1119-67-1Relevant articles and documents
An easy preparation of iodoacetylenes
Brunel, Yves
, p. 2619 - 2622 (1995)
Reaction of terminal acetylenes with bis(sym-collidine)iodine(I) hexafluorophosphate in methylene chloride leads in good yields to the formation of iodoacetylenes.
Pd(0)-catalyzed iodoalkynation of norbornene scaffolds: The remarkable solvent effect on reaction pathway
Liu, Hui,Chen, Chen,Wang, Limin,Tong, Xiaofeng
, p. 5072 - 5075 (2011)
A palladium-catalyzed iodoalkynation of norbornene has been realized with the use of alkynyl iodides 1, which is found to be strongly solventdependent. MeCN favors 1,7-iodoalkylation product 3 while CCl4 leads to 1,2-iodoalkylation product 4.
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Dieck,H.A.,Heck,R.F.
, p. 1083 - 1090 (1975)
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Unsymmetrically substituted aliphatic diacetylenes
Barbu, Eugen,Tsibouklis, John
, p. 5023 - 5026 (1996)
A general method for the synthesis of pure samples of unsymmetrically disubstituted diacetylenes of the type CH3-(CH2)(n)-C=C=C=C-CH2-OH (n=2,3,4,5) is described in detail. The materials could be polymerized thermally, in the liquid state.
COMPOUNDS, COMPOSITIONS, AND METHODS FOR MODULATING FERROPTOSIS AND TREATING EXCITOTOXIC DISORDERS
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Paragraph 0164; 0180, (2020/06/19)
The present disclosure provides, inter alia, a compound having the structure (1). Also provided are compositions containing a pharmaceutically acceptable carrier and one or more compounds according to the present disclosure. Further provided are methods f
Annulation-Induced Cascade Transformation of 5-Iodo-1,2,3-triazoles to 2-(1-Aminoalkyl)benzoxazoles
Kotovshchikov, Yury N.,Latyshev, Gennadij V.,Navasardyan, Mger A.,Erzunov, Dmitry A.,Beletskaya, Irina P.,Lukashev, Nikolay V.
supporting information, p. 4467 - 4470 (2018/08/09)
Base-mediated cyclization of (5-iodo-1,2,3-triazolyl)phenols was proposed as a new synthetic strategy for the in situ generation of diazoimines via electrocyclic ring opening of the fused heterocycle. Cu-catalyzed amination of the intermediate diazoalkanes was employed to develop an efficient cascade approach to functionalized benzoxazoles.