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Basic Information
CAS No.: 79-76-5
Name: 4-(2,2-dimethyl-6-methylenecyclohexyl)-3-buten-2-one
Molecular Structure:
Molecular Structure of 79-76-5 (4-(2,2-dimethyl-6-methylenecyclohexyl)-3-buten-2-one)
Formula: C13H20 O
Molecular Weight: 192.301
Synonyms: g-Ionone
EINECS: 201-223-8
Density: 0.91 g/cm3
Boiling Point: 267.8 °C at 760 mmHg
Flash Point: 112.3 °C
PSA: 17.07000
LogP: 3.51410
Synthetic route
472-19-5, 4352-33-4

(2,2-dimethyl-6-methylenecyclohexyl)methanol

1439-36-7

1-triphenylphosphoranylidene-2-propanone

79-76-5

γ-ionone

Conditions
ConditionsYield
Stage #1: 2,2-dimethyl-6-methylenecyclohexanemethanol With oxalyl dichloride; dimethyl sulfoxide In dichloromethane at -78℃; for 3h; Inert atmosphere;
Stage #2: With triethylamine In dichloromethane at -78 - 20℃; Inert atmosphere;
Stage #3: 1-triphenylphosphoranylidene-2-propanone In toluene for 16h; Inert atmosphere; Reflux;
67%
472-76-4

(E)-4-(2,2-Dimethyl-6-methylene-cyclohexyl)-but-3-en-2-ol

79-76-5

γ-ionone

Conditions
ConditionsYield
With manganese(IV) oxide In chloroform for 6h; Heating;

Acetic acid (E)-3-(2,2-dimethyl-6-methylene-cyclohexyl)-1-methyl-allyl ester

79-76-5

γ-ionone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: KOH / methanol / 20 °C
2: MnO2 / CHCl3 / 6 h / Heating
View Scheme
25312-34-9

alpha-ionol

79-76-5

γ-ionone

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 91 percent / pyridine / 6 h
2: propan-2-ol; xylene / 480 h / UV-irradiation
3: KOH / methanol / 20 °C
4: MnO2 / CHCl3 / 6 h / Heating
View Scheme
783324-41-4

(2E)-1-methyl-3-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-propenyl acetate

79-76-5

γ-ionone

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: propan-2-ol; xylene / 480 h / UV-irradiation
2: KOH / methanol / 20 °C
3: MnO2 / CHCl3 / 6 h / Heating
View Scheme
81752-87-6

methyl (+/-)-2,2-dimethyl-6-methylene-1-cyclohexanecarboxylate

79-76-5

γ-ionone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
2.3: 16 h / Inert atmosphere; Reflux
View Scheme
79-76-5

γ-ionone

13720-12-2

4-(2',2'-Dimethyl-6'-methylidenecyclohexyl)butan-2-one

Conditions
ConditionsYield
Stage #1: γ-ionone With water; tri-n-butyl-tin hydride; ammonium chloride; 1-triphenylphosphoranylidene-2-propanone In tetrahydrofuran for 3h; Inert atmosphere;
Stage #2: With sodium fluoride In water; ethyl acetate for 5h; Inert atmosphere;
76%
79-76-5

γ-ionone

74-86-2

acetylene

Ethinyl-Φ-ionol

Conditions
ConditionsYield
(i) naphthalene/Li, THF, (ii) /BRN= 2690409/; Multistep reaction;
79-76-5

γ-ionone

70143-17-8

(E)-4-(5,5-Dimethyl-1-oxa-spiro[2.5]oct-4-yl)-but-3-en-2-one

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 4h;
79-76-5

γ-ionone

(+)-7,11-epoxymegastigma-5(6)-en-9-one

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: MCPBA / CH2Cl2 / 4 h / 0 °C
2: 18.9 g / NaOMe / dimethylformamide / 3 h / 20 °C
3: Pseudomonas cepacia lipase PS / various solvent(s)
4: KOH / methanol / 20 °C
5: 93 percent / pyridine*SO3; Et3N / dimethylsulfoxide / 3 h
View Scheme
Multi-step reaction with 5 steps
1: MCPBA / CH2Cl2 / 4 h / 0 °C
2: 18.9 g / NaOMe / dimethylformamide / 3 h / 20 °C
3: 28 percent / NaBH4 / methanol / 2 h / 0 °C
4: Pseudomonas cepacia lipase PS / various solvent(s)
5: pyridine*SO3; Et3N / dimethylsulfoxide / 3 h
View Scheme
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    High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality produc

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

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  • (E)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one

  • Casno:

    79-76-5

    (E)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one

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    Locating in Changchun bonded area, which has absolute advantage of importing and exporting, with the R&D team having more than 10 years experience of OLED material and intermediate

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  • (e)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one

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    79-76-5

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    Min.Order: 0

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    (e)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx

    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

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  • (E)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one

  • Casno:

    79-76-5

    (E)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one

    Min.Order: 0

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    (E)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-oneAppearance:ASK Storage:Keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:by air or by sea

    Shanghai PengMo Biotechnology Co., Ltd. is engaging in researching, developing, manufacturing and exporting advanced pharmaceutical intermediates and other fine chemicals. Our comp

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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  • 4-(2,2-dimethyl-6-methylenecyclohexyl)-3-buten-2-one

  • Casno:

    79-76-5

    4-(2,2-dimethyl-6-methylenecyclohexyl)-3-buten-2-one

    Min.Order: 0

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    factory?direct?saleAppearance:powder Storage:Sealed in dry,Room Temperature Application:for pharma use Transportation:by express or by sea Port:Any main ports of China

    Hangzhou Shanyi Biotechnology Co., Ltd. is headquartered in Hangzhou, China. It is a high-tech enterprise specializing in the research and development, production, development, and

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  • 4-(2,2-dimethyl-6-methylenecyclohexyl)-3-Buten-2-one

  • Casno:

    79-76-5

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    Min.Order: 0

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    1.Fast and safety delivery by well-reputed shipping line;2.we have our own chemical laboratory and factory3.Reasonable price, excellent quality and attentive service.4.prompt reply.we can reply your inquiry within 12 hours.5.sample free(depends on pr

    We are a manufacturer and trader in China, with 10 years of experience in the export of chemical and pharmaceutical raw materials and 320 employees. We are all promoted on Made in

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+8617320695765

    Address:Qiu County gucheng ying Town Zhang Zhang Lu villag

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  • Casno:

    79-76-5

    (E)-4-(2,2-dimethyl-6-methylidenecyclohexyl)but-3-en-2-one

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-027-85953558

    Address:East Lake high tech Development Zone, Wuhan, 262, No.

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