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CAS No.: | 7080-50-4 |
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Name: | Chloramine-T trihydrate |
Molecular Structure: | |
Formula: | C7H7ClNNaO2S.3(H2O) |
Molecular Weight: | 281.693 |
Synonyms: | Benzenesulfonamide,N-chloro-4-methyl-, sodium salt, trihydrate (9CI);Sodium,(N-chloro-p-toluenesulfonamido)-, trihydrate (8CI);Benzenesulfonamide,N-chloro-4-methyl-, sodium salt, hydrate (1:1:3);Tosylchloramide sodium trihydrate; |
EINECS: | 204-854-7 |
Density: | 1.43 |
Melting Point: | 167-170 °C(lit.) |
Flash Point: | 92 °C |
Solubility: | Soluble in water and ethyl alcohol. Insoluble in benzene and ethers. |
Appearance: | White to off-white crystalline powder |
Hazard Symbols: | C |
Risk Codes: | 22-31-34-42 |
Safety: | 22-26-36/37/39-45 |
Transport Information: | UN 3263 8/PG 3 |
PSA: | 70.21000 |
LogP: | 3.09910 |
Conditions | Yield |
---|---|
With calcium hydroxide Chlorierung und Umsetzung des etnstandenen Calciumsalzes mit Natriumchlorid; | |
With water Chlorierung und Zerlegung des etnstandenen p-Toluolsulfonsaeure-dichloramids mit Natronlauge; | |
Multi-step reaction with 2 steps 1: HOCl 2: water; NaOH-solution View Scheme | |
With calcium chloride Umsetzung mit Soda oder Natriumsulfat; |
Conditions | Yield |
---|---|
With sodium hydroxide; water |
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1. Introduction of Chloramine-T trihydrate
Chloramine-T trihydrate is also called cosylchloramide sodium, it is widely used in organic synthesis.
2. Properties of Chloramine-T trihydrate
Solubility: 150 g/l (25 °C)
Molar mass: 281.69 g/mol
Bulk density: 540 - 680 kg/m3
pH value: 8 - 10 (50 g/l, H2O, 20 °C)
Flash point: 192 °C
3. Toxicity of Chloramine-T trihydrate
LD 50 oral LD50 rat 935 mg/kg
4. Safety Information of Chloramine-T trihydrate
Hazard Symbols:C
Risk Codes:
R22:Harmful if swallowed.
R31 :Contact with acids liberates toxic gas.
R34:Causes burns.
R42:May cause sensitization by inhalation.
Safety:
S22:Do not breathe dust.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
5. Transport information of Chloramine-T trihydrate
Declaration (railroad and road) ADR, RID UN 2928 Giftiger organischer fester Stoff, ätzend, n.a.g.(N-CHLOR-4-TOLUOLSULFONSAEUREAMID NATRIUMSALZ), 6.1 (8), II
Declaration (transport by sea) IMDG-Code UN 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.(N-CHLORO-4-TOLUENESULFONAMIDE SODIUM SALT), 6.1 (8), II
Declaration (transport by air) IATA-DGR UN 2928 TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S.(N-CHLORO-4-TOLUENESULFONAMIDE SODIUM SALT), 6.1 (8), II