100726-41-8

Basic information

• Product Name: (1H-benzo[d][1,2,3]triazol-1-yl)methyl benzoate
• Synonyms: (1H-benzo[d][1,2,3]triazol-1-yl)methyl benzoate
• CAS NO: 100726-41-8
• Molecular Weight: 253.26
• Mol File: 100726-41-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (1H-benzo[d][1,2,3]triazol-1-yl)methyl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1H-benzo[d][1,2,3]triazol-1-yl)methyl benzoate(100726-41-8)
• EPA Substance Registry System: (1H-benzo[d][1,2,3]triazol-1-yl)methyl benzoate(100726-41-8)

Safety Data

• Hazardous Substances Data: 100726-41-8(Hazardous Substances Data)

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 5342-31-4 bis(benzoyloxy)methane 
• 532-32-1 sodium benzoate 
• 54187-96-1 1-(chloromethyl)-1H-benzotriazole 
• 75-09-2 dichloromethane 
• 4231-62-3 1-benzoyl-1H-benzotriazole 
• 28539-02-8 1-Hydroxymethyl-1H-benzotriazole 
• 98-88-4 benzoyl chloride 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 95-14-7 1,2,3-Benzotriazole 
• 94-47-3 2-Phenylethyl benzoate 
• 28539-02-8 1-Hydroxymethyl-1H-benzotriazole 
• 100-51-6 benzyl alcohol 
• 134240-72-5 hept‐2‐yn‐1‐yl benzoate 
• 37559-19-6 3-(phenyl)prop-2-yn-1-yl benzoate 
• 60-12-8 2-phenylethanol 
• 5472-27-5 1,2,3-triphenyl-propan-2-ol 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 60045-26-3 3-phenylpropyl benzoate 

Relevant articles and documents

Novel synthesis of benzotriazolyl alkyl esters: an unprecedented CH2insertion

We have developed a novel method for the synthesis of benzotriazolyl alkyl esters (BAEs) fromN-acylbenzotriazoles and dichloromethane (DCM) under mild conditions. This reaction is one of few examples to show the use of DCM as a C-1 surrogate in carbon-heteroatom bond formation and to highlight the versatility of using DCM as a methylene building block.

A novel synthesis of esters via substitution of the benzotriazolyl group in 1-(benzotriazol-1-yl)alkyl esters with organozinc reagents

Aldehydes are converted by thionyl chloride and benzotriazole into 1-(1-chloroalyl)benzotriazoles which react with sodium carboxylates to give 1-(benzotriazol-1-yl)alkyl esters. 3. In the alternative route, 3 are prepared by substitution of one of the acetoxy groups in acylals with benzotriazole. The benzotriazolyl moiety in 3 is substituted by an alkyl, an aryl or an alkynyl group upon treatment with an organic reagent in a new versatile synthesis of esters 4.