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Product FOB Price Min.Order Supply Ability Supplier
Triethylene glycol dimethacrylate Manufacturer/High quality/Best price/In stock
Cas No: 109-16-0
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Triethylene Glycol Dimethacrylate supplier in China
Cas No: 109-16-0
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
High purity 109-16-0 TEGDMA [Tri(ethylene glycol]dimethacrylate]
Cas No: 109-16-0
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Good quality Triethylene glycol dimethacrylate//109-16-0
Cas No: 109-16-0
No Data 1 Metric Ton 2000 Metric Ton/Month Hefei TNJ chemical industry co.,ltd Contact Supplier
Triethylene glycol dimethacrylate
Cas No: 109-16-0
No Data 1 Kilogram 1 Metric Ton/Week Henan Allgreen Chemical Co.,Ltd Contact Supplier
Triethylene glycol diMethacrylate
Cas No: 109-16-0
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Triethyleneglycol dimethacrylate
Cas No: 109-16-0
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
TIANFU-CHEM_ Triethylene glycol dimethacrylate(TEGDMA), cas:109-16-0
Cas No: 109-16-0
No Data 1 Kilogram 100 Metric Ton/Month Henan Tianfu Chemical Co., Ltd. Contact Supplier
Factory Supply Triethylene glycol dimethacrylate
Cas No: 109-16-0
USD $ 160.0-200.0 / Gram 200 Gram 5 Kilogram/Day Ality Chemical Corporation Contact Supplier
SGScertificatedfactoryTriethyleneglycoldimethacrylateTEGDMAcas109-16-0price
Cas No: 109-16-0
USD $ 1.0-2.0 / Metric Ton 1 Metric Ton 2 Metric Ton/Day Hubei Jusheng Technology Co., Ltd., Contact Supplier

109-16-0 Usage

Reference

Krifka, S, et al. "A review of adaptive mechanisms in cell responses towards oxidative stress caused by dental resin monomers. " Biomaterials 34.19(2013):4555-4563.

Description

Triethylene glycol dimethacrylate is used as a cross-linking agent in the synthesis of poly (methacrylic acid-g-ethylene glycol) hydrogels which shows large changes in swelling due to changes in pH, temperature and solvent composition. They are also used as divinylic methacrylic monomers which are widely used to form copolymers with divinylbenzene (DVB) and glycidyl methacrylate (GMA) or hydroxyethyl methacrylate (HEMA) comonomers. As a monomer, it is typically used in dental resin materials that can cause specific stress responses in eukaryotic cells. It commonly used to aesthetically restore the structure and function of teeth impaired by caries, erosion, or fracture.
It is cytotoxic via apoptosis, induce genotoxic effects, and delay the cell cycle. It also influences the response of cells of the innate immune system, inhibit specific odontoblast cell functions, or delay the odontogenic differentiation and mineralization processes in pulp-derived cells including stem cells. It is also used as a diluent co-monomer in dimethacrylate based dental composites as well as being used as a branching agent in the atom transfer radical polymerization (ATRP) of styrene.

Uses

Esters of acrylic acid and methacrylic acid, more commonly known as acrylates and methacrylates are key raw materials in the coatings and printing industry, and in food packaging.

Chemical Properties

Colorless liquid
InChI:InChI=1/C14H22O6/c1-11(2)13(15)19-9-7-17-5-6-18-8-10-20-14(16)12(3)4/h1,3,5-10H2,2,4H3

109-16-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (759406)  Triethyleneglycoldimethacrylate  contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99% 109-16-0 759406-50ML 0.00CNY Detail
Aldrich (759406)  Triethyleneglycoldimethacrylate  contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99% 109-16-0 759406-10ML 0.00CNY Detail
Aldrich (759406)  Triethyleneglycoldimethacrylate  contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99% 109-16-0 759406-1ML 3,194.10CNY Detail
Aldrich (261548)  Triethyleneglycoldimethacrylate  contains 80-120 ppm MEHQ as inhibitor, 95% 109-16-0 261548-1L 1,750.32CNY Detail
Aldrich (261548)  Triethyleneglycoldimethacrylate  contains 80-120 ppm MEHQ as inhibitor, 95% 109-16-0 261548-250ML 654.03CNY Detail

109-16-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Triethylene glycol dimethacrylate

1.2 Other means of identification

Product number -
Other names (Ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Adhesives and sealant chemicals,Intermediates,Photosensitive chemicals
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:109-16-0 SDS

109-16-0Synthetic route

dimethyltin dichloride
753-73-1

dimethyltin dichloride

4-methoxy-phenol
150-76-5

4-methoxy-phenol

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

Conditions
ConditionsYield
With sodium methylate; hydroquinone In n-heptane; 2,2'-[1,2-ethanediylbis(oxy)]bisethanol91%
Methacryloyl chloride
920-46-7

Methacryloyl chloride

2-(2-(2-(tert-butyl-dimethyl-silanyloxy)-ethoxy)-ethoxy)-ethanol
201037-95-8

2-(2-(2-(tert-butyl-dimethyl-silanyloxy)-ethoxy)-ethoxy)-ethanol

A

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

B

2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate
495417-68-0

2-[2-[2-[(tert-butyldimethylsilyl)oxy]ethoxy]ethoxy]ethyl methacrylate

Conditions
ConditionsYield
With triethylamine In diethyl ether at 20℃;A n/a
B 81%
Methacryloyl chloride
920-46-7

Methacryloyl chloride

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

Conditions
ConditionsYield
With sodium hydroxide
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

Conditions
ConditionsYield
With sulfuric acid
methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

Conditions
ConditionsYield
With sodium methylate; hydroquinone
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

A

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

B

2-(2-(2-hydroxyethoxy)ethoxy)ethyl methacrylate
2351-42-0

2-(2-(2-hydroxyethoxy)ethoxy)ethyl methacrylate

C

ethylene glycol
107-21-1

ethylene glycol

D

diethylene glycol
111-46-6

diethylene glycol

Conditions
ConditionsYield
toluene-4-sulfonic acid at 70 - 100℃; Kinetics; bulbs method; at various concentrations of catalyst;
2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 73 percent / pyridine / CH2Cl2 / 20 °C
2: triethylamine / diethyl ether / 20 °C
View Scheme
Methacryloyl chloride
920-46-7

Methacryloyl chloride

2,2'-[1,2-ethanediylbis(oxy)]bisethanol
112-27-6

2,2'-[1,2-ethanediylbis(oxy)]bisethanol

A

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

B

2-(2-(2-hydroxyethoxy)ethoxy)ethyl methacrylate
2351-42-0

2-(2-(2-hydroxyethoxy)ethoxy)ethyl methacrylate

Conditions
ConditionsYield
Stage #1: 2,2'-[1,2-ethanediylbis(oxy)]bisethanol With pyridine In dichloromethane at 18 - 28℃; for 0.5h; Inert atmosphere;
Stage #2: Methacryloyl chloride In dichloromethane at 18 - 28℃; for 4h; Cooling with ice; Inert atmosphere;
5-norbornen-2-yl acetate

5-norbornen-2-yl acetate

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

poly(triethylene glycol dimethacrylate-co-5-norbornen-2-yl acetate)

poly(triethylene glycol dimethacrylate-co-5-norbornen-2-yl acetate)

Conditions
ConditionsYield
(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)(η6-p-cymene)RuCl2 for 0.0333333h; blue light irradiation;99%
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer, crosslinked, obtained by polymerization triethyleneglycol dimethylacrylate, initiated by N-propyloyloxytrimethylammonium tetraphenylborate; monomer(s): triethyleneglycol dimethylacrylate

polymer, crosslinked, obtained by polymerization triethyleneglycol dimethylacrylate, initiated by N-propyloyloxytrimethylammonium tetraphenylborate; monomer(s): triethyleneglycol dimethylacrylate

Conditions
ConditionsYield
With sulfuric acid for 0.00416667h;98%
1,3-diaminohexane

1,3-diaminohexane

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

Reaxys ID: 11387382

Reaxys ID: 11387382

Conditions
ConditionsYield
Stage #1: 1,3-diaminohexane With TW-20; sodium carbonate In water
Stage #2: triethyleneglycol dimethacrylate In water
Stage #3: With adipic acid chloride In chloroform; cyclohexane; water
97%
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

p-toluenesulfonyl iodide
1950-78-3

p-toluenesulfonyl iodide

triethylene glycol bis[2-(toluene-4-sulfonylmethyl)acrylate]

triethylene glycol bis[2-(toluene-4-sulfonylmethyl)acrylate]

Conditions
ConditionsYield
Stage #1: triethyleneglycol dimethacrylate; p-toluenesulfonyl iodide In dichloromethane at 20℃; for 24h;
Stage #2: With triethylamine In dichloromethane at 20℃; for 2h;
Stage #3: With triethylamine In ethyl acetate for 6h; Reflux;
81%
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

tartaric acid
87-69-4

tartaric acid

Reaxys ID: 11400417

Reaxys ID: 11400417

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 10 - 80℃; for 6h;75%
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

1-dodecylthiol
112-55-0

1-dodecylthiol

polymer, Mn 5870, PDI 3.44 by SEC; monomer(s): methyl methacrylate; triethylene glycol dimethacrylate; dodecanethiol

polymer, Mn 5870, PDI 3.44 by SEC; monomer(s): methyl methacrylate; triethylene glycol dimethacrylate; dodecanethiol

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 5h;65%
styrene
292638-84-7

styrene

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

poly(styrene-co-triethyleneglycol dimethacrylate), crosslinked, radical suspension polymerized, 2 mol percent triethyleneglycol dimethacrylate; monomers: styrene; triethyleneglycol dimethacrylate

poly(styrene-co-triethyleneglycol dimethacrylate), crosslinked, radical suspension polymerized, 2 mol percent triethyleneglycol dimethacrylate; monomers: styrene; triethyleneglycol dimethacrylate

Conditions
ConditionsYield
With polyvinylalcohol; dibenzoyl peroxide In water; toluene at 80℃; for 8h; Polymerization;54%
1-ethenyl-2-pyrrolidinone
88-12-0

1-ethenyl-2-pyrrolidinone

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

A

poly(N-vinylpyrrolidone-2); monomer(s): N-vinyl-2-pyrrolidone

poly(N-vinylpyrrolidone-2); monomer(s): N-vinyl-2-pyrrolidone

B

polymer; monomer(s): N-vinyl-2-pyrrolidone, 95 mol percent; triethylene glycol dimethacrylate

polymer; monomer(s): N-vinyl-2-pyrrolidone, 95 mol percent; triethylene glycol dimethacrylate

Conditions
ConditionsYield
at 21.85℃; γ-Irradiation;A 35%
B n/a
1-ethenyl-2-pyrrolidinone
88-12-0

1-ethenyl-2-pyrrolidinone

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

A

poly(N-vinylpyrrolidone-2); monomer(s): N-vinyl-2-pyrrolidone

poly(N-vinylpyrrolidone-2); monomer(s): N-vinyl-2-pyrrolidone

B

polymer; monomer(s): N-vinyl-2-pyrrolidone, 86 mol percent; triethylene glycol dimethacrylate

polymer; monomer(s): N-vinyl-2-pyrrolidone, 86 mol percent; triethylene glycol dimethacrylate

Conditions
ConditionsYield
at 21.85℃; γ-Irradiation;A 3%
B n/a
ethanol
64-17-5

ethanol

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

2-Ethoxy-2-hydroxymethylperoxy-propionic acid 2-{2-[2-(2-ethoxy-2-hydroxymethylperoxy-propionyloxy)-ethoxy]-ethoxy}-ethyl ester
64981-68-6

2-Ethoxy-2-hydroxymethylperoxy-propionic acid 2-{2-[2-(2-ethoxy-2-hydroxymethylperoxy-propionyloxy)-ethoxy]-ethoxy}-ethyl ester

Conditions
ConditionsYield
With ozone
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer; monomer(s): butyl methacrylate, 67 mol percent; dodecane-1,2-diyl dimethacrylate, 30.0 mol percent; 2,2,3,3,3-pentafluoropropyl methacrylate; 4-[2-(methacryloyloxy)ethoxycarbonyl]benzyl-N,N-diethyldithiocarbamate, 2.0 mol percent; 1,4-bis(Et2NC(S)SCH2)benzene

polymer; monomer(s): butyl methacrylate, 67 mol percent; dodecane-1,2-diyl dimethacrylate, 30.0 mol percent; 2,2,3,3,3-pentafluoropropyl methacrylate; 4-[2-(methacryloyloxy)ethoxycarbonyl]benzyl-N,N-diethyldithiocarbamate, 2.0 mol percent; 1,4-bis(Et2NC(S)SCH2)benzene

polymer; monomer(s): butyl methacrylate; dodecane-1,2-diyl dimethacrylate; 2,2,3,3,3-pentafluoropropyl methacrylate; 4-[2-(methacroyloxy)ethoxycarbonyl]benzyl-N,N-diethyldithiocarbamate; 1,4-bis(Et2NC(S)SCH2)benzene; triethylene glycol dimethacrylate

polymer; monomer(s): butyl methacrylate; dodecane-1,2-diyl dimethacrylate; 2,2,3,3,3-pentafluoropropyl methacrylate; 4-[2-(methacroyloxy)ethoxycarbonyl]benzyl-N,N-diethyldithiocarbamate; 1,4-bis(Et2NC(S)SCH2)benzene; triethylene glycol dimethacrylate

Conditions
ConditionsYield
at 20℃; for 0.166667h; UV-irradiation;
styrene
292638-84-7

styrene

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 1.6 wt percent; styrene

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 1.6 wt percent; styrene

Conditions
ConditionsYield
With poly(vinyl alcohol); dibenzoyl peroxide In water at 80℃; for 8h;
styrene
292638-84-7

styrene

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 2.2 wt percent; styrene

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 2.2 wt percent; styrene

Conditions
ConditionsYield
With poly(vinyl alcohol); dibenzoyl peroxide In water at 80℃; for 8h;
styrene
292638-84-7

styrene

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 2.7 wt percent; styrene

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 2.7 wt percent; styrene

Conditions
ConditionsYield
With poly(vinyl alcohol); dibenzoyl peroxide In water at 80℃; for 8h;
styrene
292638-84-7

styrene

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 5.3 wt percent; styrene

polymer; monomer(s): tri(ethylene glycol) dimethacrylate, 5.3 wt percent; styrene

Conditions
ConditionsYield
With poly(vinyl alcohol); dibenzoyl peroxide In water at 80℃; for 8h;
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

2-(4-dimethylaminophenyl)ethyl alcohol
50438-75-0

2-(4-dimethylaminophenyl)ethyl alcohol

dibenzoyl peroxide
94-36-0

dibenzoyl peroxide

polymer; monomer(s): triethylene glycol dimethacrylate; benzoyl peroxide; 4-(N,N-dimethylamino)phenethyl alcohol

polymer; monomer(s): triethylene glycol dimethacrylate; benzoyl peroxide; 4-(N,N-dimethylamino)phenethyl alcohol

Conditions
ConditionsYield
at 37℃; Kinetics;
1-ethenyl-2-pyrrolidinone
88-12-0

1-ethenyl-2-pyrrolidinone

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

A

poly(N-vinylpyrrolidone-2); monomer(s): N-vinyl-2-pyrrolidone

poly(N-vinylpyrrolidone-2); monomer(s): N-vinyl-2-pyrrolidone

B

polymer; monomer(s): N-vinyl-2-pyrrolidone, 72 mol percent; triethylene glycol dimethacrylate

polymer; monomer(s): N-vinyl-2-pyrrolidone, 72 mol percent; triethylene glycol dimethacrylate

Conditions
ConditionsYield
at 21.85℃; γ-Irradiation;
1-ethenyl-2-pyrrolidinone
88-12-0

1-ethenyl-2-pyrrolidinone

triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

polymer; monomer(s): N-vinyl-2-pyrrolidone, 57 mol percent; triethylene glycol dimethacrylate

polymer; monomer(s): N-vinyl-2-pyrrolidone, 57 mol percent; triethylene glycol dimethacrylate

Conditions
ConditionsYield
at 21.85℃; γ-Irradiation;
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

poly(triethylene glycol dimethacrylate); monomer(s): triethylene glycol dimethacrylate

poly(triethylene glycol dimethacrylate); monomer(s): triethylene glycol dimethacrylate

Conditions
ConditionsYield
at 21.85℃; γ-Irradiation;
triethyleneglycol dimethacrylate
109-16-0

triethyleneglycol dimethacrylate

triethylene glycol di-isobutyrate
133176-35-9

triethylene glycol di-isobutyrate

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In ethyl acetate at 20℃;

109-16-0Related news

Triethylene glycol dimethacrylate (cas 109-16-0) induces large deletions in the hprt gene of V79 cells08/26/2019

Acrylate esters are applied in industrial and consumer products often associated with polymers and resins. The difunctional methacrylate, triethylene glycol dimethacrylate (TEGDMA), is also frequently included in dental composite materials. Recently, mutagenicity testing of the compound revealed...detailed

Novel self-healing dental resin with microcapsules of polymerizable Triethylene glycol dimethacrylate (cas 109-16-0) and N,N-dihydroxyethyl-p-toluidine08/25/2019

ObjectiveBulk fracture is one of the primary reasons for resin-based dental restoration failures. To date, there has been no report on the use of polymerizable dental monomers with acceptable biocompatibility to develop a resin with substantial self-healing capability. The objectives of this stu...detailed

In vitro cellular detoxification of Triethylene glycol dimethacrylate (cas 109-16-0) by adduct formation with N-acetylcysteine08/23/2019

ObjectiveVarious protective effects of N-acetylcysteine (NAC) against triethylene glycol dimethacrylate (TEGDMA)-induced cell damage have been demonstrated, but so far there is no evidence on NAC direct monomer detoxification mechanism. Here, we hypothesized that NAC might reduce TEGDMA cytotoxi...detailed

Triethylene glycol dimethacrylate (cas 109-16-0) impairs bioenergetic functions and induces oxidative stress in mitochondria via inhibiting respiratory Complex I08/22/2019

ObjectivesEarlier studies demonstrated that dental resin monomers lower cellular viability and provoke oxidative stress. Reactive oxygen species (ROS) formation has a key role in triethylene glycol dimethacrylate (TEGDMA) induced adverse reactions. In the present study the effects of TEGDMA on m...detailed

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