CAS No.633-03-4,Basic Green 1 Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	633-03-4
Name:	Basic Green 1
Article Data:	5

Formula:	C₂₇H₃₃N₂^.HSO₄
Molecular Weight:	482.644
Synonyms:	Brilliant Green WP Crystals;Emerald Green;Avon Green A-4379;Ammonium, [4-[p- (diethylamino)-.alpha.-phenylbenzylidene]-2, 5-cyclohexadien-1-ylidene]diethyl-, sulfate (1:1);Brilliant Tungstate Green Toner GT-288;Brilliant Green Certified;Brilliant green (C.I. 42040);Calcozine Brilliant Green G;Brilliant Green Crystals;Brilliant Green B.p.;Brilliant Green Lake;Brilliant Green DSC;[4-[(4-diethylaminophenyl)-phenyl-methylidene]-1-cyclohexa-2,5-dienylidene]-diethyl-azanium; sulfuric acid;Brilliant Lake Green Y;Brilliant Green Special;Ethanaminium, N-[4-[[4- (diethylamino)phenyl]phenylmethylene]-2, 5-cyclohexadien-1-ylidene]-N-ethyl-, sulfate (1:1);Basic Green V;Deorlene Green JJO;Fast Green JJO;Brilliant Green Sulfate;C.I. Basic Green 1, Sulfate (1:1);Brilliant green aseptic;Basic Bright Green Sulfate;Brilliant Green Crystals H;Astrazon Green D;Brilliant Green GX;Aizen Diamond Green GH;Brilliant Green;Brilliant Green P;Brilliant Green BP;Astra Diamond Green GX;Brilliant Green B;Solid Green;Green EN;
EINECS:	211-190-1
Density:	1.1016 (rough estimate)
Melting Point:	180 °C
Boiling Point:	100.0
Solubility:	100 g/L (25 °C) in water
Appearance:	Metallic green crystals
Hazard Symbols:	Xn
Risk Codes:	22-36
Safety:	26-39
PSA:	92.29000
LogP:	6.48360

Synthetic route

: 129-73-7
bis(4-dimethylaminophenyl)phenylmethane

: 633-03-4
brilliant green

Conditions

Conditions	Yield
With hydrogenchloride; lead dioxide Darstellung;

: 82-90-6
bis-(4-diethylamino-phenyl)-phenyl-methane

: 633-03-4
brilliant green

Conditions

Conditions	Yield
With lead dioxide
With manganese(IV) oxide

: 98-07-7
Benzotrichlorid

: 91-66-7
N,N-diethylaniline

: 633-03-4
brilliant green

Conditions

Conditions	Yield
With zinc(II) chloride

: 630-98-8
brilliant green

A: 633-03-4
brilliant green

B: Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

Conditions

Conditions	Yield
With aq. buffer at 25℃; Rate constant; Equilibrium constant;

: Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

A: 630-98-8
brilliant green

B: 633-03-4
brilliant green

C: Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

Conditions

Conditions	Yield
With aq. buffer at 25℃; Rate constant; Equilibrium constant;

...Expand

: C27H33N2(1+)*2HO4S(1-)*H(1+)

A: 633-03-4
brilliant green

B: Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

Conditions

Conditions	Yield
With aq. buffer at 25℃; Rate constant; Equilibrium constant;

: 630-98-8
brilliant green

: 633-03-4
brilliant green

Conditions

Conditions	Yield
In water Equilibrium constant;
Multi-step reaction with 2 steps 1: concentrated hydrochloric acid / 180 °C / im Druckrohr 2: zinc chloride View Scheme

: phosphotungstic acid hydrate

: 633-03-4
brilliant green

: 3C27H33N2(1+)*O40PW12(3-)*H2O

Conditions

Conditions	Yield
In water at 90℃;	94.8%

: 925-90-6
ethylmagnesium bromide

: 633-03-4
brilliant green

: 1,1-bis-(4-diethylamino-phenyl)-1-phenyl-propane

Conditions

Conditions	Yield
With diethyl ether anschliessend Behandeln mit Wasser;

: 633-03-4
brilliant green

: 10557-57-0
propylmagnesium iodide

: 1,1-bis-(4-diethylamino-phenyl)-1-phenyl-butane

Conditions

Conditions	Yield
With diethyl ether anschliessend Behandeln mit Wasser;

Raw Materials

129-73-7

82-90-6

630-98-8

91-66-7

98-07-7

Downstream Products

70-55-3

91-66-7

17609-82-4

18127-87-2

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Toxicity Data With Reference

1.	skn-hmn 2 mg/2D-I MLD	ADVEA4 Acta Dermato-Venereologica, 52 (1972),55.
2.	skn-gpg 6 mg/3D-I	ADVEA4 Acta Dermato-Venereologica, 52 (1972),55.
3.	mmo-smc 100 µg/L	VINIT* Vsesoyuznyi Institut Nauchnoi i Tekhnicheskoi Informatsii (VINITI). All-Union Institute of Scientific and Technical Information. (Moscow, USSR) #542-84
4.	orl-rat LDLo:10 mg/kg	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases, 7 (2)(1963),54.
5.	ipr-rat LDLo:8 mg/kg	PSEBAA Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.
6.	ipr-mus LDLo:5 mg/kg	PSEBAA Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.
7.	ivn-mus LDLo:3 mg/kg	PSEBAA Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.
8.	ipr-gpg LDLo:3 mg/kg	PSEBAA Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. A mild human skin irritant. Mutation data reported. See also ALDEHYDES and SULFATES. When heated to decomposition it emits very toxic fumes of NO_x, NH₃, and SO_x.