Name: 1-Butamine 4-azide
SKU: 88192-20-5

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Basic Information

Molecular Structure:
CAS No.:	88192-20-5
Name:	1-Butamine 4-azide
Article Data:	24

Formula:	C₄H₁₀N₄
Molecular Weight:	114.15
Synonyms:	1-Butanamine,4-azido;4-Azido-1-butanamine;1-amino-4-azidobutane;4-azido-1-butylamine;6-azidobutylamine;4-azido-butylamine;1-azido-4-aminobutane;
Density:	g/cm³
Boiling Point:	°Cat760mmHg
Flash Point:	°C
PSA:	75.77000
LogP:	1.18866

Synthetic route

Conditions	Yield
With hydrogenchloride; triphenylphosphine In diethyl ether; water; ethyl acetate at 20℃; for 24h;	88%
With hydrogenchloride; water; triphenylphosphine In diethyl ether; ethyl acetate at 0 - 20℃; for 25h;	88%
With hydrogenchloride; triphenylphosphine In diethyl ether; water; ethyl acetate at 0 - 20℃; for 25h; Inert atmosphere;	88%

Conditions	Yield
With sodium hydroxide In tetrahydrofuran for 4h; Heating;	83%

Conditions	Yield
With hydrazine hydrate In ethanol for 24h;	62%
With hydrazine hydrate In tetrahydrofuran at 60℃; for 4h;
With hydrazine In methanol Inert atmosphere;

Conditions	Yield
With triflic azide; potassium carbonate; copper(II) sulfate In methanol; water	61%

Conditions	Yield
With sodium azide In water at 80℃; for 15h;	50%

Conditions	Yield
With triflic azide; potassium carbonate; copper(II) sulfate In water for 18h; Inert atmosphere;	A 30% B 40%

Conditions	Yield
With hydrogenchloride In ethyl acetate at 20℃; for 72h;
With trifluoroacetic acid In dichloromethane at 20℃; for 16h;

Conditions	Yield
With hydrogenchloride; water In diethyl ether; hexane at 0℃; modified Staudinger reaction;

Conditions	Yield
With sodium azide In water; N,N-dimethyl-formamide at 80 - 85℃; for 8h;	343.7 g
Stage #1: 1,4-dibromo-butane With sodium azide In water; N,N-dimethyl-formamide at 80 - 90℃; for 12h; Stage #2: With hydrogenchloride; triphenylphosphine In water at 25 - 35℃; for 12h;