is also known as Bis(phenoxarsin-10-yl) ether. It belongs to the product categories of Industrial/Fine Chemicals. Its EINECS number is 200-377-3. This chemical's molecular formula is C₂₄H₁₆As₂O₃ and molecular weight is 502.23. What's more, its systematic name is 10,10'-oxybis(10H-phenoxarsinine). Its classification code is Skin / Eye Irritant. It is a new kind of industrial mould inhibitor. It is mouldproof and antibacterial, and is one of the most effective antimicrobial in industrial fields. It can be used as an antimicrobial add to the PVC products, plastic products, PVC flooring, metope paint and so on.

Physical properties of 10,10-Oxybisphenoxarsine are: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 2; (4)Polar Surface Area: 27.69 Å²; (5)Flash Point: 214.1 °C; (6)Enthalpy of Vaporization: 77.65 kJ/mol; (7)Boiling Point: 531.3 °C at 760 mmHg; (8)Vapour Pressure: 7.77E-11 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O5c1c(cccc1)[As](O[As]2c4ccccc4Oc3c2cccc3)c6ccccc56
(2)Std. InChI: InChI=1S/C24H16As2O3/c1-5-13-21-17(9-1)25(18-10-2-6-14-22(18)27-21)29-26-19-11-3-7-15-23(19)28-24-16-8-4-12-20(24)26/h1-16H
(3)Std. InChIKey: VCRZAKVGPJFABU-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
bird - wild	LD50	oral	24mg/kg (24mg/kg)		Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972.
guinea pig	LCLo	inhalation	141mg/m³/2H (141mg/m³)		Toxicology. Vol. 10, Pg. 341, 1978.
guinea pig	LD50	oral	24mg/kg (24mg/kg)	BEHAVIORAL: MUSCLE WEAKNESS LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Toxicology. Vol. 10, Pg. 341, 1978.
mouse	LDLo	oral	42mg/kg (42mg/kg)		Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985.
rat	LD50	oral	40mg/kg (40mg/kg)	BEHAVIORAL: MUSCLE WEAKNESS LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Toxicology. Vol. 10, Pg. 341, 1978.