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73874-95-0

Basic Information
CAS No.: 73874-95-0
Name: 4-N-Boc-aminopiperidine
Molecular Structure:
Molecular Structure of 73874-95-0 (4-N-Boc-aminopiperidine)
Formula: C10H20N2O2
Molecular Weight: 200.28
Synonyms: 4-N-Boc-amino-piperidine;4-(N-tert-Butoxycarbonylamino)piperidine;4-Boc-AminoPiperidine;4-tert-Butoxycarbonyl-aminopiperidine;4-(N-BOC-amino) piperidine;4-N-Boc-Amino Piperidine;4-(Boc-amino)piperidine;tert-butyl piperidin-4-ylcarbamate;4-(N-Boc-amino)piperidine;4-Boc-amino piperidine;4-Boc-aminopiperindine;4-N-(tert-Butoxycarbonyl)aminopiperidine;N-Boc-piperidin-4-amine;tert-butyl N-(3,4,5,6-tetrahydro-2H-pyridin-4-yl)carbamate;
EINECS: 616-026-6
Density: 1.02 g/cm3
Melting Point: 162-166 °C
Boiling Point: 304.8 °C at 760 mmHg
Flash Point: 138.2 °C
Solubility:
Appearance: Off-white solid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-37/39
Transport Information:
PSA: 50.36000
LogP: 1.98280
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    4-N-BOC-Aminopiperidine

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Specification

The 4-N-Boc-aminopiperidine, with the CAS registry number 73874-95-0, is also known as Boc-4-aminopiperidine. It belongs to the product categories of Amines; Blocks; Pharmacetical; Pyridine Series; Pyrans, Piperidines & Piperazines; Piperidine; Piperidines; Pyrans, Piperidines & Piperazines; Building Blocks; Heterocyclic Building Blocks. This chemical's molecular formula is C10H20N2O2 and molecular weight is 200.278. Its IUPAC name is called tert-butyl N-piperidin-4-ylcarbamate. The product should be sealed and stored in cool and dry place. What's more, it should be protected from strong oxides. 4-N-Boc-aminopiperidine is used for pharmaceutical intermediates.

Physical properties of 4-N-Boc-aminopiperidine: (1)ACD/LogP: 1.16; (2)ACD/BCF (pH 5.5): 1; (3)ACD/BCF (pH 7.4): 1; (4)ACD/KOC (pH 5.5): 1; (5)ACD/KOC (pH 7.4): 1; (6)#H bond acceptors: 4; (7)#H bond donors: 2; (8)#Freely Rotating Bonds: 3; (9)Index of Refraction: 1.48; (10)Molar Refractivity: 55.446 cm3; (11)Molar Volume: 195.2 cm3; (12)Surface Tension: 35.73 dyne/cm; (13)Density: 1.026 g/cm3; (14)Flash Point: 138.152 °C; (15)Enthalpy of Vaporization: 54.522 kJ/mol; (16)Boiling Point: 304.823 °C at 760 mmHg; (17)Vapour Pressure: 0.001 mmHg at 25°C.

Preparation of 4-N-Boc-aminopiperidine: this chemical can be prepared by (1-benzyl-piperidin-4-yl)-carbamic acid tert-butyl ester. This reaction will need reagent cyclohexene and solvent ethanol. The reaction time is 3.5 hours. The yield is about 92%.

4-N-Boc-aminopiperidine can be prepared by (1-benzyl-piperidin-4-yl)-carbamic acid tert-butyl ester

Uses of 4-N-Boc-aminopiperidine: it can be used to produce [1-(4-nitro-benzyl)-piperidin-4-yl]-carbamic acid tert-butyl ester at temperature of 20 °C. This reaction will need reagents acetic acid, sodium triacetoxyborohydride and solvent tetrahydrofuran with reaction time of 20 hours. The yield is about 78%.

4-N-Boc-aminopiperidine can be used to produce [1-(4-nitro-benzyl)-piperidin-4-yl]-carbamic acid tert-butyl ester

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC(C)(C)OC(=O)NC1CCNCC1
(2)InChI: InChI=1S/C10H20N2O2/c1-10(2,3)14-9(13)12-8-4-6-11-7-5-8/h8,11H,4-7H2,1-3H3,(H,12,13)
(3)InChIKey: CKXZPVPIDOJLLM-UHFFFAOYSA-N