CAS No.58-89-9,gamma-1,2,3,4,5,6-Hexachlorocyclohexane Suppliers

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Basic Information

Molecular Structure:
CAS No.:	58-89-9
Name:	gamma-1,2,3,4,5,6-Hexachlorocyclohexane
Article Data:	40

Formula:	C₆H₆Cl₆
Molecular Weight:	290.832
Synonyms:	Lentox;Lindafor;Lindane;Lindosep;Lintox;Lintox 3;Lorexane;Mglawik L;Milbol 49;Neo-Scabicidol;Nexit;Nexol E;Nicochloran;Omnitox;Ovadziak;PLK;Pedraczak;Quellada;Scabene;Spritz-Rapidin;Spritzlindane;Spruehpflanzol;TAP85;Tri-6;Viton;g-Benzene hexachloride;g-Benzohexachloride;g-HCH;g-Hexachloran;g-Hexachlorane;g-Hexachlorobenzene;g-Lindane;Entomoxan;Fenoform forte;Forst-Nexen;Gamacid;Gamene;Gamma benzenehexachloride;Gamma-HCH;Gammalin 20;Gammexane;Geolin G 3;Gexane;HCC;HCCH;HGI;Hexa;Hexachlorane;Hexachlorocyclohexane;Hexyclan;Hilbeech;Hortex;Inexit;Kanodane;Kokotine;Lasochron;Lendine;Aficide;Agrocide;Agrocide III;Agrocide WP;Aparasin;Aphtiria;Aplidal;Arbitex;BBH;Ben-Hex;Bercema-Spritz-Lindan 50;Bexol;Celanex;Detmol Extract;Dol Granule;Drilltox-Spezial Aglukon;
EINECS:	200-401-2
Density:	1.593 g/cm³
Melting Point:	113-115 °C(lit.)
Boiling Point:	287.999 °C at 760 mmHg
Flash Point:	157.495 °C
Appearance:	white powder
Hazard Symbols:	T,N
Risk Codes:	20/21-25-48/22-50/53-64
Safety:	36/37-45-60-61
Transport Information:	UN 2811 6.1/PG 1
PSA:	0.00000
LogP:	3.64440

Synthetic route

: 319-84-6
alpha-hexachlorocyclohexane

: 58-89-9
LINDANE

Conditions

Conditions	Yield
With aluminium trichloride at 170℃; Irradiation;
With aluminum tri-bromide at 170℃; Irradiation;
With aluminium(III) iodide at 170℃; Irradiation;
With aluminium trichloride in einem elektrischen Feld von 8000 V;

: 71-43-2
benzene

: 58-89-9
LINDANE

Conditions

Conditions	Yield
With methylene chloride; chlorine im UV-Licht;
With diisopropyl peroxydicarbonate; chlorine im UV-Licht;
With ammonium chloride; chlorine im UV-Licht;

: 319-86-8
delta-lindane

A: 58-89-9
LINDANE

B: 319-85-7
beta-hexachlorocyclohexane

C: 41992-55-6
α-3,4,5,6-Tetrachlorocyclohex-1-ene

: 319-84-6
alpha-hexachlorocyclohexane

: 319-81-3, 1782-00-9, 28810-35-7, 28810-37-9, 28810-38-0, 33875-95-5, 41992-55-6, 56933-25-6, 85687-83-8
γ-3,4,5,6-Tetrachlorocyclohex-1-ene

: 319-81-3, 1782-00-9, 28810-35-7, 28810-37-9, 28810-38-0, 33875-95-5, 41992-55-6, 56933-25-6, 85687-83-8
δ-3,4,5,6-Tetrachlorocyclohex-1-ene

Conditions

Conditions	Yield
With TEA In benzene at 20 - 25℃; Quantum yield; Product distribution; Mechanism; Irradiation;

...Expand

: 319-85-7
beta-hexachlorocyclohexane

A: 58-89-9
LINDANE

B: 41992-55-6
α-3,4,5,6-Tetrachlorocyclohex-1-ene

: 319-84-6
alpha-hexachlorocyclohexane

: 319-81-3, 1782-00-9, 28810-35-7, 28810-37-9, 28810-38-0, 33875-95-5, 41992-55-6, 56933-25-6, 85687-83-8
γ-3,4,5,6-Tetrachlorocyclohex-1-ene

: 319-81-3, 1782-00-9, 28810-35-7, 28810-37-9, 28810-38-0, 33875-95-5, 41992-55-6, 56933-25-6, 85687-83-8
δ-3,4,5,6-Tetrachlorocyclohex-1-ene

Conditions

Conditions	Yield
With TEA In benzene at 20 - 25℃; Quantum yield; Product distribution; Mechanism; Irradiation;

...Expand

: 319-84-6
alpha-hexachlorocyclohexane

A: 319-86-8
delta-lindane

B: 58-89-9
LINDANE

C: 319-85-7
beta-hexachlorocyclohexane

D: 41992-55-6
α-3,4,5,6-Tetrachlorocyclohex-1-ene

: 319-81-3, 1782-00-9, 28810-35-7, 28810-37-9, 28810-38-0, 33875-95-5, 41992-55-6, 56933-25-6, 85687-83-8
γ-3,4,5,6-Tetrachlorocyclohex-1-ene

: 319-81-3, 1782-00-9, 28810-35-7, 28810-37-9, 28810-38-0, 33875-95-5, 41992-55-6, 56933-25-6, 85687-83-8
δ-3,4,5,6-Tetrachlorocyclohex-1-ene

Conditions

Conditions	Yield
With TEA In benzene at 20 - 25℃; Quantum yield; Product distribution; Mechanism; Irradiation;

...Expand

75-90 degree boiling distillates from coking: 75-90 degree boiling distillates from coking

: 58-89-9
LINDANE

Conditions

Conditions	Yield
With water; chlorine

: 71-43-2
benzene

A: 58-89-9
LINDANE

B α-, β and δ-benzene hexachloride: α-, β and δ-benzene hexachloride

Conditions

Conditions	Yield
With sodium hydroxide; chlorine

: 7446-70-0
aluminium trichloride

: 319-86-8
delta-lindane

A: 58-89-9
LINDANE

: 319-84-6
alpha-hexachlorocyclohexane

Conditions

Conditions	Yield
at 140℃;

...Expand

: 56-23-5
tetrachloromethane

: 41992-55-6
α-3,4,5,6-Tetrachlorocyclohex-1-ene

: 7782-50-5
chlorine

A: 58-89-9
LINDANE

: 319-84-6
alpha-hexachlorocyclohexane

Conditions

Conditions	Yield
mit Gluehlampenlicht.Irradiation;

...Expand

: 319-86-8
delta-lindane

: 7705-08-0
iron(III) chloride

nitrogen: nitrogen

A: 58-89-9
LINDANE

: 319-84-6
alpha-hexachlorocyclohexane

Conditions

Conditions	Yield
at 170℃;

...Expand

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Chemistry

Molecular Formula: C₆H₆Cl₆
Molar mass: 290.83 g/mol
EINECS: 200-401-2
Density: 1.59 g/cm³
Flash Point: 157.5 °C
Index of Refraction: 1.532
Boiling Point: 288 °C at 760 mmHg
Vapour Pressure: 0.00416 mmHg at 25°C
Melting point: 113-115 °C(lit.)
Storage temp: 0-6°C
Appearance: White powder
Stable: Stable. Incompatible with strong oxidizing agents
Product categories of lindane (58-89-9): Fluoroelastomer;Insectcide;Organics
Structure of lindane (58-89-9):

XLogP3-AA: 3.8
H-Bond Donor: 0
H-Bond Acceptor: 0
IUPAC Name: 1,2,3,4,5,6-Hexachlorocyclohexane
Canonical SMILES: C1(C(C(C(C(C1Cl)Cl)Cl)Cl)Cl)Cl
InChI: InChI=1S/C6H6Cl6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h1-6H
InChIKey: JLYXXMFPNIAWKQ-UHFFFAOYSA-N

Uses

lindane (58-89-9) is used for the prevention and treatment of vermin ofof rice, wheat, soybeans, corn, vegetables, fruit, tobacco, forest, granaries and others .

Production

In A, B, C, D and other conformational isomers (ie, α-, β-, γ-, δ-body, etc.) of 666, only the gamma has strong insecticidal property. Lindane's industrial production is based on 666 different isomers at different temperatures in methanol, and the different solubility and various isomers of differences to be extracted.They need an appropriate amount of methanol and the extraction temperature .

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
cat	LD50	oral	25mg/kg (25mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 72, 1982.
cat	LDLo	unreported	50mg/kg (50mg/kg)	BEHAVIORAL: TREMOR LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS	Pharmacology and Toxicology. English translation of FATOAO. Vol. 22, Pg. 273, 1959.
child	TDLo	oral	111mg/kg (111mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Archives of Environmental Health. Vol. 25, Pg. 374, 1972.
child	TDLo	oral	180mg/kg (180mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: DYSPNEA LUNGS, THORAX, OR RESPIRATION: CYANOSIS	"Clinical Memoranda on Economic Poisons," U.S. Dept. HEW, Public Health Service, Communicable Disease Center, Atlanta, GA, 1956Vol. -, Pg. 1, 1956.
dog	LD50	oral	40mg/kg (40mg/kg)		Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 11, 1978.
dog	LDLo	intravenous	7500ug/kg (7.5mg/kg)		Tieraerztliche Umschau. Vol. 5, Pg. 61, 1950.
guinea pig	LD50	oral	127mg/kg (127mg/kg)		Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 6, Pg. 386, 1947.
hamster	LD50	intraperitoneal	640mg/kg (640mg/kg)		Archives of Toxicology. Vol. 58, Pg. 152, 1986.
hamster	LD50	oral	360mg/kg (360mg/kg)		European Journal of Toxicology and Environmental Hygiene. Vol. 7, Pg. 159, 1974.
human	LDLo	oral	840mg/kg (840mg/kg)		Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 34, Pg. 1232, 1992.
mammal (species unspecified)	LD50	unreported	300mg/kg (300mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 17(3), Pg. 32, 1973.
man	TDLo	skin	20mg/kg/6W-I (20mg/kg)	SENSE ORGANS AND SPECIAL SENSES: VISUAL FIELD CHANGES: EYE CARDIAC: OTHER CHANGES	American Journal of Diseases of Children. Vol. 141, Pg. 125, 1987.
mouse	LCLo	inhalation	120mg/m3/6H (120mg/m3)	BLOOD: CHANGES IN OTHER CELL COUNT (UNSPECIFIED) BLOOD: CHANGES IN LEUCOCYTE (WBC) COUNT	Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 8(10), Pg. 55, 1964.
mouse	LD50	intracrebral	60mg/kg (60mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Toxicology Letters. Vol. 60, Pg. 289, 1992.
mouse	LD50	intraperitoneal	125mg/kg (125mg/kg)		Soviet Genetics. English translation of GNKAA5. Vol. 2, Pg. 80, 1966.
mouse	LD50	oral	44mg/kg (44mg/kg)		Journal of Economic Entomology. Vol. 65, Pg. 632, 1972.
rabbit	LD50	oral	60mg/kg (60mg/kg)		Journal of Hygiene, Epidemiology, Microbiology, and Immunology. Vol. 22, Pg. 115, 1978.
rabbit	LD50	skin	50mg/kg (50mg/kg)	BEHAVIORAL: EXCITEMENT BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Quarterly Bulletin--Association of Food and Drug Officials of the United States. Vol. 16, Pg. 3, 1952.
rabbit	LDLo	intravenous	4500ug/kg (4.5mg/kg)	BEHAVIORAL: TREMOR LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD	Journal of Pharmacology and Experimental Therapeutics. Vol. 92, Pg. 140, 1948.
rat	LD50	intraperitoneal	35mg/kg (35mg/kg)		Naunyn-Schmiedeberg's Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 212, Pg. 463, 1951.
rat	LD50	oral	76mg/kg (76mg/kg)		Special Publication of the Entomological Society of America. Vol. 78-1, Pg. 11, 1978.
rat	LD50	skin	414mg/kg (414mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(7), Pg. 87, 1990.
rat	LD50	unreported	125mg/kg (125mg/kg)	BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(8), Pg. 29, 1963.
women	TDLo	skin	19mg/kg/1H-I (19mg/kg)	BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS" BEHAVIORAL: EXCITEMENT SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"	Annals of Emergency Medicine. Vol. 24, Pg. 972, 1994.

Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man , 5 (1974),p. 47.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man , 20 (1979),p. 195.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-14 (1977). . EPA Extremely Hazardous Substances List. EPA Genetic Toxicology Program. Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List.

Safety Profile

Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. A human systemic poison by ingestion. Also a poison by ingestion, skin contact, intraperitoneal, intravenous, and intramuscular routes. Human systemic effects by ingestion: convulsions, dyspnea, and cyanosis. Experimental teratogenic and reproductive effects. Mutation data reported. See also BENZENE HEXACHLORIDE and other benzene hexachloride entries. When heated to decomposition it emits toxic fumes of Cl⁻, HCl, and phosgene.

Hazard Codes: T,N,F,Xn,Xi
Risk Statements:
11: Highly Flammable
20: Harmful by inhalation
21: Harmful in contact with skin
22: Harmful if swallowed
23: Toxic by inhalation
24: Toxic in contact with skin
25: Toxic if swallowed
38: Irritating to the skin
39: Danger of very serious irreversible effects
48: Danger of serious damage to health by prolonged exposure
50: Very Toxic to aquatic organisms
53: May cause long-term adverse effects in the aquatic environment43: May cause sensitization by skin contact
62: Possible risk of impaired fertility
64: May cause harm to breast-fed babies
65: Harmful: May cause lung damage if swallowed
67: Vapors may cause drowsiness and dizziness
Safety Statements:
9: Keep container in a well-ventilated place
16: Keep away from sources of ignition - No smoking
29: Do not empty into drains
33: Take precautionary measures against static discharges
36: Wear suitable protective clothing
37: Wear suitable gloves
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
60: This material and/or its container must be disposed of as hazardous waste
61: Avoid release to the environment. Refer to special instructions safety data sheet
62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label

Standards and Recommendations

OSHA PEL: TWA 0.5 mg/m³ (skin)
ACGIH TLV: TWA 0.5 mg/m³ (skin)
DFG MAK: 0.1 mg/m³; Not Classifiable as a Human Carcinoge

Analytical Methods

For occupational chemical analysis use NIOSH: Aldrin and Lindane, 5502.

Specification

lindane (58-89-9) also can be called Kwell ; alpha-HCH ; Beta-HCH ; Aalindan ; Hexachlorane ; Jacutin ; gamma-HCH ; Beta-Lindane .