Tetrahedron Letters p. 1461 - 1462 (1993)
Update date:2022-08-16
Topics:
Zhdankin
Stang
Lithium alkynolates (R-C≡COLi, R = CH3, n-C4H9, t-C4H9, Ph), generated in situ from dibromomethylketones and a strong base, react with electrophiles (diethyl chlorophosphate or benzoyl chloride) with the formation of the corresponding ynol esters.
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