104892-58-2

Basic information

• Product Name: 3,4,5-TRIBROMOACETOPHENONE
• Synonyms: 3,4,5-TRIBROMOACETOPHENONE;1-(3,4,5-Tribromophenyl)ethanone
• CAS NO: 104892-58-2
• Molecular Formula: C₈H₅Br₃O
• Molecular Weight: 356.84
• Product Categories: Aromatic Acetophenones & Derivatives (substituted)
• Mol File: 104892-58-2.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,4,5-TRIBROMOACETOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,5-TRIBROMOACETOPHENONE(104892-58-2)
• EPA Substance Registry System: 3,4,5-TRIBROMOACETOPHENONE(104892-58-2)

Safety Data

• Hazardous Substances Data: 104892-58-2(Hazardous Substances Data)

Upstream product

• 99-90-1 para-bromoacetophenone 
• 22589-50-0 4-amino-3,5-dibromo-acetophenone 
• 799291-47-7 1-(3,4,5-tribromo-phenyl)-ethanol 
• 64-19-7 acetic acid 

Downstream Products

• 861343-32-0 1-(3,4,5-tribromo-2-nitro-phenyl)-ethanone 
• 618-74-6 3,4,5-tribromobenzoic acid 
• 87976-31-6 C₇H₃⁽²⁾H₃O₂ 
• 116772-89-5 C₈H₃⁽²⁾H₇O 

Relevant articles and documents

Remote electronic effects in the rhodium-catalyzed nucleophilic ring opening of oxabenzonorbornadienes.

We report the application of our rhodium-catalyzed nucleophilic ring-opening methodology to unsymmetrically arene-substituted oxabenzonorbornadienes. The regioselectivity of the ring opening was investigated using a variety of nucleophiles that led to a broad selection of dihydronaphthalene products. It was found that good to excellent regioselectivities are obtained using strongly pi-donating substituents, whereas sigma-donating and electron-withdrawing functionalities have a minimal effect. Post ring-opening manipulations of functional groups in the dihydronaphthalene products were shown to give efficient access to mono- and diamine tetrahydronaphthalene building blocks.