10031-27-3Relevant articles and documents
Stability limits and properties of Tl2TeBr6, Cs 2TeBr6, and Rb2TeBr6
Peresh,Zubaka,Kun,Galagovets,Barchii,Sabov
, p. 849 - 852 (2001)
The composition stability limits of the compounds Tl2TeBr 6, Cs2TeBr6, and Rb2TeBr6 were determined from differential thermal analysis, microstructural, and microhardness data. The congruen
Druce, P. M.,Lappert, M. F.
, (1971)
Solvothermal synthesis and crystal structure of Te8[U2Br10], containing a polymeric chalcogen cation (Te82+)n
Beck,Fischer
, p. 369 - 372 (2008/10/08)
Under solvothermal conditions, the reaction of Te, TeBr4 and UBr5 in SiBr4 at 200°C yields Te8[U2Br10] as silvery crystals. The crystal structure (triclinic, P1, a = 900.8(4), b = 1205.1(5), c = 1366.0(6) pm, α = 80.93(4)°, β = 76.83(3)°, γ = 78.84(3)°, Z = 2) is built of one-dimensional polymeric (Te82+)n cations consisting of boat-shaped Te6 rings, which are linked by Te2 bridges. The anions [U2Br102-]n are also polymeric, consisting of edge sharing UBr7 pentagonal bipyramids [UBr3Br4/22-]n and contain U(IV). Both chains are parallel to each other and run along the crystallographic a-axis. The cation represents a formerly unknown isomer of Te82+ ions. So far, Te82+ has been known as molecular clusters in Te8[MCl6] (M = Zr, Hf, Re) and (Te8)(Te6)[WCl6]4, or in form of linked bicyclic monomers that are present in Te8[WCl6]2. A polymeric chain-like form closely related to Te8[U2Br10] was found in Te8[Bi4Cl14].