10557-03-6

Upstream product

• 613-91-2 acetophenone oxime 
• 77-78-1 dimethyl sulfate 
• 64-17-5 ethanol 
• 74-88-4 methyl iodide 
• 124-41-4 sodium methylate 
• 64948-39-6 C₁₁H₁₇NOSi 
• 420-37-1 trimethoxonium tetrafluoroborate 
• 4229-44-1 N-methylhydroxyamine hydrochloride 
• 536-74-3 phenylacetylene 
• 98-86-2 acetophenone 
• 4316-37-4 1,1,-diethoxy-1-phenylethane 

Downstream Products

• 65708-59-0 2,3-dimethyl-3-phenyl-isoxazolidin-5-one 
• 909900-42-1 C₂₅H₂₉NOSi 
• 3376-23-6 C-phenyl-N-methylnitrone 
• 39626-50-1 (E) ethyl 2-benzoyl-3-methyl-cinnamate 
• 39626-49-8 (Z) ethyl 2-benzoyl-3-methyl-cinnamate 
• 139286-59-2 2,3-dimethyl-3-phenyl-4-ethoxycarbonyl-4-isoxazoline 
• 139286-69-4 2,3-dimethyl-3-phenyl-4-ethoxycarbonyl-4-isoxazoline 
• 139286-60-5 2,3-dimethyl-3,5-diphenyl-4-ethoxycarbonyl-4-isoxazoline 
• 593-77-1 N-Methylhydroxylamine 
• 98-86-2 acetophenone 

Relevant academic research and scientific papers

Enantioselective Synthesis of Cα-Tetrasubstituted N-Hydroxyl-α-amino Nitriles via Cyanation of Ketonitrones Using Me2(CH2Cl)SiCN

Here, we report an unprecedented catalytic enantioselective cyanation of ketonitrones enabled by the bifunctional cyanating reagent Me2(CH2Cl)SiCN. This approach allows facile access to optically active N-hydroxyl-α-amino nitriles that are of high synthet

Tin-free radical alkylation of ketones via N-silyloxy enamines

The radical alkylation of ketones is achieved by their conversion into corresponding N-silyloxy enamines, followed by a radical reaction with alkyl halides bearing electron-withdrawing groups. The Royal Society of Chemistry 2006.

Synthesis of Novel N-methanamine

The synthesis and configurational purity of a series of novel N-methanamine N-oxides 9a-q and 10a, b is reported.Directly after the synthesis, ketonitrones 9, 10 were found to exist exclusively in the (E) form, although

1,3-Dipolar Cycloadditions of Nitrones Derived from the Reaction of Acetylenes with Hydroxylamines

A study of the reaction of hydroxylamines with a variety of acetylenes has been carried out.Methylhydroxylamine readily reacts with methyl propiolate to give methyl 4-carbomethoxy-2-methyl-4-isoxazolidine-3-acetate.Further heating of this material results

A CONVENIENT SYNTHESIS OF NITRONES BY N-ALKYLATION OF O-TRIMETHYLSILYLOXIMES

Aldoxime and ketoxime-O-trimethylsilyl ethers can be alkylated with trialkyl-oxonium tetrafluoroborates and alkyl triflates at or below room temperature to produce nitrones in good yields.