102340-69-2Relevant articles and documents
Continuous flow biocatalytic resolutions of methyl sulfinylacetates
Liu, Zhanxiang,Burgess, Kevin
, p. 6325 - 6327 (2012/01/02)
Product inhibition was encountered for some substrates in the resolution of methyl sulfinylacetates mediated by lipase Amano AK, so an apparatus to continually extract the carboxylate product was devised. This was applied to resolve some sulfoxides with h
Double diastereodifferentiation in the hydroxylative Knovenagel condensation
Trost,Mallart
, p. 8025 - 8028 (2007/10/02)
The stereoinduction in formation of γ-hydroxy-α,β-unsaturated enoates using chiral α-sulfinyl esters and chiral aldehydes is a function of the absolute stereochemistry of the sulfoxide, the substituent on the sulfoxide, and the amount of base.
A FACILE ROUTE TO HOMOCHIRAL SULFOXIDES
Burgess, Kevin,Henderson, Ian
, p. 3633 - 3636 (2007/10/02)
Biocatalytic resolution of methyl sulfinylacetates afford sulfoxides (R)-(1)-(6) in very high optical yields; the products have been used in a systematic study of the "SPAC" reaction, an asymmetric synthesis of γ-hydroxy-α,β-unsaturated esters.
ENZYME MEDIATED SYNTHESIS OF OPTOCALLY ACTIVE ο-ARENESULFINYLALKANOIC ESTERS
Ohta, Hiromichi,Kato, Yasuo,Tsuchihashi, Gen-ichi
, p. 217 - 218 (2007/10/02)
Incubation of methyl arenesulfinylacetates and methyl α-benzenesulfinylpropionate with Corynebacterium equi IFO 3730 afforded the corresponding chiral sulfoxides of high optical purites in moderate to good chemical yields.
