17799-96-1Relevant articles and documents
A convenient synthesis of 1H-2,3-benzoxazines by an acid-catalyzed intramolecular Mitsunobu reaction
Kai, Hiroyuki,Nakai, Toru
, p. 6895 - 6897 (2001)
A convenient, efficient method for the preparation of benzoxazines is described. 2-(Hydroxyiminomethyl)benzyl alcohols were cyclodehydrated to construct 1H-2,3-benzoxazines by acid-catalyzed intramolecular Mitsunobu reaction. This reaction depended on the
Iridium-Catalyzed Acid-Assisted Hydrogenation of Oximes to Hydroxylamines
Cope, Christopher J.,Cramer, Nicolai,Mas-Roselló, Josep,Pinson, Benjamin,Robinson, Alan,Smejkal, Tomas,Tan, Eric
supporting information, p. 15524 - 15532 (2021/06/11)
We found that cyclometalated cyclopentadienyl iridium(III) complexes are uniquely efficient catalysts in homogeneous hydrogenation of oximes to hydroxylamine products. A stable iridium C,N-chelation is crucial, with alkoxy-substituted aryl ketimine ligand