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CAS No.: | 5804-85-3 |
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Name: | DIETHYLALUMINUM CYANIDE SOLUTION |
Molecular Structure: | |
Formula: | C5H10 Al N |
Molecular Weight: | 111.123 |
Synonyms: | Aluminum,(cyano-C)diethyl-; Aluminum, cyanodiethyl- (7CI,8CI); Cyanodiethylalane;Cyanodiethylaluminum; Diethylaluminum cyanide |
Density: | g/cm3 |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
Hazard Symbols: | F,T+,N |
Risk Codes: | R11; R26/27/28; R32; R38; R48/20; R50/53; R63; R65; R67 |
Safety: | 3587410 |
PSA: | 23.79000 |
LogP: | 2.03508 |
diethylaluminium cyanide
(RS,2R)-(-)-N-[(tert-butyldimethylsilyl)oxy]-2-phenylacetylidene-p-toluenesulfinamide
(RS,2S,3R)-(-)-N-(p-toluenesulfinyl)-2-amino-[(tert-butyldimethylsilyl)oxy]-3-phenylpropionitrile
Conditions | Yield |
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With isopropyl alcohol In tetrahydrofuran at -78 - 20℃; Addition; | 100% |
diethylaluminium cyanide
N-tert-butyloxycarbonylpiperidin-4-one
tert-butyl 4-[benzyl(cyclopropylcarbonyl)amino]-4'-cyano-1,4'-bipiperidine-1'-carboxylate
Conditions | Yield |
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Stage #1: N-benzyl-N-piperidin-4-ylcyclopropanecarboxamide; N-tert-butyloxycarbonylpiperidin-4-one With titanium(IV) isopropylate In dichloromethane at 20℃; for 72h; Stage #2: diethylaluminium cyanide In dichloromethane; toluene for 16h; | 100% |
C13H20N2O
diethylaluminium cyanide
N-tert-butyloxycarbonylpiperidin-4-one
Conditions | Yield |
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Stage #1: C13H20N2O; N-tert-butyloxycarbonylpiperidin-4-one With titanium(IV) isopropylate at 25℃; for 24h; Stage #2: diethylaluminium cyanide In toluene at 20℃; for 24h; | 100% |
diethylaluminium cyanide
Conditions | Yield |
---|---|
Stage #1: rac-(4R,5S,6S)-1-benzyloxy-5,6-dihydroxy-5,6-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)-1-azaspiro[3.5]non-8-ene-2,7-dione; diethylaluminium cyanide In tetrahydrofuran at 0 - 80℃; for 3h; Inert atmosphere; Stage #2: With N-Bromosuccinimide In tetrahydrofuran at 0 - 20℃; for 0.25h; Product distribution / selectivity; | 100% |
diethylaluminium cyanide
(S)-2-((2S,3S)-3-Trimethylsilanyl-oxiranyl)-hexan-2-ol
(E)-(S)-4-Hydroxy-4-methyl-oct-2-enenitrile
Conditions | Yield |
---|---|
In tetrahydrofuran for 2h; Heating; | 99% |
diethylaluminium cyanide
(R)-benzyl glycidol
(3R)-4-(benzyloxy)-3-hydroxybutanenitrile
Conditions | Yield |
---|---|
In toluene; benzene at 0 - 20℃; | 99% |
diethylaluminium cyanide
2,3-epoxy-17-methyl-androstan-17-ol
(2R,3S,5S,8R,9S,10S,13S,14S,17S)-3,17-Dihydroxy-10,13,17-trimethyl-hexadecahydro-cyclopenta[a]phenanthrene-2-carbonitrile
Conditions | Yield |
---|---|
In toluene for 4h; Ambient temperature; | 98% |
diethylaluminium cyanide
(1aβ,3α,3aα,6α,7aβ,7bβ)-3-<<(1,1-dimethylethyl)dimethylsilyl>oxy>octahydro-6-methyl-5H-oxireno<1>benzopyran-5-one
(3R,4aR,5R,6R,8S,8aS)-8-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-3-methyl-2-oxo-octahydro-chromene-6-carbonitrile
Conditions | Yield |
---|---|
In tetrahydrofuran; toluene for 3h; Ambient temperature; | 98% |
11-oxatricyclo<4.4.1.01,6>undeca-3,8-diene
diethylaluminium cyanide
trans-8a-hydroxy-1,4,4a,5,8,8a-hexahydronaphthalene-4a-carbonitrile
Conditions | Yield |
---|---|
In dichloromethane at 20℃; | 98% |
diethylaluminium cyanide
(E)-N-benzylidene-2-methoxybenzenamine
α-[(2-methoxyphenyl)amino]-benzeneacetonitrile
Conditions | Yield |
---|---|
With (R)-1,1'-Bi-2-naphthol In toluene at -78 - -40℃; for 3h; | 98% |