1001-62-3

Usage

Uses

Used in Chemical Synthesis:
Dimethanesulfonyl peroroxyde is used as a powerful oxidizing agent for the synthesis of organic compounds. It is particularly effective in the oxidation of sulfides to sulfoxides and for the cleavage of certain functional groups, making it a valuable tool in the development of new chemical products.
Used in Polymerization Reactions:
In the polymer industry, Dimethanesulfonyl peroroxyde is used as an initiator for polymerization reactions. Its ability to release free radicals makes it an effective catalyst for the formation of polymer chains, contributing to the production of various polymer-based materials.
Used in Industrial Processes:
Dimethanesulfonyl peroroxyde is employed in various industrial processes, where its strong oxidizing properties are harnessed to facilitate specific chemical transformations. Its use in these applications can lead to improved efficiency and product quality.
Used in Research and Development:
In the field of scientific research, Dimethanesulfonyl peroroxyde is used as a reagent in the exploration of new chemical reactions and mechanisms. Its unique properties make it a valuable asset in the development of novel compounds and materials.

InChI:InChI=1/C2H6O6S2/c1-9(3,4)7-8-10(2,5)6/h1-2H3

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 75-75-2 methanesulfonic acid 

Downstream Products

• 66178-40-3 O-deuterio-methanesulfonic acid 
• 130351-44-9 C₃H₃⁽²⁾H₂NO₃S 
• 7143-01-3 Methanesulfonic anhydride 
• 75-75-2 methanesulfonic acid 
• 16156-56-2 cyclohexyl mesylate 
• 35822-90-3 benzoyl-tert-butylnitroxyl radical 
• 75-07-0 acetaldehyde 
• 64-19-7 acetic acid 
• 71-43-2 benzene 
• 110-61-2 butanedinitrile 
• 3586-51-4 methanesulfonyloxyacetonitrile 
• 16156-59-5 phenyl methanesulfonate 
• 1064138-56-2 1-phenylbut-3-enyl methanesulfonate 
• 10090-05-8 trimethylsilyl methanesulfonate 

Relevant academic research and scientific papers

Late-Stage Aromatic C-H Oxygenation

Synthetic methods for oxidative aromatic C-O bond formation are sparse, despite their demand in metabolite synthesis for drug discovery and development. We report a novel methodology for late-stage C-O bond formation of arenes. The reaction proceeds with excellent functional group tolerance even for highly functionalized substrates. The resulting aryl mesylates provide access to potential human metabolites of pharmaceuticals, and may be used directly to install a C-F bond to block metabolic hotspots. A charge-transfer interaction between the reagent bis(methanesulfonyl) peroxide and the substrate arenes may be relevant for the chemoselective functionalization of arenes over other functional groups.

PROCESS FOR PREPARING BIS(ALKANESULFONYL PEROXIDE)

A process for preparing bis(alkanesulfonyl)peroxide of the formula (I), in which ALK represents an alkyl group, characterized by the following process steps: a)mixing an alkylsulfonic acid chloride in a reaction vessel; b)with an excess of a peroxide-containing compound; c)optionally adding a basic compound if hydrogen peroxide is employed; d)allowing the mixture to react; adding water to terminate the reaction; and e)separating the reaction product obtained, bis(alkanesulfonyl)peroxide.