10595-51-4

Basic information

• Product Name: N-METHYL-4-NITROSOANILINE
• Synonyms: 4-nitroso-N-methylaniline;Benzenamine, N-methyl-4-nitroso-;Nsc66522
• CAS NO: 10595-51-4
• Molecular Formula: C₇H₈N₂O
• Molecular Weight: 136.1546
• Mol File: 10595-51-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 259.5°Cat760mmHg
• Flash Point: 110.7°C
• Appearance: /
• Density: 1.11g/cm³
• Vapor Pressure: 0.0129mmHg at 25°C
• Refractive Index: 1.55
• CAS DataBase Reference: N-METHYL-4-NITROSOANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-METHYL-4-NITROSOANILINE(10595-51-4)
• EPA Substance Registry System: N-METHYL-4-NITROSOANILINE(10595-51-4)

Safety Data

• Hazardous Substances Data: 10595-51-4(Hazardous Substances Data)

Usage

Purification Methods

Crystallise it from *C6H6. The picrate has m 166o(dec) (from MeOH or CHCl3). [Beilstein 7 III 3370, 12 IV 1228.]

InChI:InChI=1/C7H8N2O/c1-8-6-2-4-7(9-10)5-3-6/h2-5,8H,1H3

Upstream product

• 100-61-8 N-methylaniline 
• 7647-01-0 hydrogenchloride 
• 60-29-7 diethyl ether 
• 64-17-5 ethanol 
• 614-00-6 N-methyl-N-nitrosoaniline 
• 7664-93-9 sulfuric acid 
• 10035-10-6 hydrogen bromide 
• 2032-36-2 Thiobenzmorpholid 

Downstream Products

• 99-80-9 N,4-Dinitroso-N-methylbenzeneamine 
• 105339-33-1 cyano-(4-methylamino-phenylimino)-acetic acid ethyl ester 
• 479-45-8 tetryl 
• 57838-93-4 5-Amino-2-methyl-4-(4-methylamino-phenylamino)-phenol 
• 93320-66-2 1-[4-(Methyl-nitroso-amino-)-phenylazo]-[2]naphthol 
• 623-09-6 N-methyl-benzene-1,4-diamine 
• 102266-74-0 3-Amino-4,4-dicyan-2-<4-(methylamino)phenylimino>-3-butensaeure-ethylester 
• 56330-19-9 5-Amino-2-methyl-4-[(E)-4-methylamino-phenylimino]-cyclohexa-2,5-dienone 
• 103646-51-1 cyano-(4-methylamino-phenylimino)-acetic acid methyl ester 
• 4435-12-5 azophenin 
• 637-62-7 p-benzoquinone oxime 
• 74-89-5 methylamine 
• 3421-08-7 2,5-bis(phenylamino)-1,4-benzoquinone 

Relevant articles and documents

N-NITROSAMINES AS REAGENTS FOR THE =C=S=C=O TRANSFORMATION

N-nitrosopiperidine and N-nitroso-N-methylaniline react in acidic solution with thiocarbonyl compounds to give the corresponding carbonyl analogues.Secondary- and tertiary thioamides, xanthione, thio- and dithiobutyrolactone, thiocoumarin, certain thiourea derivatives, dithio-O,O-thiocarbonic, S,S-trithiocarbonic- and N,N disubstituted thiocarbamic esters are all converted into the corresponding O-analogues.Thiobenzamide and N-phenylthiourea yield 1,2,4-thiadiazoles.All the reactions are run with iodide (I-) as NO+-carrier.The kinetics of the reaction have been studied under pseudo-first order conditions, and the reaction rate is proportional to the Pearson's nucleophilicity parameter of ions.The =C=S =C=O transformation is also found to take place in gastric juice.