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10060-11-4

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10060-11-4 Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 10060-11-4 differently. You can refer to the following data:
1. white powder(s); unstable; decomposes into polymer subchloride at low temp [MER06] [HAW93]
2. Germanium(II) hydroxide, Ge(OH)2, is obtained by action of alkali hydroxides upon germanium(II) chloride, GeCl2, solutions; it is amphiprotic, dissolving in excess of the alkali. Moreover, the acid form, sometimes called germanous acid, is obtained upon heating the hydroxide: Ge(OH)2 HGe(O)H.

Check Digit Verification of cas no

The CAS Registry Mumber 10060-11-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,6 and 0 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 10060-11:
(7*1)+(6*0)+(5*0)+(4*6)+(3*0)+(2*1)+(1*1)=34
34 % 10 = 4
So 10060-11-4 is a valid CAS Registry Number.
InChI:InChI=1/Cl2Ge/c1-3-2

10060-11-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name dichlorogermanium

1.2 Other means of identification

Product number -
Other names Dichlorogermylene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10060-11-4 SDS

10060-11-4Synthetic route

diazoacetic acid ethyl ester
623-73-4

diazoacetic acid ethyl ester

Triethylgerman
1188-14-3

Triethylgerman

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

A

germanium dichloride
10060-11-4

germanium dichloride

B

triethyl(phenyl)germane
2817-41-6

triethyl(phenyl)germane

C

tetraphenylgermane
1048-05-1

tetraphenylgermane

Conditions
ConditionsYield
In pentane byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe;A 57%
B n/a
C n/a
germanium
7440-56-4

germanium

Iodine monochloride
7790-99-0

Iodine monochloride

A

germanium monochloride
21110-21-4

germanium monochloride

B

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
In gas Kinetics; metals were vaporized in a high temperature beam and the vapor were collimated upon entering a separatly pumped chamber filled with halogen; chemiluminescence spectroscopy;
germanium(II) sulfide

germanium(II) sulfide

lead(II) chloride

lead(II) chloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
excess of GeS;
germanium
7440-56-4

germanium

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
350-400°C;
hexachlorodisilane
13465-77-5

hexachlorodisilane

germaniumtetrachloride
10038-98-9

germaniumtetrachloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
In neat (no solvent, gas phase) at 550°C; detn. by chemical trapping;
germanium hydride trichloride
1184-65-2

germanium hydride trichloride

germanium dichloride
10060-11-4

germanium dichloride

Conditions
ConditionsYield
byproducts: HCl; thermal decompn.;

10060-11-4Downstream Products

10060-11-4Relevant articles and documents

Jonkers, G.,Kerk, S. M. van der,Lange C. A. de

, p. 69 - 76 (1982)

ASSISTANCE NUCLEOPHILE DANS DES REACTIONS DE REDUCTION D'ORGANOHALOGENO- ET HALOGENO-GERMANES PAR DES REDUCTEURS DOUX R3M(IVB)-H ET RCHO: GERMYLANIONS, DERIVES FONCTIONNELS DU GERMANIUM

Castel, A.,Riviere, P.,Satge, J.

, p. 137 - 146 (2007/10/02)

Catalytic activity of nuclophiles such as tertiary amines and diazo derivatives in the reduction of halogermanes by means of gentle reductive agents, such as R3M(IVB)-H or RCHO, has been shown.In the particular case of enolisable aldehyde, a competition between nucleophilic substitution at the metal and germanium-halogen bond reduction has been observed.Transposition of enoxygermanes formed through the substitution process, leads to β-germylaldehydes.

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