10286-75-6

Basic information

• Product Name: N-(3,4-Dichlorophenyl)benzamide
• Synonyms: N-(3,4-Dichlorophenyl)benzamide;3',4'-DICHLOROBENZANILIDE
• CAS NO: 10286-75-6
• Molecular Formula: C₁₃H₉Cl₂NO
• Molecular Weight: 266.1227
• Mol File: 10286-75-6.mol
• Article Data: 9

Chemical Properties

• Melting Point: 145-146 °C
• Boiling Point: 304.7°Cat760mmHg
• Flash Point: 138.1°C
• Appearance: /
• Density: 1.384g/cm³
• Vapor Pressure: 0.00086mmHg at 25°C
• Refractive Index: 1.656
• PKA: 11.97±0.70(Predicted)
• CAS DataBase Reference: N-(3,4-Dichlorophenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3,4-Dichlorophenyl)benzamide(10286-75-6)
• EPA Substance Registry System: N-(3,4-Dichlorophenyl)benzamide(10286-75-6)

Safety Data

• Hazardous Substances Data: 10286-75-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H9Cl2NO/c14-11-7-6-10(8-12(11)15)16-13(17)9-4-2-1-3-5-9/h1-8H,(H,16,17)

Upstream product

• 98-88-4 benzoyl chloride 
• 95-76-1 m,p-dichloroaniline 
• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 
• 151169-75-4 3,4-dichlophenylboronic acid 
• 2399-66-8 1-benzoylpyrrolidin-2-one 
• 20555-91-3 3,4-dichloroiodobenzene 
• 932-90-1 Benzaldoxime 
• 100-47-0 benzonitrile 
• 99-54-7 3,4-dichloronitrobenzene 
• 65-85-0 benzoic acid 
• 71144-20-2 (3,4-Dichloranilino)phenyl-acetonitril 
• 6004-21-3 3'-chloro-benzanilide 

Downstream Products

• 95-76-1 m,p-dichloroaniline 
• 100-51-6 benzyl alcohol 
• 666175-14-0 1-[(3,4-dichlorophenylimino)phenylmethyl]-3-ethylthiourea 
• 344250-20-0 N-(3,4-dichlorophenyl)benzimidoyl chloride 
• 10278-50-9 3',4'-dichlorothiobenzanilide 

Relevant articles and documents

Copper-catalyzed regioselective synthesis of N-aryl amides from aldoximes and aryl halides

Ligand-assisted copper-catalyzed reaction of aldoximes with aryl halides is described for the regioselective synthesis of N-aryl amides. This protocol is simple and compatible with a wide range of functional groups attached to the aryl ring of the halides as well as aldoximes. Copyright

Metal-free transamidation of benzoylpyrrolidin-2-one and amines under aqueous conditions

N-Acyl lactam amides, such as benzoylpyrrolidin-2-one, benzoylpiperidin-2-one, and benzoylazepan-2-one reacted with amines in the presence of DTBP and TBAI to afford the transamidated products in good yields. The reactions were conducted under aqueous conditions and good functional group tolerance was achieved. Both aliphatic and aromatic primary amines displayed good activity under metal-free conditions. A radical reaction pathway is proposed.

Copper-Catalyzed Regioselective Synthesis of N-Aryl Amides from Aldoximes and Aryl Halides

Ligand-assisted copper-catalyzed reaction of aldoximes with aryl halides is described for the regioselective synthesis of N-aryl amides. This protocol is simple and compatible with a wide range of functional groups attached to the aryl ring of the halides as well as aldoximes.