62506-88-1

Basic information

• Product Name: N-BENZYLIDENE-N-(DIPHENYLMETHYL)AMINE
• Synonyms: n-benzylidene-α-phenylbenzylamine;N-Benzylidene-N-(diphenylmethyl)amine 95%
• CAS NO: 62506-88-1
• Molecular Formula: C₂₀H₁₇N
• Molecular Weight: 271.36
• Mol File: 62506-88-1.mol
• Article Data: 62

Chemical Properties

• Melting Point: 99-103 °C(lit.)
• Boiling Point: 399.4°C at 760 mmHg
• Flash Point: 187.8°C
• Appearance: /
• Density: 0.99g/cm³
• Vapor Pressure: 3.16E-06mmHg at 25°C
• Refractive Index: 1.572
• Storage Temp.: 2-8°C
• CAS DataBase Reference: N-BENZYLIDENE-N-(DIPHENYLMETHYL)AMINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-BENZYLIDENE-N-(DIPHENYLMETHYL)AMINE(62506-88-1)
• EPA Substance Registry System: N-BENZYLIDENE-N-(DIPHENYLMETHYL)AMINE(62506-88-1)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-37/38-41-50/53
• Safety Statements: 36/37-60-61
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 62506-88-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C20H17N/c1-4-10-17(11-5-1)16-21-20(18-12-6-2-7-13-18)19-14-8-3-9-15-19/h1-16,20H/b21-16+

Upstream product

• 7699-79-8 benzhydrylidene-benzyl-amine 
• 141-52-6 sodium ethanolate 
• 100-52-7 benzaldehyde 
• 91-00-9 Benzhydrylamine 
• 100-51-6 benzyl alcohol 
• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 119-61-9 benzophenone 
• 20989-17-7 Phenylglycinol 
• 104669-28-5 (2-Bromo-phenyl)-[1-phenyl-meth-(E)-ylidene]-amine 
• 167390-83-2 (E)-N-(2-iodophenyl)-1-phenylmethanimine 
• 908588-80-7 2-bromo-4-methoxy-N-[(1E)-phenylmethylene]aniline 
• 65-85-0 benzoic acid 
• 1485-72-9 N-benzoyl-diphenylmethylamine 
• 1809-19-4 dibutyl hydrogen phosphite 

Downstream Products

• 108606-83-3 t-butyl 3-diphenylmethylamino-2-methyl-3-phenylpropane-thioate 
• 108606-83-3 t-butyl 3-diphenylmethylamino-2-methyl-3-phenylpropane-thioate 
• 129823-48-9 (2S,3R)-3-(Benzhydryl-amino)-2-methyl-3-phenyl-propionic acid methyl ester 
• 129823-48-9 (2R,3R)-3-(Benzhydryl-amino)-2-methyl-3-phenyl-propionic acid methyl ester 
• 124067-72-7 4-(m-methoxybenzoyloxy)-4-(m-methoxyphenyl)-1,1,3-triphenyl-2-azabuta-1,3-diene 
• 80993-27-7 (+/-)-diethyl [α-((diphenylmethyl)amino)benzyl]phosphonate 
• 177723-18-1 (S)-2-(diphenylmethyl)amino-2-phenylacetonitrile 
• 187819-60-9 rac-N-benzhydryl-α-phenylglycine nitrile 
• 209183-09-5 t-butyl (S)-3-(benzhydrylamino)-3-phenylpropionate 
• 119-61-9 benzophenone 
• 2835-06-5 phenylglycin 
• 233585-42-7 cis-1-benzhydryl-(3R)-phenyl-aziridine-(2R)-carboxylic acid ethyl ester 
• 359454-74-3 methyl 1-diphenylmethylamino-1-phenyl-methyl phosphinate 

Relevant articles and documents

Probing Catalyst Function – Electronic Modulation of Chiral Polyborate Anionic Catalysts

Boroxinate complexes of VAPOL and VANOL are a chiral anionic platform that can serve as a versatile staging arena for asymmetric catalysis. The structural underpinning of the platform is a chiral polyborate core that covalently links together alcohols (or

Dehydrogenative amide synthesis from alcohols and amines utilizing N-heterocyclic carbene-based ruthenium complexes as efficient catalysts: The influence of catalyst loadings, ancillary and added ligands

The metal-catalyzed dehydrogenative coupling of alcohols and amines to access amides has been recognized as an atom-economic and environmental-friendly process. Apart from the formation of the amide products, three other kinds of compounds (esters, imines and amines) may also be produced. Therefore, it is of vital importance to investigate product distribution in this transformation. Herein, N-heterocyclic carbene-based Ru (NHC/Ru) complexes [Ru-1]-[Ru-5] with different ancillary ligands were prepared and characterized. Based on these complexes, we selected condition A (without an added NHC precursor) and condition B (with an added NHC precursor) to comprehensively explore the selectivity and yield of the desired amides. After careful evaluation of various parameters, the Ru loadings, added NHC precursors and the electronic/steric properties of ancillary NHC ligands were found to have considerable influence on this catalytic process.

Microwave-assisted synthesis of α-aminophosphonates with sterically demanding α-aryl substituents

A series of N-benzhydryl protected α-aminophosphonates with α-phenyl, α-(1-naphtyl), α-(9-anthryl) or α-(1-pyrenyl) substituents was synthesized by the Kabachnik–Fields condensation of diphenylmethylamine (benzhydrylamine), the corresponding aryl aldehyde and a dialkyl phosphite under MW irradiation. X-ray studies performed at low temperatures for a few of these α-aminophosphonates confirmed the presence of unusually short intramolecular Cα–Hδ+ ··· δ+H–Cperi contacts.