Unii-SI7jkx4F22

Base Information

• Chemical Name: Unii-SI7jkx4F22
• CAS No.: 10060-11-4
• Molecular Formula: Cl2Ge
• Molecular Weight: 143.496
• European Community (EC) Number: 233-192-1
• DSSTox Substance ID: DTXSID40143425,DTXSID80164992
• Wikidata: Q2331626
• Mol file: 10060-11-4.mol

Synonyms:10060-11-4;GeCl2;UNII-SI7JKX4F22;EINECS 233-192-1;Cl2Ge;Cl2-Ge;DTXSID40143425;DTXSID80164992;CID 6327122;Germanium chloride (GeCl2) (6CI,8CI,9CI);Q2331626

Chemical Property of Unii-SI7jkx4F22

Chemical Property:

• Melting Point: 110-165°C (dec.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 18.46000
• Density: g/cm³
• LogP: 1.25640
• Water Solubility.: decomposes in H2O; soluble ether, benzene; insolublealcohol and chloroform [HAW93] [MER06]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 143.8588831
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

DICHLOROGERMADIYL DIOXANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Cl[Ge]Cl

Technology Process of Unii-SI7jkx4F22

There total 6 articles about Unii-SI7jkx4F22 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

diazoacetic acid ethyl ester (623-73-4) + Triethylgerman (1188-14-3) + germaniumtetrachloride (10038-98-9) + phenylmagnesium bromide (100-58-3) → germanium dichloride (10060-11-4) + triethyl(phenyl)germane (2817-41-6) + tetraphenylgermane (1048-05-1)

Guidance literature:

In pentane; byproducts: N2; 1 equiv of diazoester adding to a soln. of equimolar mixt. of Ge derivs., allowing to stand for 48 h at 20°C, orange-red oil decanting, PhMgBr adding to a supernatant; identified as adduct with ClCH2OMe;

DOI:10.1016/S0022-328X(00)87640-8

Reference yield:

germanium (7440-56-4) + Iodine monochloride (7790-99-0) → germanium monochloride (21110-21-4) + germanium dichloride (10060-11-4)

Guidance literature:

In gas; metals were vaporized in a high temperature beam and the vapor were collimated upon entering a separatly pumped chamber filled with halogen; chemiluminescence spectroscopy; Kinetics;

DOI:10.1063/1.456952

Reference yield:

hexachlorodisilane (13465-77-5) + germaniumtetrachloride (10038-98-9) → germanium dichloride (10060-11-4)

Guidance literature:

In neat (no solvent, gas phase); at 550°C; detn. by chemical trapping;

upstream raw materials:

germanium

Iodine monochloride

lead(II) chloride

germaniumtetrachloride

Refernces

• 1、 Wang,Cheong,Parson. "Chemiluminescent reactions of ground and metastable states of the group IV a elements with halogens". . p. 2834 - 2839. Retrieved 2007/10/02.