100114-07-6Relevant articles and documents
Synthesis and thermal transformations of 5-nitropyrimidin-4-yl dialkyldithiocarbamates
Ryabova,Makarov,Chernyshev,Granik
, p. 882 - 888 (2004)
On heating, 5-nitropyrimidin-4-yl dialkyldithiocarbamates undergo two types of transformations. One type of these transformations involves intramolecular ipso-substitution of the nitro group to form bis(4- dialkylcarbamoylthiopyrimidin-5-yl) disulfides, whereas another type of transformations involves elimination of carbon disulfide to give 4,6-diamino-5-nitropyrimidine derivatives. The reaction pathway is controlled by the steric effect of the substituent at position 6 of the pyrimidine ring.
