10278-02-1

Basic information

• Product Name: 1-methoxy-2-(prop-1-en-2-yl)benzene
• Synonyms: 1-Isopropenyl-2-methoxybenzene; benzene, 1-methoxy-2-(1-methylethenyl)-; methyl 2-(prop-1-en-2-yl)phenyl ether
• CAS NO: 10278-02-1
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.2017
• Mol File: 10278-02-1.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 212.7°C at 760 mmHg
• Flash Point: 77.2°C
• Density: 0.93g/cm³
• Vapor Pressure: 0.248mmHg at 25°C
• Refractive Index: 1.503
• CAS DataBase Reference: 1-methoxy-2-(prop-1-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxy-2-(prop-1-en-2-yl)benzene(10278-02-1)
• EPA Substance Registry System: 1-methoxy-2-(prop-1-en-2-yl)benzene(10278-02-1)

Safety Data

• Hazardous Substances Data: 10278-02-1(Hazardous Substances Data)

Upstream product

• 21022-73-1 2-(2'-methoxyphenyl)-2-propanol 
• 7335-26-4 ethyl 2-methoxybenzoate 
• 19493-09-5 Methylenetriphenylphosphorane 
• 10277-93-7 2-isopropenylphenol 
• 74-88-4 methyl iodide 
• 917-64-6 methyl magnesium iodide 
• 579-74-8 2-Methoxyacetophenone 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 118-93-4 o-hydroxyacetophenone 
• 590-14-7 1-bromo-1-propene 
• 100-66-3 methoxybenzene 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 119-36-8 methyl salicylate 
• 3045-32-7 2-(1-hydroxy-1-methylethyl)phenol 

Downstream Products

• 579-74-8 2-Methoxyacetophenone 
• 2944-47-0 o-isopropylanisole 
• 63667-67-4 2-<1-Methyl-cyclopropyl>-anisol 
• 1029124-38-6 (E)-2-(2-methoxy-phenyl)-1-nitro-propene 
• 1156454-37-3 C₁₉H₃₀N₂O₂ 
• 1253909-36-2 (R)-1-methoxy-2-(1-nitropropan-2-yl)benzene 
• 13524-78-2 3,3-dimethyl-2,3-dihydrobenzo[b]furan 

Relevant articles and documents

Oxidative [4+2] Cycloaddition of α-(N-Arylamino) Carbonyls with Aryl Alkenes by Multiple C-H Functionalizations and [1,2]-Aryl Shifts

A new, general copper-catalyzed oxidative tandem [4+2] cycloaddition of α-(N-arylamino) carbonyl compounds with aryl alkenes to produce highly substituted quinolines has been developed, which allows the formation of three new C-C bonds through a sequence of multiple C-H functionalizations, annulation, and [1,2]-aryl shifts.

Aqueous ZnCl2 Complex Catalyzed Prins Reaction of Silyl Glyoxylates: Access to Functionalized Tertiary α-Silyl Alcohols

An efficient Prins reaction of silyl glyoxylates in the presence of an aqueous ZnCl2 complex as a catalyst was developed, providing functionalized tertiary α-silyl alcohols in high yields under mild conditions. A preliminary investigation indicated that the aqueous ZnCl2 complex acted as a dual functional catalyst of Br?nsted and Lewis acid to activate the carbonyl groups of silyl glyoxylates via a dual-activation model.

Visible-light-promoted radical alkylation/cyclization of allylic amide with N-hydroxyphthalimide ester: Synthesis of oxazolines

An efficient photocatalytic alkylation/cyclization of allylic amide with N-hydroxyphthalimide ester has been developed. The transformation is taken advantage of alkyl radicals to attack allylic amide with the assist of inexpensive rose bengal as photocatalyst to prepare a series of alkyl substituted oxazolines in moderate to excellent yields. High regioselectivity, operational safety, mild conditions and excellent substrate generality give this protocol broad application prospects.

A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)2P(O)H

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO)2P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic triflones are obtained in moderate to good yields.