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CAS No.: | 85-02-9 |
---|---|
Name: | 5,6-BENZOQUINOLINE |
Article Data: | 35 |
Molecular Structure: | |
Formula: | C13H9 N |
Molecular Weight: | 179.221 |
Synonyms: | 1-Azaphenanthrene;5,6-Benzo[f]quinoline; 5,6-Benzoquinoline; NSC 9850; b-Naphthoquinoline |
Density: | 1.187g/cm3 |
Melting Point: | 89-91 °C |
Boiling Point: | 349 °C (721 mmHg) |
Flash Point: | 166 °C |
Solubility: | Insoluble in water |
Appearance: | BROWN CRYSTALLINE POWDER |
Hazard Symbols: | |
Risk Codes: | 40-36/37/38 |
Safety: | Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. |
PSA: | 12.89000 |
LogP: | 3.38800 |
5,6-benzoquinoline N-oxide
benzo[f]quinoline
Conditions | Yield |
---|---|
With Methyl phenyldiazoacetate; copper(II) bis(trifluoromethanesulfonate) In 1,2-dichloro-ethane at 60℃; for 12h; Inert atmosphere; Sealed tube; Molecular sieve; | 92% |
2-(2-methyl-pyridin-3-yl)-benzaldehyde
benzo[f]quinoline
Conditions | Yield |
---|---|
With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; | 80% |
Conditions | Yield |
---|---|
With 2,4,6-trimethyl-pyridine; oxygen; palladium diacetate; trifluoroacetic acid at 150℃; for 16h; Schlenk technique; | 80% |
5,6-benzoquinoline N-oxide
A
benzo[f]quinoline
B
benzoquinolin-1(2H)-one
C
2,3-dihydro-1H-benzindole-3-carbaldehyde
Conditions | Yield |
---|---|
In water at 16℃; Irradiation; | A 3% B 74% C 4% |
benzo[f]quinoline
Conditions | Yield |
---|---|
With phosphoric acid In water; 1,2-dichloro-benzene at 170℃; under 760.051 Torr; for 24h; | 74% |
5,6-benzoquinoline N-oxide
A
benzo[f]quinoline
B
2,3-dihydro-1H-benzindole-3-carbaldehyde
Conditions | Yield |
---|---|
In cyclohexane at 16℃; Irradiation; | A 9% B 66% |
Conditions | Yield |
---|---|
With sulfuric acid at 150℃; |
Benzyl phenyl sulfide
benzoquinoline radical ion
A
benzo[f]quinoline
B
benzyl radical
C
thiophenolate
Conditions | Yield |
---|---|
With tetrabutylammonium perchlorate In N,N-dimethyl-formamide at 25℃; Rate constant; Thermodynamic data; ΔG0, cyclovoltammetry; |
A
phenanthridine
B
benzo[f]quinoline
C
o-terphenyl
D
1,2,3,10b-tetrahydrofluoranthene
Conditions | Yield |
---|---|
With air at 900℃; Condensation; combustion; pyrolysis; PAH formation; Formation of xenobiotics; Further byproducts given. Title compound not separated from byproducts; | A 0.04 mg B 0.12 mg C 0.19 mg D 0.16 mg |
2-[(E)-2-phenylethenyl]pyridine
A
benzo[f]quinoline
B
(Z)-2-(2-phenylethenyl)pyridine
C
rac-2,2'-((1R,2R,3S,4S)-2,4-diphenylcyclobutane-1,3-diyl)dipyridine
Conditions | Yield |
---|---|
With cyclomaltooctaose Product distribution; Further Variations:; Reagents; Solvents; Dimerization; Isomerization, Aromatization; Irradiation; |
IUPAC Name: Benzo[f]quinoline
Synonyms: beta-Naphthoquinoline ; Benzo[f]quinoline ; b-Naphthoquinoline ; Naphthopyridine ; 1-Azaphenanthrene ; 5,6-Benzo(f)quinoline ; 5,6-benzoquinoline
CAS NO: 85-02-9
Molecular Formula of Benzo[f]quinoline (CAS NO.85-02-9) : C13H9N
Molecular Weight of Benzo[f]quinoline (CAS NO.85-02-9) : 179.22
Molecular Structure of Benzo[f]quinoline (CAS NO.85-02-9) :
EINECS: 201-582-0
Mol File: 85-02-9.mol
Merck : 1105
Index of Refraction: 1.726
Surface Tension: 54 dyne/cm
Density: 1.187 g/cm3
Flash Point: 155.9 °C
Enthalpy of Vaporization: 57.15 kJ/mol
Boiling Point: 350.4 °C at 760 mmHg
Vapour Pressure: 8.89E-05 mmHg at 25°C
Melting point: 89-91 °C
Appearance:Yellow crystals or white powder
Benzo[f]quinoline (CAS NO.85-02-9) is use as raw materials of organic synthesis .
1. | mma-sat 50 µg/plate | 50NNAZ Polynuclear Aromatic Hydrocarbons: Mechanisms, Methods and Metabolism, Papers of the 8th International Symposium, Columbus, OH, 1983. 7 (1983),73. | ||
2. | pic-esc 7500 ng/well | MUREAV Mutation Research. 260 (1991),349. |
EPA Genetic Toxicology Program.
Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes Xn
Risk Statements 40-36/37/38
S40:To clean the floor and all objects contaminated by this material, use .... (there follows suitable cleaning material).
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 45-36/37/39-26
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RTECS DK1428000
1.General Description :Yellow crystals or white powder. Characteristic irritating odor.
2.Air & Water Reactions: Sensitive to prolonged exposure to air. Insoluble in water.
Reactivity Profile : 5,6-Benzoquinoline neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.
3.Fire Hazard : 5,6-Benzoquinoline is combustible.