125706-40-3Relevant articles and documents
Biocatalytic Resolutions of Sulfinylalkanoates: A Facile Route to Optically Active Sulfoxides
Burgess, Kevin,Henderson, Ian,Ho, Kwok-Kan
, p. 1290 - 1295 (2007/10/02)
Two methods are presented for kinetic resolutions of compounds containing ester and sulfoxide functionalities (sulfinylalkanoates).In the first a crude lipase preparation from Pseudomonas sp. (K 10) mediates enantioselective hydrolysis of these esters in
A FACILE ROUTE TO HOMOCHIRAL SULFOXIDES
Burgess, Kevin,Henderson, Ian
, p. 3633 - 3636 (2007/10/02)
Biocatalytic resolution of methyl sulfinylacetates afford sulfoxides (R)-(1)-(6) in very high optical yields; the products have been used in a systematic study of the "SPAC" reaction, an asymmetric synthesis of γ-hydroxy-α,β-unsaturated esters.