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CAS No.: | 721-26-6 |
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Name: | META-DIISOPROPYLBENZENEDIHYDROPEROXIDE |
Article Data: | 16 |
Molecular Structure: | |
Formula: | C12H18 O4 |
Molecular Weight: | 226.273 |
Synonyms: | Hydroperoxide,(m-phenylenediisopropylidene)di- (7CI,8CI); Hydroperoxide,[1,3-phenylenebis(1-methylethylidene)]bis- (9CI);1,3-Bis(1-hydroperoxy-1-methylethyl)benzene;1,3-Di(2-hydroperoxyisopropyl)benzene; 1,3-Diisopropylbenzene dihydroperoxide;m-Bis(1-hydroperoxy-1-methylethyl)benzene; m-Bis(hydroperoxyisopropyl)benzene;m-Diisopropylbenzene dihydroperoxide; m-Phenylenediisopropylidenedihydroperoxide; a,a'-Dihydroperoxy-m-diisopropylbenzene |
Density: | 1.145g/cm3 |
Melting Point: | 61 °C |
Boiling Point: | 376.8°C at 760 mmHg |
Flash Point: | 181.7°C |
PSA: | 86.58000 |
LogP: | 3.71320 |
1,3-diisopropylbenzene
3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene
1,3-di(2-hydroperoxy-2-propyl)benzene
Conditions | Yield |
---|---|
With oxygen In water at 83 - 92℃; under 2250.23 Torr; for 10h; pH=9 - 11; Product distribution / selectivity; | 66.1% |
With oxygen; sodium formate; sodium acetate; iron(II) acetate; sodium carbonate In water at 90℃; under 2250.23 Torr; for 6h; Product distribution / selectivity; | |
With oxygen; sodium formate; sodium acetate; sodium carbonate In water at 90℃; under 2250.23 Torr; for 6h; Product distribution / selectivity; | |
With oxygen at 90℃; Product distribution / selectivity; |
1,3-diisopropylbenzene
A
3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene
B
1,3-di(2-hydroperoxy-2-propyl)benzene
Conditions | Yield |
---|---|
With air; sodium carbonate at 90℃; | |
With air; sodium carbonate at 90℃; |
1,3-diisopropylbenzene
A
1,3-bis(1',1'-dimethylhydroxymethyl)benzene
B
3-(2-hydroxy-2-propyl)-1-(2-hydroperoxy-2-propyl)benzene
C
3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene
D
1,3-di(2-hydroperoxy-2-propyl)benzene
E
2-(3-isopropyl-phenyl)-propan-2-ol
Conditions | Yield |
---|---|
With oxygen; 1,10-Phenanthroline; magnesium naphthenate at 80 - 120℃; Rate constant; Kinetics; Thermodynamic data; E(act.) for various reaction products formation, other catalyst; |
1,3-diisopropylbenzene
A
3-(2-hydroxy-2-propyl)-1-(2-hydroperoxy-2-propyl)benzene
B
3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene
C
1,3-di(2-hydroperoxy-2-propyl)benzene
Conditions | Yield |
---|---|
With oxygen; amino acids copper salts at 110℃; Product distribution; var. catalysts, selectivity of catalysts; | |
With oxygen at 90℃; under 2250.23 Torr; for 10h; pH=9 - 11; Product distribution / selectivity; |
1,3-diisopropylbenzene
oxygen
B
1,3-bis(1',1'-dimethylhydroxymethyl)benzene
C
3-(2-hydroxy-2-propyl)-1-(2-hydroperoxy-2-propyl)benzene
D
1,3-di(2-hydroperoxy-2-propyl)benzene
E
acetylisopropylbenzene monocarbinol
F
2-(3-isopropyl-phenyl)-propan-2-ol
G
1-[3-(propan-2-yl)phenyl]ethan-1-one
Conditions | Yield |
---|---|
With sodium hydroxide; 3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene In water at 90℃; |
3-(2-hydroxy-2-propyl)-1-(2-hydroperoxy-2-propyl)benzene
B
1,3-bis(1',1'-dimethylhydroxymethyl)benzene
C
3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene
D
1,3-di(2-hydroperoxy-2-propyl)benzene
E
acetylisopropylbenzene monocarbinol
F
2-(3-isopropyl-phenyl)-propan-2-ol
G
1-[3-(propan-2-yl)phenyl]ethan-1-one
Conditions | Yield |
---|---|
With sodium hydroxide In water; 4-methyl-2-pentanone at 90℃; Heating / reflux; |
3-(2-hydroxy-2-propyl)-1-(2-hydroperoxy-2-propyl)benzene
B
1,3-bis(1',1'-dimethylhydroxymethyl)benzene
C
3-isopropyl-1-(2-hydroperoxy-2-propyl)benzene
D
1,3-di(2-hydroperoxy-2-propyl)benzene
E
acetylisopropylbenzene monocarbinol
F
2-(3-isopropyl-phenyl)-propan-2-ol
Conditions | Yield |
---|---|
With sodium sulfite In water; 4-methyl-2-pentanone Heating / reflux; |
Conditions | Yield |
---|---|
sulfur trioxide In 4-methyl-2-pentanone at 70℃; for 0.166667h; Product distribution / selectivity; | A n/a B 94% |
Conditions | Yield |
---|---|
With sulfuric acid; acetone; butanone | |
With with acid-agent treated Fuller's earth; acetone; benzene |