104669-28-5

Basic information

• Product Name: (2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine
• Synonyms: (2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine
• CAS NO: 104669-28-5
• Molecular Weight: 260.133
• Mol File: 104669-28-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine(104669-28-5)
• EPA Substance Registry System: (2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine(104669-28-5)

Safety Data

• Hazardous Substances Data: 104669-28-5(Hazardous Substances Data)

Upstream product

• 167390-83-2 (E)-N-(2-iodophenyl)-1-phenylmethanimine 
• 908588-80-7 2-bromo-4-methoxy-N-[(1E)-phenylmethylene]aniline 
• 100-52-7 benzaldehyde 
• 615-36-1 2-bromoaniline 

Downstream Products

• 167390-83-2 (E)-N-(2-iodophenyl)-1-phenylmethanimine 
• 62506-88-1 (E)-N-(phenylmethylene)benzhydrylamine 
• 344-61-6 (E)-1-phenyl-N-(2-(trifluoromethyl)phenyl)methanimine 
• 908588-80-7 2-bromo-4-methoxy-N-[(1E)-phenylmethylene]aniline 
• 945033-63-6 8-bromo-4-(triisopropylsilyl)methyl-2-phenylquinoline 
• 100-52-7 benzaldehyde 
• 615-36-1 2-bromoaniline 

Relevant articles and documents

Synthesis of 1,2-dihydropyridines using vinyloxiranes as masked dienolates in imino-aldol reactions

The application of vinyloxiranes, substituted with an electron-withdrawing group, as masked dienolates in vinylogous imino-aldol reactions was achieved. Under the reaction conditions highly substituted 1,2-dihydropyridines were obtained in moderate to good yields. Mechanistic studies indicate that the reaction proceeds via the formation of an (E)-amino-α,β-unsaturated aldehyde, followed by isomerization to the (Z)-isomer, cyclization, and elimination of a water molecule, leading to the formation of the 1,2-dihydropyridine.