1065-05-0

Basic information

• Product Name: 2,2,4,4,6,6-hexakis(2,2,2-trifluoroethoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine
• CAS NO: 1065-05-0
• Molecular Formula: C₁₂H₁₂F₁₈N₃O₆P₃
• Molecular Weight: 729.1327
• Mol File: 1065-05-0.mol
• Article Data: 8

Chemical Properties

• Density: 1.84g/cm³
• Refractive Index: 1.392
• CAS DataBase Reference: 2,2,4,4,6,6-hexakis(2,2,2-trifluoroethoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,4,4,6,6-hexakis(2,2,2-trifluoroethoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine(1065-05-0)
• EPA Substance Registry System: 2,2,4,4,6,6-hexakis(2,2,2-trifluoroethoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine(1065-05-0)

Safety Data

• Hazardous Substances Data: 1065-05-0(Hazardous Substances Data)

Usage

General Description

2,2,4,4,6,6-hexakis(2,2,2-trifluoroethoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine is a chemical compound with the molecular formula C18F18O6N3P3. It is an organophosphorus compound that contains six trifluoroethoxy groups attached to a triazatriphosphinine core. 2,2,4,4,6,6-hexakis(2,2,2-trifluoroethoxy)-1,3,5,2lambda~5~,4lambda~5~,6lambda~5~-triazatriphosphinine is used as a ligand in coordination chemistry and catalysis due to its unique structure and properties. It has been studied for its potential applications in the development of new catalysts for organic synthesis and as a stabilizing agent for metal nanoparticles. In addition, this compound is of interest for its potential use in materials science and as a building block for the synthesis of other organophosphorus compounds.

Upstream product

• 75-89-8 2,2,2-trifluoroethanol 
• 420-87-1 sodium 2,2,2-trifluoroethanolate 
• 56859-55-3 (2,2,2-trifluoroethoxy)trimethylsilane 
• 940-71-6 2,2,4,4,6,6-hexachloro-1,3,5-triaza-2,4,6-triphosphorine 
• 24524-93-4 Pentakis-(2,2,2-trifluor-aethoxy)-monohydroxy-cyclotriphosphazen, Natriumsalz 
• 106938-63-0 Toluene-4-sulfonic acid 2,4,4,6,6-pentakis-(2,2,2-trifluoro-ethoxy)-2λ⁵,4λ⁵,6λ⁵-[1,3,5,2,4,6]triazatriphosphinin-2-yl ester 
• 77772-20-4 C₁₂H₁₈Cl₃N₉P₃⁽³⁺⁾*3Cl^(1-) 
• 74868-58-9 hexakis(imidazolyl)cyclotriphosphazene 
• 53640-39-4 2,2,4,4,6,6-hexa-(p-chlorophenoxo)cyclotri-λ⁵-phosphazatriene 

Downstream Products

• 333-36-8 1,1,1-trifluoro-2-(2,2,2-trifluoroethoxy)ethane 
• 24524-93-4 Pentakis-(2,2,2-trifluor-aethoxy)-monohydroxy-cyclotriphosphazen, Natriumsalz 
• 7736-60-9 N₃P₃(OCH₂CF₃)5OPh 
• 17351-95-0 (2,2,2-trifluoroethoxy)benzene 

Relevant articles and documents

Polyfluoroalkoxy and aryloxy cyclic phosphazenes: an alternative synthetic route to substitution reactions using siloxanes in the presence of fluoride ion catalysts

Keywords: Polyfluoroalkoxy cyclic phosphazenes; Aryloxy cyclic phosphazenes; Synthesis; Fluoride ion catalyst; NMR spectroscopy; X-Ray crystal structures

Synthesis and application of additives based on trifluoroethoxy-cyclo-phosphazene into polymer nanofibers

This paper is focused on the synthesis and application of phosphazene derivatives, hexakis(2,2,2–trifluoroethoxy)-cyclo-triphosphazene and tetrakis(2,2,2-trifluoroethoxy)-diamino-cyclo-triphosphazene. These compounds were used as additives into some common polymers. As the synthesized compounds themselves show enhanced hydrophobicity, the nanofibers, made from them by electrospinning technology, should exhibit the enhanced hydrophobicity, too. It was found that hydrophobic properties of fibers are influenced by number of trifluoroethoxy groups bound to the phosphazene cycle. The use of these modified nanofibers especially in surface protection is expected. The result of the use can be the creation of efficient, removable, compact protect layer for long-term objects storing.

Synthesis of new polyelectrolytes via backbone quaternization of poly(aryloxy- and alkoxyphosphazenes) and their small molecule counterparts

Novel polyelectrolytes were synthesized by quaternization of the backbone of poly(alkoxy- and aryloxyphosphazenes) with strong alkylation reagents. As models for the synthesis of these polymers, similar quaternization reactions were also carried out on small-molecule alkoxy and aryloxy cyclotriphosphazenes. The quaternized small molecules and high polymers were characterized by 1H NMR, 31P NMR, DSC, TGA, and AC impedance studies. The quaternized poly(alkoxyphosphazenes) showed ionic conductivities of 2.58 × 10-4 S?cm-1 at 25 °C and 2.09 × 10 -3 S?cm-1 at 80 °C, which are among the highest values for known solvent-free ionically conducting polymers.