65662-88-6

Basic information

• Product Name: 4-BROMO DIPHENYL SULFIDE
• Synonyms: 4-BROMO DIPHENYL SULFIDE;4-Bromodiphenylsulphide;1-Bromo-4-phenylsulfanylbenzene;4-Bromo diphenyl sul
• CAS NO: 65662-88-6
• Molecular Formula: C₁₂H₉BrS
• Molecular Weight: 265.17
• Mol File: 65662-88-6.mol
• Article Data: 98

Chemical Properties

• Boiling Point: 355.6 °C at 760 mmHg
• Flash Point: 168.8 °C
• Appearance: /
• Density: 1.49 g/cm³
• Vapor Pressure: 6.35E-05mmHg at 25°C
• Refractive Index: 1.681
• CAS DataBase Reference: 4-BROMO DIPHENYL SULFIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMO DIPHENYL SULFIDE(65662-88-6)
• EPA Substance Registry System: 4-BROMO DIPHENYL SULFIDE(65662-88-6)

Safety Data

• Hazardous Substances Data: 65662-88-6(Hazardous Substances Data)

Usage

General Description

4-Bromo diphenyl sulfide is a chemical compound with the molecular formula C12H9BrS. It is a crystalline solid with a pale yellow color, and it is commonly used in organic synthesis and as a building block for various chemical reactions. 4-BROMO DIPHENYL SULFIDE is known for its strong odor and is considered to be hazardous if it comes into contact with the skin or if it is ingested. It is also used in the production of pharmaceuticals, dyes, and agricultural chemicals. 4-Bromo diphenyl sulfide is also known to be an effective flame retardant in some applications. Overall, it is an important industrial chemical with various uses in different industries.

InChI:InChI=1/C12H9BrS/c13-10-6-8-12(9-7-10)14-11-4-2-1-3-5-11/h1-9H

Upstream product

• 945-51-7 1,1'-sulfinylbisbenzene 
• 106-37-6 1.4-dibromobenzene 
• 108-98-5 thiophenol 
• 52599-10-7 (4-bromo-phenyl)-phenylsulfanyl-diazene 
• 10442-39-4 tetra-n-butylammonium cyanide 
• 30506-30-0 1-bromo-4-ethylthiobenzene 
• 118-92-3 anthranilic acid 
• 108-86-1 bromobenzene 
• 882-33-7 diphenyldisulfane 
• 5467-74-3 4-Bromophenylboronic acid 
• 5335-84-2 bis(4-bromophenyl)disulfide 
• 98-80-6 phenylboronic acid 
• 591-50-4 iodobenzene 
• 106-53-6 para-bromobenzenethiol 

Downstream Products

• 88519-49-7 (4-iodophenyl)(phenyl)thioether 
• 23038-36-0 1-bromo-4-(phenylsulphonyl)benzene 
• 25186-92-9 1-bromo-4-(phenylsulfinyl)benzene 
• 52872-99-8 4-phenylmercaptothiophenol 
• 61654-48-6 N-phenyl-4-(phenylsulfonyl)benzenamine 
• 97442-87-0 1-ethynyl-4-(phenylsulfonyl)benzene 
• 1598371-20-0 [¹⁸F](4-fluorophenyl)(1-(4-hydroxybutyl)piperidin-4-yl)methanone 
• 1598371-21-1 C₁₈H₂₄⁽¹⁸⁾FNO₃ 
• 1598371-34-6 (4-(1-(4-acetoxybutyl)piperidine-4-carbonyl)phenyl)diphenylsulfonium trifluoromethanesulfonate 
• 1598371-36-8 (4-(1-(4-ethoxy-4-oxobutyl)piperidine-4-carbonyl)phenyl)diphenylsulfonium trifluoromethanesulfonate 
• 1598371-59-5 4-(4-(4-(phenylthio)benzoyl)piperidin-1-yl)butyl acetate 

Relevant articles and documents

Chan-Lam-Type C-S Coupling Reaction by Sodium Aryl Sulfinates and Organoboron Compounds

A Chan-Lam-Type C-S coupling reaction using sodium aryl sulfinates has been developed to provide diaryl thioethers in up to 92% yields in the presence of a copper catalyst and potassium sulfite. Both electron-rich and electron-poor sodium aryl sulfinates and diverse organoboron compounds were tolerated for the synthesis of aryl and heteroaryl thioethers and dithioethers. The mechanistic study suggested that potassium sulfite was involved in the deoxygenation of sulfinate through a radical process.

N-bromosuccinimide/HCl mediated reduction of sulfoxides to sulfides

An efficient reduction of sulfoxides to sulfides mediated by N-bromosuccinimide (NBS)/HCl system has been developed. This protocol shows good functional group compatibility as well as broad substrates scope with operational simplicity.

Spiroconjugated Tetraaminospirenes as Donors in Color-Tunable Charge-Transfer Emitters with Donor-Acceptor Structure

Charge-transfer emitters are attractive due to their color tunability and potentially high photoluminescence quantum yields (PLQYs). We herein present tetraaminospirenes as donor moieties, which, in combination with a variety of acceptors, furnished 12 charge-transfer emitters with a range of emission colors and PLQYs of up to 99 %. The spatial separation of their frontier molecular orbitals was obtained through careful structural design, and two DA structures were confirmed by X-ray crystallography. A range of photophysical measurements supported by DFT calculations shed light on the optoelectronic properties of this new family of spiro-NN-donor-acceptor dyes.