16737-30-7Relevant articles and documents
A Polymer-Bound 4-Aminopyridine: Synthesis and Reactivity
Menger, F. M.,McCann, D.J.
, p. 3928 - 3930 (1985)
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Cope et al.
, p. 1750,1751 (1960)
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Isopropenyl acetate: A cheap and general acylating agent of alcohols under metal-free conditions
Temperini, Andrea,Minuti, Lucio,Morini, Tommaso,Rosati, Ornelio,Piazzolla, Francesca
, p. 4051 - 4053 (2017/09/27)
Functionalized primary, secondary and tertiary alcohols are efficiently acetylated by isopropenyl acetate and catalytic p-TsOH.
Iron(III) tosylate catalyzed acylation of alcohols, phenols, and aldehydes
Baldwin, Neil J.,Nord, Anna N.,O'Donnell, Brendan D.,Mohan, Ram S.
, p. 6946 - 6949 (2013/01/15)
Iron(III) p-toluenesulfonate (tosylate) is an efficient catalyst for acetylation of alcohols, phenols, and aldehydes. The acetylation of 1° and 2° alcohols, diols, and phenols proceeded smoothly with 2.0 mol % of catalyst. However, the reaction worked well with only a few 3° alcohols. The methodology was also applicable to the synthesis of a few benzoate esters but required the use of 5.0 mol % catalyst. Aldehydes could also be converted into the corresponding 1,1-diesters (acylals) under the reaction conditions. Iron(III) tosylate is an inexpensive, and easy to handle, commercially available catalyst.
