104911-35-5Relevant academic research and scientific papers
Reaction of lithium alkynolates with acid chlorides: A conventional approach to the preparation of ynol esters
Zhdankin,Stang
, p. 1461 - 1462 (1993)
Lithium alkynolates (R-C≡COLi, R = CH3, n-C4H9, t-C4H9, Ph), generated in situ from dibromomethylketones and a strong base, react with electrophiles (diethyl chlorophosphate or benzoyl chloride) with the formation of the corresponding ynol esters.
