Stereoselective addition of cyanide reagents to nitrones

DOI: 10.1016/0040-4039(95)01377-T

Source and publish data:

Tetrahedron Letters p. 6949 - 6952 (1995)

Update date:2022-08-16

Topics:

Authors:

Merchan, Francisco L.

Merino, Pedro

Tejero, Tomas

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Article abstract of DOI:10.1016/0040-4039(95)01377-T

An exploration of the diastereoselective addition of cyanide reagents to the nitrone 1 derived from D-glyceraldehyde acetonide to afford mixtures of syn-2 and anti-2 is presented. Trimethylsilyl cyanide was found to add to the nitrone 1 with essentially complete syn-stereoselectivity in excellent yields.

Full text of DOI:10.1016/0040-4039(95)01377-T

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