Products Categories
| CAS No.: | 6311-35-9 |
|---|---|
| Name: | 6-Bromonicotinic acid |
| Article Data: | 15 |
| Molecular Structure: | |
|
|
|
| Formula: | C6H4BrNO2 |
| Molecular Weight: | 202.007 |
| Synonyms: | 6-bromopyridine-3-carboxylic acid;6-bromopyridine-3-carboxylate;2-Bromopyridine-5-carboxylic acid;2-bromo-5-Pyridinecarboxylic acid;3-Pyridinecarboxylic acid, 6-bromo-;2-bromo-5-pyridine carboxylic acid; |
| EINECS: | 628-671-0 |
| Density: | 1.814 g/cm3 |
| Melting Point: | 200-203 °C(lit.) |
| Boiling Point: | 343.261 °C at 760 mmHg |
| Flash Point: | 161.399 °C |
| Appearance: | Off-white plates |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 22-36/37/38 |
| Safety: | 26-36 |
| PSA: | 50.19000 |
| LogP: | 1.54230 |
- 81281-59-67-Benzylideneaminotheophylline
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
- 958254-66-51H-Imidazo[4,5-b]pyridine-2-carboxaldehyde, 1-methyl-, hydrochloride
- 99170-93-1N-Methyl-2-oxazolamine
- 717878-06-31-(4-fluorophenyl)-4-nitro-1H-imidazole
- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
| Conditions | Yield |
|---|---|
| With potassium permanganate; Aliquat 336 In water for 4.5h; Heating; | 50% |
| With potassium permanganate; Alquat-336 In water for 1.5h; Heating; | 50% |
| With potassium permanganate; Aliquat 336 In water at 110℃; for 2.5h; | 44% |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 93 percent / 1.) aq. 48percent HBr, bromine; 2.) aq. sodium nitrite / 1.) -20 deg C, 90 min; 2.) 15 deg C, 1 h 45 min 2: 50 percent / potassium permanganate / aliquat-336 / H2O / 4.5 h / Heating View Scheme | |
| Multi-step reaction with 2 steps 1: bromine; aqueous sodium nitrite solution; aqueous hydrobromic acid 2: aqueous KMnO4 View Scheme |
| Conditions | Yield |
|---|---|
| With phosphorus pentabromide | |
| With phosphorus(V) oxybromide at 170℃; for 0.166667h; Neat (no solvent); |
- 149806-06-4
6-bromonicotinaldehyde
- 6311-35-9
6-bromonicotinic acid
| Conditions | Yield |
|---|---|
| With 1,4-dithio-D,L-threitol; recombinant aldehyde dehydrogenase from Escherichia coli; water‐forming NADH oxidase from Streptococcus mutans; NAD In aq. phosphate buffer at 40℃; for 4h; pH=8.5; Reagent/catalyst; Green chemistry; Enzymatic reaction; chemoselective reaction; |
- 26218-78-0
methyl 6-bromonicotinate
- 6311-35-9
6-bromonicotinic acid
| Conditions | Yield |
|---|---|
| With water; sodium hydroxide In tetrahydrofuran at 25℃; for 16h; | 13.0 g |
| Conditions | Yield |
|---|---|
| With sulfuric acid Reflux; | 100% |
| With triphenylphosphine; diethylazodicarboxylate In diethyl ether for 1.16667h; Ambient temperature; | 79% |
| Stage #1: 6-bromonicotinic acid With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane for 1h; Stage #2: methanol | 55% |
| Conditions | Yield |
|---|---|
| With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine In dichloromethane at 0 - 20℃; for 18h; | 100% |
| With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20 - 23℃; for 15h; Inert atmosphere; | 75% |
| With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 20℃; for 2h; | 60% |
- 6311-35-9
6-bromonicotinic acid
- 1200575-98-9
tert-butyl 4-[6-(dimethoxyboryl)-4H-1,3-benzodioxin-2-yl]piperidine-1-carboxylate
- 1200576-01-7
6-{2-[1-(tert-butoxycarbonyl)piperidin-4-yl]-4H-1,3-benzodioxin-6-yl} nicotinic acid
| Conditions | Yield |
|---|---|
| With potassium carbonate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2 In water; acetonitrile at 160℃; for 0.333333h; Irradiation; | 100% |
| Conditions | Yield |
|---|---|
| With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 12h; | 94% |
| With potassium carbonate In N,N-dimethyl-formamide at 0 - 55℃; for 4h; | 0.909 g |
- 6311-35-9
6-bromonicotinic acid
| Conditions | Yield |
|---|---|
| With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; N-ethyl-N,N-diisopropylamine In ethyl acetate; acetonitrile at 20℃; for 18h; | 93% |
What can I do for you?
Get Best Price
Chemistry
The Molecular Structure of 6-Bromonicotinic acid (CAS NO.6311-35-9):
Empirical Formula: C6H4BrNO2
Molecular Weight: 202.0055
IUPAC Name: 6-bromopyridine-3-carboxylic acid
Appearance: Off-white Plates
Nominal Mass: 201 Da
Average Mass: 202.0055 Da
Monoisotopic Mass: 200.942533 Da
Index of Refraction: 1.616
Molar Refractivity: 38.96 cm3
Molar Volume: 111.3 cm3
Surface Tension: 63.2 dyne/cm
Density: 1.813 g/cm3
Flash Point: 161.4 °C
Enthalpy of Vaporization: 61.96 kJ/mol
Boiling Point: 343.3 °C at 760 mmHg
Vapour Pressure: 2.73E-05 mmHg at 25°C
Synonyms: Ilab-bb f1921-0015 ; Iflab-bb f1926-0006 ; Aurora 23320 ; Akos bbs-00001340 ; 6-Bromonicotinc acid ; 6-Bromonicotinic acid ; 6-Bromopyridine-3-carboxylic acid ; 6-Bromo-3-pyridinecarboxylic acid
Product Categories: blocks;Bromides;Carboxes;Pyridines;Pyridine;pyridine derivative;Acids and Derivatives;Heterocycles;Pyridines, Pyrimidines, Purines and Pteredines;pharmacetical;Carboxylic Acids;Bromopyridines;Halopyridines;Carboxylic Acids;Picolinic acid series
Safety Profile
Hazard Codes: 
Xn
Xi
Risk Statements: 22-36/37/38
R22: Harmful if swallowed
R36/37/38: Irritating to eyes, respiratory system and skin
Safe Statements:
S26: In case of contact with eyes, rinse immediately with plenty of WATER and seek medical advice
S36: Wear suitable protective clothing
WGK Germany: 3
Hazard Note: Irritant
HazardClass: IRRITANT