10471-14-4Relevant articles and documents
HCo(CO)4 AS AN ACID CATALYST IN VINYL ETHER REACTIONS
Freudenberger, John H.,Matsui, Yasushi,Orchin, Milton
, p. 1811 - 1814 (1982)
At room conditions in the presence of alcohols, HCo(CO)4 instead of being consumed by vinyl ethers, functions as an acid catalyst for acetal formation.
Juvet,Chiu
, p. 1560 (1961)
Process and catalysts for the oxidation of methanol and/or ethanol
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Page/Page column 8, (2008/06/13)
A process for oxidation of methanol, ethanol, or a mixture of methanol and ethanol comprising contacting the methanol and/or ethanol with an oxygen-containing gas and a supported catalyst comprising one or more platinum group oxides. The process conditions and/or catalyst may be selected to as to selectively produce methyl formate from methanol or diethoxyethane from ethanol. The invention also includes certain novel supported platinum group metal oxide catalysts. Preferred catalysts include one or more ruthenium oxides.
SYNTHESIS OF UNSYMMETRICAL 1,1-DIALKOXYALKANES AND THEIR SULFUR-CONTAINING ANALOGS
Gazizova, L. B.,Imashev, U. B.,Musavirov, R. S.,Kantor, E. A.,Zlotskii, S. S.,et al.
, p. 226 - 231 (2007/10/02)
Acyclic acetals and 1,1-di(alkylthio)alkanes enter into exchange reactions in the presence of aprotic acids and of the KU-2 cation-exchange resin with the formation of the unsymmetric acetals and 1-alkoxy-1-alkylthioalkanes.In reaction with ethylal di(ethylthio)methane forms 3,5,7-trioxanonane in addition to ethylthioethoxymethane. 2-Methyl-4-thia-2-hexene was found in the products from the reaction of 1,1-di(ethylthio)-2-methylpropane with methylal.