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633-03-4

Basic Information
CAS No.: 633-03-4
Name: Basic Green 1
Molecular Structure:
Molecular Structure of 633-03-4 (Basic Green 1)
Formula: C27H33N2.HSO4
Molecular Weight: 482.69
Synonyms: Brilliant Green WP Crystals;Emerald Green;Avon Green A-4379;Ammonium, [4-[p- (diethylamino)-.alpha.-phenylbenzylidene]-2, 5-cyclohexadien-1-ylidene]diethyl-, sulfate (1:1);Brilliant Tungstate Green Toner GT-288;Brilliant Green Certified;Brilliant green (C.I. 42040);Calcozine Brilliant Green G;Brilliant Green Crystals;Brilliant Green B.p.;Brilliant Green Lake;Brilliant Green DSC;[4-[(4-diethylaminophenyl)-phenyl-methylidene]-1-cyclohexa-2,5-dienylidene]-diethyl-azanium; sulfuric acid;Brilliant Lake Green Y;Brilliant Green Special;Ethanaminium, N-[4-[[4- (diethylamino)phenyl]phenylmethylene]-2, 5-cyclohexadien-1-ylidene]-N-ethyl-, sulfate (1:1);Basic Green V;Deorlene Green JJO;Fast Green JJO;Brilliant Green Sulfate;C.I. Basic Green 1, Sulfate (1:1);Brilliant green aseptic;Basic Bright Green Sulfate;Brilliant Green Crystals H;Astrazon Green D;Brilliant Green GX;Aizen Diamond Green GH;Brilliant Green;Brilliant Green P;Brilliant Green BP;Astra Diamond Green GX;Brilliant Green B;Solid Green;Green EN;
EINECS: 211-190-1
Density: 1.1016 (rough estimate)
Melting Point: 180 °C
Boiling Point: 100.0
Flash Point:
Solubility: 100 g/L (25 °C) in water
Appearance: Metallic green crystals
Hazard Symbols: HarmfulXn
Risk Codes: 22-36
Safety: 26-39
Transport Information:
PSA: 92.29000
LogP: 6.48360
Synthetic route
129-73-7

bis(4-dimethylaminophenyl)phenylmethane

633-03-4

brilliant green

Conditions
ConditionsYield
With hydrogenchloride; lead dioxide Darstellung;
82-90-6

bis-(4-diethylamino-phenyl)-phenyl-methane

633-03-4

brilliant green

Conditions
ConditionsYield
With lead dioxide
With manganese(IV) oxide
98-07-7

Benzotrichlorid

91-66-7

N,N-diethylaniline

633-03-4

brilliant green

Conditions
ConditionsYield
With zinc(II) chloride
630-98-8

brilliant green

A

633-03-4

brilliant green

B

Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

Conditions
ConditionsYield
With aq. buffer at 25℃; Rate constant; Equilibrium constant;

Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

A

630-98-8

brilliant green

B

633-03-4

brilliant green

C

Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

Conditions
ConditionsYield
With aq. buffer at 25℃; Rate constant; Equilibrium constant;

C27H33N2(1+)*2HO4S(1-)*H(1+)

A

633-03-4

brilliant green

B

Bis-(4-diethylamino-phenyl)-phenyl-methanol; compound with sulfuric acid

Conditions
ConditionsYield
With aq. buffer at 25℃; Rate constant; Equilibrium constant;
630-98-8

brilliant green

633-03-4

brilliant green

Conditions
ConditionsYield
In water Equilibrium constant;
Multi-step reaction with 2 steps
1: concentrated hydrochloric acid / 180 °C / im Druckrohr
2: zinc chloride
View Scheme

phosphotungstic acid hydrate

633-03-4

brilliant green

3C27H33N2(1+)*O40PW12(3-)*H2O

Conditions
ConditionsYield
In water at 90℃;94.8%
925-90-6

ethylmagnesium bromide

633-03-4

brilliant green

1,1-bis-(4-diethylamino-phenyl)-1-phenyl-propane

Conditions
ConditionsYield
With diethyl ether anschliessend Behandeln mit Wasser;
633-03-4

brilliant green

10557-57-0

propylmagnesium iodide

1,1-bis-(4-diethylamino-phenyl)-1-phenyl-butane

Conditions
ConditionsYield
With diethyl ether anschliessend Behandeln mit Wasser;
151-50-8

potassium cyanide

633-03-4

brilliant green

63174-26-5

bis-(4-diethylamino-phenyl)-phenyl-acetonitrile

633-03-4

brilliant green

630-98-8

brilliant green

Conditions
ConditionsYield
With hydroxide In water Equilibrium constant; Rate constant;
633-03-4

brilliant green

ethylmagnesium bromide

α-phenyl-α.α-bis--propane

α-phenyl-α.α-bis--propane

633-03-4

brilliant green

630-98-8

brilliant green

Conditions
ConditionsYield
at 20℃; Geschwindigkeit; in gepufferter wss.Loesung;
14337-01-0

hydroxide

633-03-4

brilliant green

630-98-8

brilliant green

Conditions
ConditionsYield
at 25℃; Rate constant; Loesung vom pH 10.2 und 12.2;
14337-01-0

hydroxide

57-09-0

cetyltrimethylammonim bromide

633-03-4

brilliant green

630-98-8

brilliant green

Conditions
ConditionsYield
at 25℃; Rate constant;
14337-01-0

hydroxide

151-21-3

sodium dodecyl-sulfate

633-03-4

brilliant green

630-98-8

brilliant green

Conditions
ConditionsYield
at 25℃; Rate constant;
7647-01-0

hydrogenchloride

633-03-4

brilliant green

zinc

zinc

82-90-6

bis-(4-diethylamino-phenyl)-phenyl-methane

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:571-86217390

    Address:Huacai International Building,Sandun,Westlake District,Hangzhou 310030,Zhejiang,China

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  • Brilliant Green

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    633-03-4

    Brilliant Green

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     China (Mainland)  |  Contact Details

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  • Basic Green 1

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    633-03-4

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    Business Type:Manufacturers

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    633-03-4

    TIANFU-CHEM Basic Green 1

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    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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    633-03-4

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     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

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    633-03-4

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    633-03-4

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    Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete

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    633-03-4

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    633-03-4

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    Hangzhou Ocean Chemical Co.ltd is a comprehensive chemical enterprise which mainly integrates R&D, production, marketing business of chemical in lab-pack, semi-bulk and bulk-quanti

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-88025872, 28272092, 28272096

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Toxicity Data With Reference

1.   

skn-hmn 2 mg/2D-I MLD

    ADVEA4    Acta Dermato-Venereologica, 52 (1972),55.
2.   

skn-gpg 6 mg/3D-I

    ADVEA4    Acta Dermato-Venereologica, 52 (1972),55.
3.   

mmo-smc 100 µg/L

    VINIT*    Vsesoyuznyi Institut Nauchnoi i Tekhnicheskoi Informatsii (VINITI). All-Union Institute of Scientific and Technical Information. (Moscow, USSR) #542-84
4.   

orl-rat LDLo:10 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases, 7 (2)(1963),54.
5.   

ipr-rat LDLo:8 mg/kg

    PSEBAA    Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.
6.   

ipr-mus LDLo:5 mg/kg

    PSEBAA    Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.
7.   

ivn-mus LDLo:3 mg/kg

    PSEBAA    Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.
8.   

ipr-gpg LDLo:3 mg/kg

    PSEBAA    Proceedings of the Society for Experimental Biology and Medicine, 31 (1934),825.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion, intraperitoneal, and intravenous routes. A mild human skin irritant. Mutation data reported. See also ALDEHYDES and SULFATES. When heated to decomposition it emits very toxic fumes of NOx, NH3, and SOx.