1054-59-7

Usage

Uses

Used in Pesticides:
(diphenylphosphoryl-phenyl-phosphoryl)benzene is used as an active ingredient in pesticides for its potential to control pests effectively. Its organophosphorus nature may contribute to its pesticidal properties, making it a candidate for further research and development in this field.
Used in Flame Retardants:
In the flame retardant industry, (diphenylphosphoryl-phenyl-phosphoryl)benzene is utilized as an additive to enhance the fire resistance of materials. Its organophosphorus composition could provide the necessary chemical reactions to slow down the spread of flames and improve safety standards in various products.
Used in Chemical Reactions:
Due to its unique structure and properties, (diphenylphosphoryl-phenyl-phosphoryl)benzene may be employed as a reactant or intermediate in specific chemical reactions. Its reactivity and the ability to form new compounds could be valuable in the synthesis of pharmaceuticals, dyes, or other specialty chemicals.
Used in Industrial Processes:
The potential applications of (diphenylphosphoryl-phenyl-phosphoryl)benzene extend to various industrial processes where its organophosphorus nature could be leveraged for specific technical advantages. This may include its use in the production of plastics, coatings, or other materials that require unique chemical properties.
It is crucial to handle and use (diphenylphosphoryl-phenyl-phosphoryl)benzene with caution, as organophosphorus compounds can pose risks to human health and the environment. Proper safety measures and regulations must be adhered to in its production, application, and disposal.

InChI:InChI=1/C24H20O2P2/c25-27(21-13-5-1-6-14-21,22-15-7-2-8-16-22)28(26,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H

Upstream product

• 41006-23-9 P,P'-tetraphenyl-oxalic acid diphosphide 
• 75980-60-8 (2,4,6-trimethylbenzoyl)diphenylphosphine oxide 
• 15475-27-1 potassium diphenylphosphine 
• 829-85-6 diphenylphosphane 
• 1079-66-9 chloro-diphenylphosphine 
• 1499-21-4 Diphenylphosphinic chloride 
• 1101-41-3 Tetraphenyldiphosphin 
• 20472-49-5 ethyl diphenylthiophosphinite 
• 19115-01-6 potassium diphenylphosphide 

Downstream Products

• 5849-36-5 diphenylphosphinic anhydride 
• 102462-49-7 S-octyl diphenylphosphinothioate 
• 5573-42-2 (benzyloxy)di(phenyl)phosphine oxide 
• 2544-45-8 tetraphenyldiphosphine-1-oxide-2-sulfide 
• 34253-15-1 4-methoxy-o-phenyl phenyl(phenyl)phosphinate 
• 5510-78-1 diphenylthiophosphinic acid-S-phenyl ester 
• 1707-03-5 diphenyl-phosphinic acid 
• 1300197-18-5 {(2,4,6-trimethylphenyl)ethynyl}diphenylphosphine oxide 
• 19259-65-5 S-hexyl diphenylthiophosphinate 

Relevant academic research and scientific papers

DIPHOSPHINE DERIVATIVES. Part VIII. Tetraphenyldiphosphine dioxide and tetraphenyldiphosphine disulphide: structure and skeletal vibrations. Preparation of diphenyphosphinodiselenoic anhydroselenide, Ph2P(Se)SeP(Se)Ph2

The X-ray powder diffraction pattern for tetraphenyldiphosphine dioxide Ph2P(O)P(O)Ph2 can be satisfactorily indexed on the assumption that the compound is isomorphous with tetraphenyldiphosphine disulphide.Calculated crystal data for the dioxide are: monoclinic, P21/c, a = 9.44(1), b = 15.62(3), c = 13.87(3) Angstroem, β = 98.0(1)0 Z = 4.The P-P stretch is assigned in the Raman spectrum of the disulphide at 536 cm-1 and in dioxide at the usually high frequency of 601 cm-1.The reaction of tetraphenyldiphosphine with KSeCN in acetonitrile leads to oxidation of the phosphorous and selenium insertion into the P-P bond, yielding Ph2P(Se)SeP(Se)Ph2, diphenylphosphinodiselenoic anhydroselenide, previously only identified in solution.

Reaction of quinoline-5,8-diones with selected charged phosphorus nucleophiles

The redox reactivity of the two quinoline-5,8-dione derivatives2-methyl-5, 8-dioxo-5,8-dihydroquinoline-7-amine (2a) and N-(2-methyl-5,8-dioxo-5,8- dihydroquinolin-7-yl)acet-amide (2b)has been demonstrated by their reaction with negatively charged three-c

New look into the synthesis of polyhalogenoarylphosphanes

The present study shows new aspects of the synthesis of polyhalogenoarylphosphanes. The sterically hindered anions Ph(R)P-Y- (1a-c, Y = O, lone pair; R = Ph, But) have been used to show the complexity of the reaction between phosphorus nucleophiles and hexahalogenobenzenes or 9-bromofluorene (E3). The Ph(But)P-O-(1a) anion reacts with hexachlorobenzene (E1), hexafluorobenzene (E2), or E3 to give Ph(R)P(O)X (4a-c, X = F, Cl, Br) with the release of the corresponding carbanion as a nucleofuge, followed by side reactions. In contrast, the lithium phosphides Ph(R)PLi (1b,c) react with hexahalogenobenzenes to give the corresponding diphosphanes 5a,b as the main product and traces of P-arylated products, i.e., Ph(R)P-C6X 5 (10a,b, X = Cl, F). Unexpectedly, Ph(But)PLi (1b) reacts with an excess of 9-bromofluorene to give only halogenophosphane Ph(Bu t)P-X. Taylor & Francis Group, LLC.

New approaches to the synthesis of diphosphine dioxides and hypophosphoric acid esters

An union >P-O- has been applied as an efficient synthetic precursor of four coordination compounds of the R2P(O)-(O)PR 2 type, namely diphosphine dioxides (R = alkyl, aryl) as well as hypophosphoric acid esters (R = alkoxy, aryloxy), in a one-pot reaction. Furthermore, there were elaborated some mechanistic aspects of the origin of the >P(O)-O-(O)PP-O- and >P(O)X (X= Cl, Br) electrophiles. Attention is focused on the synthesis of the >P(O)-(O)P compounds.

(2,4,6-Trimethylbenzoyl)diphenylphosphine oxide photochemistry. A direct time-resolved spectroscopic study of both radical fragments

The photochemistry of (2,4,6-trimethylbenzoyl)diphenylphosphine oxide (1) has been investigated using time-resolved infrared (TRIR) and time-resolved UV spectroscopy (laser flash photolysis (LFP)), in addition to conventional photochemical steady-state te

Reactions of P_Cl compounds in presence of SMI2

Conversion of P-Cl to P-H and P-C bonds are induced by SmI2 in mild conditions. Especially phosphines oxides and sulfides are obtained in good yields.

ELECTRON-TRANSFER PROCESSES. PART 40. REACTION OF ALKYL RADICALS WITH DIPHENYLPHOSPHIDE ANION

The anion Ph2P- (K+, 18-crown-6) reacts with t-BuHgCl in HMPA to form Ph2PCMe3 by a free radical chain mechanism.In Me2SO, PhP(O)CMe3 is produced.Reaction of Ph2P- with PhCOCH2HgCl yields the oxidative dimerization product isolable from HMPA but readily converted to Ph2P(O)P(O)Ph2 in Me2SO.

Studies on the Occurence of Hydrogen Transfer, 67. Enediol Diesters by Acylating Electroreductive Dimerization of Acyl Chlorides with Lithium Amalgam

Aromatic, aliphatic, and aromatic-aliphatic acyl chlorides (and anhydrides) are transformed by lithium amalgam (Li/Hg) to cis- and/or trans enediol diesters 1-10 (acylating reductive dimerization), mostly in ca. 70percent yields.The influence of the solvent on the reaction course is investigated.Starting from 2,2'-biphenyldicarbonyl dichloride, the phenanthrene 7 is formed; phthalide 8 is the reaction-product using phthaloyl dichloride as starting material.Diphenylphosphinyl chloride is reduced by Li/Hg to tetraphenyldiphosphane dioxide (15).A reaction mechanism for the acylating reductive dimerization is proposed on the basis of the halve-wave potentials determined for 12 acyl chlorides and four 1,2-diketones.The latter are intermediates in the acylating reductive dimerization of the acyl chlorides.Enediol diesters are obtained starting from 1,2-diketones and Li/Hg in the presence of acyl chlorides.Trimethylsilyl chloride is unsuitable as a trap for the enediols; it is preferentially reduced at the Li/Hg interface.Tetrahydrofuran as solvent is transformed to RC(O)O-4-Cl by a known ring-opening acylation reaction in the presence of Lewis acids (LiCl or ZnCl2) formed by the decomposition of Li/Hg and Zn/Hg.

The Behaviour of Oxalyl-bis(diphenylphosphane) Towards Oxygen

In dependence of the solvent, oxalyl-bis(diphenylphosphane) (1) is oxidized with molecular oxygen either in a radical or an ionic mechanism to give - via the radicals PPh2 and the recombination products 2 (3) - the oxide 2 (4) and 2O (6), respectively.In both cases CO and CO2 are eliminated in nearly equal amounts. - Keywords: Oxidation of Oxalyl-bis(diphenylphosphane), Mechanism