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| CAS No.: | 90-01-7 |
|---|---|
| Name: | 2-Hydroxybenzyl alcohol |
| Molecular Structure: | |
|
|
|
| Formula: | C7H8O2 |
| Molecular Weight: | 124.139 |
| Synonyms: | Benzylalcohol, o-hydroxy- (8CI);1-(o-Hydroxyphenyl)methanol;2-Hydroxybenzenemethanol;2-Hydroxymethylphenol;2-Methylolphenol;Diathesin;NSC 3814;Salicyl alcohol;Salicylicalcohol;Saligenin;Saligenol;o-(Hydroxymethyl)phenol;o-Hydroxybenzylalcohol;o-Methylolphenol;a,2-Dihydroxytoluene;a-Hydroxy-o-cresol; |
| EINECS: | 201-960-5 |
| Density: | 1.22 g/cm3 |
| Melting Point: | 83-85 °C(lit.) |
| Boiling Point: | 267.5 °C at 760 mmHg |
| Flash Point: | 133.7 °C |
| Solubility: | water: 67 g/L (22 °C) |
| Appearance: | light brown crystalline powder |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 26-36 |
| PSA: | 40.46000 |
| LogP: | 0.88450 |
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| Conditions | Yield |
|---|---|
| With dihydrogen peroxide In tetrahydrofuran; water; acetic acid for 30h; Ambient temperature; | 100% |
| Conditions | Yield |
|---|---|
| Stage #1: methyl salicylate With lithium aluminium tetrahydride In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; Stage #2: With hydrogenchloride In tetrahydrofuran; water; ethyl acetate at 0℃; Inert atmosphere; | 100% |
| With lithium aluminium tetrahydride In 2-methyltetrahydrofuran at -15 - 20℃; for 24.16h; | 93% |
| With zinc(II) tetrahydroborate; cyclohexene In tetrahydrofuran for 4h; Heating; | 70% |
| With lithium aluminium tetrahydride In diethyl ether | |
| With C21H24N4Ru(1+)*F6P(1-); potassium tert-butylate; hydrogen In tetrahydrofuran at 50℃; under 18751.9 Torr; for 4h; Catalytic behavior; |
| Conditions | Yield |
|---|---|
| With tri-n-butyl-tin hydride In methanol; diethyl ether for 4h; Reduction; Heating; | 100% |
| With N-methylpyrrolidine zinc borohydride In tetrahydrofuran at 20℃; for 0.166667h; | 100% |
| With Zr(BH4)2Cl2(dabco)2 In water for 0.8h; Heating; | 93% |
- 90-01-7
salicylic alcohol
| Conditions | Yield |
|---|---|
| With water | 100% |
| Conditions | Yield |
|---|---|
| With formic acid; C20H29ClIrN4(1+)*Cl(1-) In water at 80℃; for 0.166667h; chemoselective reaction; | 99% |
| With hydrogen for 0.583333h; | 98% |
| With (7,8-benzoquinolinato)hydrido(aqua)bis(triphenylphosphine)iridium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen; N-ethyl-N,N-diisopropylamine In toluene at 80℃; under 760.051 Torr; for 4h; | 98% |
- 82112-31-0
1-(tert-butyldimethylsilanyloxy)-2-(tert-butyldimethylsilanyloxymethyl)benzene
- 90-01-7
salicylic alcohol
| Conditions | Yield |
|---|---|
| With phosphomolybdic acid hydrate; silica gel In tetrahydrofuran at 20℃; for 18h; | 99% |
| With tetrabutyl ammonium fluoride In tetrahydrofuran at 0℃; for 0.25h; |
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate; Trimethyl borate; dimethyl sulfate In tetrahydrofuran at 20℃; for 4.5h; Product distribution; Further Variations:; Reagents; reagent ratios; | 98% |
| With [Zn(BH4)2(py)] In tetrahydrofuran for 1.5h; Heating; | 93% |
| With lithium aluminium tetrahydride In diethyl ether at 23℃; for 5h; Inert atmosphere; | 93% |
- 18544-92-8
1-Trimethylsilanyloxy-2-trimethylsilanyloxymethyl-benzene
- 90-01-7
salicylic alcohol
| Conditions | Yield |
|---|---|
| With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0666667h; Green chemistry; | 98% |
| With Nafion-H(R); silica gel In hexane at 20℃; for 0.5h; | 95% |
| With montmorillonite K-10 In methanol for 0.7h; Ambient temperature; | 90% |
| With nano magnetic sulfated zirconia (Fe3O4 at ZrO2/SO42-) In neat (no solvent) at 20℃; for 0.833333h; Green chemistry; | 80% |
- 1058648-87-5
2-((methoxymethoxy)methyl)phenol
- 90-01-7
salicylic alcohol
| Conditions | Yield |
|---|---|
| phosphotungstic acid In ethanol for 2h; Heating; | 96% |
| With 1-methylimidazole hydrogen sulfate at 120℃; for 0.0416667h; Microwave irradiation; chemoselective reaction; | 90% |
- 1058648-91-1
2-[(ethoxymethoxy)methyl]phenol
- 90-01-7
salicylic alcohol
| Conditions | Yield |
|---|---|
| With 1-methylimidazole hydrogen sulfate at 120℃; for 0.0333333h; Microwave irradiation; chemoselective reaction; | 94% |
| phosphotungstic acid In ethanol for 3.5h; Heating; | 90% |
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Chemistry
2-HYDROXYMETHYLPHENOL(90-01-7) is an organic compound with the formula of C7H8O2 ,its chemical name is 2-Hydroxybenzyl alcohol and the formula weight is 124.14g/mol
CAS No.: 90-01-7
EINECS: 201-960-5
RTECS: DO6430000
RTECS Class: Reproductive Effector
IUPAC NAME: 2-(hydroxymethyl)phenol
Chemical Structure:
The chemical synonymous of 2-HYDROXYMETHYLPHENOL(90-01-7) are 2-Dihydroxytoluene;2-hydroxy-benzenemethano;2-Hydroxybenzenemethanol;2-hydroxy-Benzenemethanol;2-Hydroxymethylphenol;alpha,2-Dihydroxytoluene;alpha-Hydroxy-o-cresol;Benzenemethanol, 2-hydroxy- and so on.
The density of 2-HYDROXYMETHYLPHENOL(90-01-7) is 1,613 g/cm3and it has a melting point of 83-85 °C(lit.).The boiling point is 267.5 °C at 760 mmHg.Its flash point is 133.7 °C.The water solubility should be equal to 67 g/L (22 oC).
Appearance: light brown crystalline powder
History
Product Categories about 2-HYDROXYMETHYLPHENOL(90-01-7) is mainly Aromatics .
Uses
2-HYDROXYMETHYLPHENOL(90-01-7) is used for the pharmaceutical industry and used as a medicine, perfume, pesticide intermediates
Consensus Reports
Safety Profile
An experimental teratogen. Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:
Xi: Irritant 
Risk Statements about 2-HYDROXYMETHYLPHENOL(90-01-7):
R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Statements about 2-HYDROXYMETHYLPHENOL(90-01-7):
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 Wear suitable protective clothing.
Specification
Stability: Stable. Incompatible with acids, acid chlorides, acid anhydrides, strong oxidizing agents.
Storage:Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling:Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Fire Fighting:Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.Use agent most appropriate to extinguish fire.