10181-56-3Relevant articles and documents
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Elam,Davis
, p. 1562,1564 (1967)
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Photochemistry of Dimethylthioketene Dimers
Muthuramu, Kayambu,Ramamurthy, Vaidhyanathan
, p. 4532 - 4533 (1980)
Thioketones and dithioesters, using 1,3-cyclobutanedithione and 3-mercapto-2,2,4-trimethyldithio-3-pentenoic acid β-thiolactone as models are found to undergo α-cleavage to give the diradical and carbene as reactive intermediates.
Expected and unexpected results in reactions of fluorinated nitrile imines with (cyclo)aliphatic thioketones
Utecht, Greta,Sioma, Justyna,Jasiński, Marcin,Mlostoń, Grzegorz
, p. 68 - 75 (2017/09/11)
A series of (cyclo)aliphatic thioketones have been tested towards trifluoroacetonitrile imines, generated in situ via base-induced dehydrohalogenation of the respective hydrazonoyl bromides. Typically, non-enolisable thioketones yielded exclusively 3-trif
Addition reactions of sulfenyl and sulfinyl chlorides with 3-phenyl-1-azabicyclo[1.1.0]butane
Mloston, Grzegorz,Woznicka, Marta,Drabowicz, Jozef,Linden, Anthony,Heimgartner, Heinz
experimental part, p. 1419 - 1429 (2009/02/07)
The reactions of 3-phenyl-1-azabicyclo[1.1.0]butane with α-chlorosulfenyl chlorides and sulfinyl chlorides lead to the corresponding sulfenamides and sulfinamides, respectively, which possess an azetidine ring. It is proposed that a two-step mechanism occurs involving an intermediate carbenium ion, which is formed by the addition of the electrophile at the N-atom and cleavage of the N(1)-C(3) bond. The structures of 9b and 10b are established by X-ray crystallography.