1020-49-1

Usage

Physical form

white to light brown crystalline powder

Odor

faint

Usage

reagent in organic synthesis, intermediate in production of pharmaceuticals and agrochemicals

Known for

acting as a catalyst in chemical reactions

Used in production of

saquinavir (HIV protease inhibitor), insecticides, herbicides

Stability

stable under normal conditions

Upstream product

• 110-89-4 piperidine 
• 62790-85-6 tert-Butyl(dimethyl)-(4-methylphenoxy)silane 
• 330-00-7 Phenyl fluorosulfonate 
• 108-95-2 phenol 
• 16475-29-9 phenylchlorosulfate 
• 66950-63-8 phenyl N,N-dimethylsulfamate 
• 35856-62-3 1-piperidinesulfonyl chloride 

Relevant academic research and scientific papers

SuFEx-based synthesis of polysulfates

High-molecular-weight polysulfates are readily formed from aromatic bis(silyl ethers) and bis(fluorosulfates) in the presence of a base catalyst. The reaction is fast and proceeds well under neat conditions or in solvents, such as dimethyl formamide or N-methylpyrrolidone, to provide the desired polymers in nearly quantitative yield. These polymers are more resistant to chemical degradation than their polycarbonate analogues and exhibit excellent mechanical, optical, and oxygen-barrier properties. High-molecular-weight polysulfates are readily formed from aromatic bis(silyl ethers) and bis(fluorosulfates) in the presence of a base catalyst. The polymers were obtained in nearly quantitative yield under neat conditions, they are more resistant to chemical degradation than their polycarbonate analogues and exhibit excellent mechanical, optical, and oxygen-barrier properties. BPA=bisphenol A.

LES SYSTEMES BIPHASIQUES. 7. SYNTHESE DE SULFAMATES SIMPLES ET N-SUBSTITUES DANS LES CONDITIONS DE TRANSFERT DE PHASE LIQUIDE-LIQUIDE

We report the very facile and convenient syntheses of sulfamate esters of the general structures R-O-SO2-NH2 and R-O-SO2-NR1R2 respectively by reduction of aryloxysulfonyl azides and by reaction of amine N-sulfonyl chlorides with phe

Betylates. 1. Synthesis and reactions of an isolable betylate, N,N-dimethyl-N-(phenoxysulfonyl)methanaminium fluorosulfate

Phenyl betylate fluorosulfate (2), the first example of a "betylate" (trialkylammoniosulfate ester), has been prepared by methylation of phenyl N,N-dimethylsulfamate with methyl fluorosulfate.Nucleophiles react with 2 either by attack on the sulfur or methyl carbon atoms, but with no sign of any products derived from benzyne or the phenyl cation.A synthesis of enol N,N-dimethylsulfamates has been devised using a reagent, Me2NSO2N(1+)Me3 FSO3(1-), prepared from tetramethylsulfamide and methyl fluorosulfate, but no satisfactory method was found for converting the sulfamic ester to the betylate.Evidence is presented that phenyl chlorosulfate reacts with trimethylamine to give the phenylbetylate which then undergoes further reaction.