102608-96-8Relevant academic research and scientific papers
Retro-aldol reactions in micellar media
Vashchenko, Elena V.,Knyazeva, Irina V.,Krivoshey, Alexander I.,Vashchenko, Valerii V.
, p. 1545 - 1549 (2013/02/21)
Convenient methods for retro-aldol reactions of a, β-unsaturated ketones in micellar media under acidic or basic conditions are proposed that enable obtaining optically pure (3R)-methylcyclohexanone and (1R,4R)-4- methylmenthone in high yields. Springer-V
Simple and effective protocol for Claisen-Schmidt condensation of hindered cyclic ketones with aromatic aldehydes
Vashchenko, Valeriy,Kutulya, Lidiya,Krivoshey, Alexander
, p. 2125 - 2134 (2008/03/28)
A simple and effective methodology for Claisen-Schmidt condensation of (-)-menthone and other hindered cyclic ketones with aromatic aldehydes under highly basic conditions using a polar aprotic solvent and a strong base (alkali metal hydroxide or an alkoxide) is described and discussed. Georg Thieme Verlag Stuttgart.
Synthesis and properties of benzylidene derivatives of terpenoid ketones
Chuiko,Vinarskaya,Izotova,Tychinskaya
, p. 196 - 199 (2007/10/03)
Optically active benzylidene derivatives of camphor and menthone were obtained in preparative yields by condensation of the ketones with aromatic aldehydes in DMSO in the presence of t-BuOLi. The synthesized α,β-unsaturated ketones show high specific rotation and thus are suitable to bedoping component to liquid-crystalline compositions.
Addition of 4-Hydroxycoumarin to &α,&β-Unsaturated Carbonyl Derivatives and Mannich Base Methiodides Derived from Cyclic Ketones
Khanna, Vijay,Paraskar, Sunil R.,Ladwa, P. H.,Bhide, M. B.
, p. 102 - 105 (2007/10/02)
Five new 4-hydroxycoumarins incorporating a cyclic ketone have been synthesized, their structures established by PMR, IR and UV spectral data, and screened for their anticoagulant activity.
