1684-14-6

Usage

Chemical Properties

light beige or grey solid

Synthesis Reference(s)

Tetrahedron Letters, 17, p. 2347, 1976 DOI: 10.1016/S0040-4039(00)78773-9

InChI:InChI=1/C20H14N2/c1-3-9-15(10-4-1)19-20(16-11-5-2-6-12-16)22-18-14-8-7-13-17(18)21-19/h1-14H

Upstream product

• 5623-30-3 1-Benzoyl-1-phenyl-2-piperidino-ethanol 
• 95-54-5 1,2-diamino-benzene 
• 66242-64-6 1,3-dimethyl-4,5-diphenyl-4,5-dihydroxyimidazolidin-2-one 
• 39145-59-0 o-phenylenediamine hydrochloride 
• 127-09-3 sodium acetate 
• 64-19-7 acetic acid 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 134-81-6 benzil 
• 67-56-1 methanol 
• 5227-55-4 2,3-diphenyl quinoxaline N-oxide 
• 151-50-8 potassium cyanide 
• 98-88-4 benzoyl chloride 
• 10442-39-4 tetra-n-butylammonium cyanide 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 112689-30-2 2,3-dicyclohexyl-decahydro-quinoxaline 
• 5016-08-0 2,3-diphenyl-1,2-dihydro-quinoxaline 
• 5227-55-4 2,3-diphenyl quinoxaline N-oxide 
• 5227-56-5 2,3-diphenylquinoxaline-N₁,N₄-dioxide 
• 7739-06-2 cis-1,2,3,4-tetrahydro-2,3-diphenylquinoxaline 
• 7739-06-2 (+/-)-trans-2,3-diphenyl-1,2,3,4-tetrahydro-quinoxaline 
• 215-64-5 dibenzo[a,c]phenacine 
• 716-79-0 2-phenyl-1H-benzoimidazole 
• 7739-06-2 trans-1,2,3,4-tetrahydro-2,3-diphenylquinoxaline 
• 415682-29-0 [Cu(2,3-diphenylquinoxaline)2ClO₄] 
• 1075217-49-0 2-butyl-2,3-bisphenyl-1H-quinoxaline 
• 1075217-59-2 2-phenyl-2,3-bisphenyl-1H-quinoxaline 
• 1075217-61-6 2-(4-methoxyphenyl)-2,3-bisphenyl-1H-quinoxaline 
• 1075217-63-8 2-(4-dimethylaminophenyl)-2,3-bisphenyl-1H-quinoxaline 

Related news

Color tuning of red phosphorescence: New iridium complexes containing fluorinated 2,3-DIPHENYLQUINOXALINE (cas 1684-14-6) ligands09/27/2019

The new iridium complexes containing a derivative of 2,3-diphenylquinoxaline as an emitting ligand were synthesized, and their photophysical properties were investigated. The complexes prepared in this study were bis(6-F-2,3-di(p-fluorophenyl) quinoxalinato)iridium acetylacetonate (Ir(6-F-2,3-dp...detailed

New 2,3-DIPHENYLQUINOXALINE (cas 1684-14-6) containing organic D-A-π-A dyes with nickel oxide photocathode prepared by surfactant-mediated synthesis for high performance p-type dye-sensitized solar cells09/26/2019

Dye-sensitized solar cells (DSSCs) are one of the most promising organic photovoltaics. The optimized efficiency of a tandem cell combined with both n- and p-type DSSCs was theoretically predicted to be 43%. The bottleneck for reaching the optimized performance is limited by the p-type half-cell...detailed

Highly efficient solution-processed pure red phosphorescent organic light-emitting diodes using iridium complexes based on 2,3-DIPHENYLQUINOXALINE (cas 1684-14-6) ligand09/25/2019

We synthesized two highly efficient red phosphorescent Ir(III) complexes, bis[2,3-diphenylquinoxalinato-N,C2′]iridium(III) pyrazinate (dpq)2Ir(prz) (1) and bis[2,3-diphenylquinoxalinato- N,C2′]iridium(III) 5-methylpyrazinate (dpq)2Ir(mprz) (2), which are both based on the use of 2,3-diphenylqu...detailed

The vibrational assignments of the infrared and Raman spectra of the symmetrically substituted 2,3-DIPHENYLQUINOXALINE (cas 1684-14-6) and its N,N′-dioxide: Experimental and computational study09/24/2019

2,3-diphenylquinoxaline (DPQ) and 2,3-diphenylquinoxaline N,N′-dioxide (DPQDO) (also known as 2,3-diphenylquinoxaline 1,4-dioxide) were synthesized, and their infrared and Raman spectra were measured. The structural stability and the vibrational spectra of the two quinoxaline molecules were inv...detailed

Relevant academic research and scientific papers

Green and efficient synthesis of quinoxaline derivatives via ceric ammonium nitrate promoted and in situ aerobic oxidation of α-hydroxy ketones and α-keto oximes in aqueous media

The direct conversion of α-hydroxy ketones and α-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green and efficient reaction media, is reported.

Quinoxaline synthesis from α-hydroxy ketones via a tandem oxidation process using catalysed aerobic oxidation

The direct conversion of α-hydroxy ketones into quinoxalines via metal-catalysed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines is reported. Catalyst screening indicated that these transformations could be carried out efficiently using 2 mol% Pd(OAc) 2 or RuCl2(PPh3)3-TEMPO; the palladium system was utilised for a range of transformations.

Comprehensive experimental investigation of mechanically induced 1,4-diazines synthesis in solid state

Compared mechanosynthesis of two condensed 1,4-diazines were investigated in ball milling conditions from o-phenylenediamine. 13C CP-MAS NMR revealed a hemiaminal intermediate for dibenzo[a,c]phenazine synthesis accumulated under mechanical act

Highly efficient synthesis of quinoxaline derivatives catalized by iridium complex

A novel iridium complex was used to catalyze a mild reaction of phenylenediamine with propanediol that led to formation of quinoxaline derivatives with moderate to high yields. The reaction diemonstrated strong compatibility with substrates bearing various functional groups.

2-Iodo benzoic acid: An unconventional precursor for the one pot multi-component synthesis of quinoxaline using organo Cu (II) catalyst

This is the first reported, unconventional, efficient strategy for the synthesis of quinoxaline from 2 to iodo benzoic acid and sodium azide in presence of organo Cu (II) catalyst. Herein, a very simple, versatile one pot multi-component protocol for the synthesis of biologically active compound, quinoxaline has been described via Schmidt reaction and the nucleophilic substitution reaction. The isolated compounds were characterized by 1H NMR, 13C NMR. Our reported organo catalyst was characterized by single crystal XRD, SEM.

Synthesis, characterization and catalytic activity of oxovanadium(IV) complexes of heterocyclic acid hydrazones

Two acid hydrazones, furan-2-carbaldehyde nicotinic hydrazone (L1) and furan-2-carbaldehyde benzhydrazone (L2) have been synthesized and they are characterized by elemental analysis, IR, NMR and UV spectral analysis. Oxovanadium(IV) complexes of these two

Biomass into chemicals: One-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts

An efficient and selective one-pot two-step method, for the synthesis of quinoxalines by oxidative coupling of vicinal diols with 1,2-phenylenediamine derivatives, has been developed by using gold nanoparticles supported on nanoparticulated ceria (Au/CeO2) or hydrotalcite (Au/HT) as catalysts and air as oxidant, in the absence of any homogeneous base. Reaction kinetics shows that the reaction controlling step is the oxidation of the diol to α-hydroxycarbonyl compound. Furthermore, a one-pot three-step synthesis of 2-methylquinoxaline starting from 1,2-dinitrobenzene and 1,2-propanediol has been successfully carried out with 98% conversion and 83% global yield to the final product.

Synthesis of new polyaza heterocycles. Part 42: Diazines

Using Pd-catalyzed Stille cross-coupling reactions, we report here the synthesis of various mono- or bis(tri-n-butylstannyl)diazines which were reacted with various halogenated diazines to access to various polyaza heterocyclic derivatives.

Tungstophosphoric acid/mesoporous silicas as suitable catalysts in quinoxaline synthesis

Quinoxalines and their derivatives are of great value in the chemical and biological sciences. These compounds are found in dyes, agrochemicals, and are used as building blocks of drugs for the treatment of different diseases. Quinoxalines and their deriv

Synthesis, characterization and application of α-Ca3 (PO4)2 as a heterogeneous catalyst for the synthesis of 2.3-diphenylquinoxaline derivatives and knoevenagel condensation under green conditions

Green chemistry is now paramount in modern life and industrial sector. It has become a research priority and a scientific challenge. In this study, alpha-tricalcic phosphate was prepared as a green catalytic medium. This medium has been characterized by v