100668-78-8

Basic information

• Product Name: (+/-)-leucoperezone trimethyl ether
• Synonyms: (+/-)-leucoperezone trimethyl ether
• CAS NO: 100668-78-8
• Molecular Weight: 292.419
• Mol File: 100668-78-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (+/-)-leucoperezone trimethyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-leucoperezone trimethyl ether(100668-78-8)
• EPA Substance Registry System: (+/-)-leucoperezone trimethyl ether(100668-78-8)

Safety Data

• Hazardous Substances Data: 100668-78-8(Hazardous Substances Data)

Upstream product

• 100668-77-7 (+/-)-8-hydroxyleucoperezone 
• 110-93-0 6-Methyl-hept-5-en-2-on 
• 180303-11-1 Trifluoro-methanesulfonic acid 5-methyl-1-methylene-hex-4-enyl ester 
• 93092-14-9 1-bromo-5-hydroxy-2,3-dimethoxybenzene 
• 100668-76-6 Formic acid 3-bromo-4,5-dimethoxy-phenyl ester 
• 78312-28-4 5-nitro-2,3-dimethoxytoluene 
• 100668-75-5 3,4-dimethoxy-5-methylphenol 
• 86232-53-3 3-Methyl-4,5-dimethoxyaniline 
• 6948-30-7 5-bromoveratralaldehyde 
• 23030-39-9 1-bromo-2,3,5-trimethoxybenzene 
• 2973-76-4 5-bromo-4-hydroxy-3-methoxybenzaldehyde 
• 4463-33-6 1,2-dimethoxy-3-methylbenzene 

Downstream Products

• 3600-95-1 (-)-perezone 
• 100761-40-8 (+/-)-2-(1,5-dimethyl-4-hexenyl)-3-methoxy-5-methyl-2,5-cyclohexadiene-1,4-dione <(+/-)-O-methylperezone> 

Relevant articles and documents

Total Synthesis of (?)-Perezoperezone through an Intermolecular [5+2] Homodimerization of Hydroxy p-Quinone

The first copper-catalyzed intermolecular [5+2] homodimerization of hydroxy p-quinone is presented, furnishing bicyclo[3.2.1]octadienone core structures in typically good yields and excellent diastereoselectivities. Applying this synthetic approach enables a concise nine-step total synthesis of (?)-perezoperezone from commercially available 3,5-dimethoxytoluene.